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11.
Routine analysis of hydrocarbons, PCB and PAH in marine sediments using supercritical CO2 extraction
Automated Supercritical Fluid Extraction (SFE), using CO2, was tested and optimised for routine analysis of hydrocarbons (THC), polychlorinated biphenyls (PCB) and polycyclic aromatic hydrocarbons (PAH) in marine sediments. The aim of the exercise was to reduce the amount of solvents used and to reduce the manual handling time for each sample. The sediments contained elemental sulphur, which was removed during the extraction step using activated Cu. Similar recoveries and reproducibility where found for THC when conventional solvent extractions and SFE where compared. Modifying the CO2 with methanol was necessary to obtain extraction recoveries similar to conventional extraction methods for PCB and PAH. 相似文献
12.
Assessment of sampling and chemical analysis of source-separated organic household waste 总被引:2,自引:0,他引:2
la Cour Jansen J Spliid H Hansen TL Svärd A Christensen TH 《Waste management (New York, N.Y.)》2004,24(6):541-549
The quality of the waste sampling procedure and chemical analysis was evaluated in a research program on characterization of organic waste obtained after disc screening of source-separated organic household waste. The sampling procedures focused on a truckload of waste and involved several steps of subsampling including shredding, mixing, blending, high-speed-blending, drying and milling prior to analysis of the organic waste with respect to ash content, crude fibers, crude fat, crude protein, sugar, starch, enzyme-digestible organic matter, P, N, C, H, S and calorific value. The statistical evaluation of the procedures involved 10 samples of the same truckload of waste obtained by splitting the sample at each level in the procedure according to a staggered, incomplete nested statistical design. Furthermore, one sample was analysed six times over a period of approximately one year. The statistical evaluation showed that no single step in the sampling procedure contributed with excessive variance and that the variance caused by the sampling procedure was approximately the same as the variance in the chemical analysis observed over a year. The variance varied with the analytical parameter but for most parameters the uncertainty was satisfactorily low (of the order of 3-10% expressed as the relative standard deviation, which is considered to be satisfactory for waste characterization). 相似文献
13.
Automobile insurance claims were examined to determine the rates of neck injuries in rear-end crashes for vehicles with and without redesigned head restraints, redesigned seats, or both. Results indicate that the improved geometric fit of head restraints observed in many newer vehicle models are reducing the risk of whiplash injury substantially among female drivers (about 37% in the Ford Taurus and Mercury Sable), but have very little effect among male drivers. New seat designs, such as active head restraints that move upward and closer to drivers' heads during a rear impact, give added benefit, producing about a 43% reduction in whiplash injury claims (55% reduction among female drivers). Estimated effects of Volvo's Whiplash Injury Prevention System and Toyota's Whiplash Injury Lessening design were based on smaller samples and were not statistically significant. 相似文献
14.
Odland JØ Nieboer E Romanova N Thomassen Y Hofoss D Lund E 《Journal of environmental monitoring : JEM》2001,3(2):177-184
Concentrations in human placenta of 11 essential elements (P, Ca, Mg, Cu, S, Na, Fe, Zn, K, Se, Mn) and 5 toxic elements (Ba, Sr, Pb, Ni, Cd) are compared for each of two arctic communities in eastern Norway and western Russia, and for another in each country located at more southerly latitudes. All but Mg, Fe, P and K were present in higher concentrations in the Russian study group. The observed inter-element correlations are reflected by the four major factors identified in a principal component analysis. The total variation explained was 67.3%, of which more than half (35.3%) was contributed by Factor 1. P, Ca, Mg, Ba, Sr, Pb, and Ni were major contributors to this factor. The placental concentrations of these elements depended strongly on gestational age, increasing from about week 35 and peaking near weeks 39 and 40, and exhibited skewed frequency distributions and a dependence on maternal smoking. The gestational-dependent mineralization of the placenta is interpreted to reflect the deposition of metal phosphates coinciding with smoking-induced tissue damage. The loadings of the remaining three factors are reviewed in the context of common uptake mechanisms, similar biochemistries and unique transport pathways. The inter-element relationships and grouping of the elements observed should constitute a scientific base for the use of placenta composition in environmental monitoring and epidemiological studies. 相似文献
15.
Louise Simonsen Inge S. Fomsgaard Bo Svensmark Niels Henrik Spliid 《Journal of environmental science and health. Part. B》2013,48(5):365-375
The fate of glyphosate and its degradation product aminomethylphosphonic acid (AMPA) was studied in soil. Labeled glyphosate was used to be able to distinguish the measured quantities of glyphosate and AMPA from the background values since the soil was sampled in a field where glyphosate had been used formerly. After addition of labeled glyphosate, the disappearance of glyphosate and the formation and disappearance of AMPA were monitored. The resulting curves were fitted according to a new EU guideline. The best fit of the glyphosate degradation data was obtained using a first-order multi compartment (FOMC) model. DT50 values of 9 days (glyphosate) and 32 days (AMPA) indicated relatively rapid degradation. After an aging period of 6 months, the leaching risk of each residue was determined by treating the soil with pure water or a phosphate solution (pH 6), to simulate rain over a non-fertilized or fertilized field, respectively. Significantly larger (p < 0.05) amounts of aged glyphosate and AMPA were extracted from the soil when phosphate solution was used as an extraction agent, compared with pure water. This indicates that the risk of leaching of aged glyphosate and AMPA residues from soil is greater in fertilized soil. The blank soil, to which 252 g glyphosate/ha was applied 21 months before this study, contained 0.81 ng glyphosate/g dry soil and 10.46 ng AMPA/g dry soil at the start of the study. Blank soil samples were used as controls without glyphosate addition. After incubation of the blank soil samples for 6 months, a significantly larger amount of AMPA was extracted from the soil treated with phosphate solution than from that treated with pure water. To determine the degree of uptake of aged glyphosate residues by crops growing in the soil, 14C-labeled glyphosate was applied to soil 6.5 months prior to sowing rape and barley seeds. After 41 days, 0.006 ± 0.002% and 0.005 ± 0.001% of the applied radioactivity was measured in rape and barley, respectively. 相似文献
16.
Torsten Norlander Henrik Bergman Trevor Archer 《Journal of environmental psychology》1998,18(4):399-408
The purpose of the present study was to explore whether or not flotation restricted environmental stimulation technique (REST) facilitates the creative problem-solving ability and originality. Sample 1 consisted of 40 subjects, 20 men and 20 women, randomly assigned in equal numbers to either a nonREST group (armchair-sitting) or to a floating REST group. Both groups worked on a `chain puzzle' for 5 min and were then interrupted with 45 min of sitting or floating. The subjects were then given the task of continuing with the creative problem-solving test. Sample 2 consisted of 54 subjects, 27 men and 27 women, randomly assigned in equal numbers to either a nonREST group (armchair-sitting), a dryREST group (lying on a couch in a dark room) or a flotation REST group. The groups then had to fill in a couple of paper-and-pen tests and were given scores on fluency, obvious answers, original answers, elegance and deductive thinking. The results (impaired creative problem-solving ability and higher originality for the floating group) were interpreted as an indication of cognitive function where the primary process still dominates over the secondary process. 相似文献
17.
18.
This study estimates efficient nitrogen load reductions to the Stockholm archipelago, a Swedish coastal zone in the Baltic
Sea, and compares these with politically determined and implemented nitrogen abatement programs. The region is relatively
well equipped with necessary data, and a simple programming model is constructed. The results show a large divergence in efficient
nitrogen reductions, mainly due to the divergences in benefit estimates from water quality improvements in the archipelago.
However, the results need to be interpreted with caution due to all uncertainties related to predicting net values from changes
in nitrogen load to a coastal zone. In spite of this, it is still of policy relevance to infer results which show that the
politically determined target coincides with an efficient nitrogen reduction at relatively low benefit estimate, but that
actual net benefits could be increased from a reallocation of abatement measures towards more low cost measures. 相似文献
19.
This paper investigates the impact of the recent criminalisation of humanitarian actors engaged in the search for and rescue of migrants in distress in the Mediterranean Sea, focusing on the impact on the motivation and engagement of humanitarian volunteers in Greece. It argues that criminalisation is aimed at reducing search and rescue (SAR) activities and thus removing perceived ‘pull factors’ for migrants. The paper locates this phenomenon within the broader trend of policing and punishing those who assist migrants in order to deter them and prevent others from engaging in such endeavours. It finds that efforts to criminalise can have the unintended effects of encouraging and mobilising volunteers, as well as generating public attention and support for migrants. However, the negative consequences of criminalisation are far-reaching, including contributing to a high mortality rate among those crossing the Mediterranean without SAR capabilities and the heightened risk of violence against migrants and those who help them. 相似文献
20.
Stakeholders on Meat Production, Meat Consumption and Mitigation of Climate Change: Sweden as a Case
Henrik Lerner Bo Algers Stefan Gunnarsson Anders Nordgren 《Journal of Agricultural and Environmental Ethics》2013,26(3):663-678
In this paper we analyse and discuss the views of Swedish stakeholders on how to mitigate climate change to the extent it is caused by meat production. The stakeholders include meat producer organisations, governmental agencies with direct influence on meat production, political parties as well as non-governmental organisations. Representatives of twelve organisations were interviewed. Several organisations argued against the mitigation option of reducing beef production despite the higher greenhouse gas intensity of beef compared to pork and chicken meat (according to life cycle analysis). Regarding feed production some organisations proposed use of the best available industrial fertilizers, others were against all use of such fertilizers. Several organizations suggested domestic production of more protein-rich fodder and use of manure for biogas production. Regarding meat consumption the focus was on throwing away less food as waste and on eating less meat but the best (most climate friendly) meat, which was considered to be Swedish meat in contrast to imported meat. There was agreement on many issues. Most disagreement was found regarding political steering. We find many of the stakeholders’ mitigation proposals regarding meat production and consumption acceptable. However, we are to some extent critical to their defence of Swedish beef production. We also point out certain problems with the suggestion to reduce consumption of imported meat but not of domestically produced meat. 相似文献