Studying the modes of selenium occurrence in high-Se soils and its behaviors can improve understanding and evaluating its cycling, flux, and balance in geo-ecosystems and its influence on health. In this paper, using a modified sequential chemical extraction technique, seven operationally defined selenium fractions and Se valence distribution were determined about five soils in which paddy was planted (W1, W2, W3, W4, W5) and five soils in which maize was planted (H1, H2, H3, H4, H5) around the selenium-rich core, Ziyang County, Shaanxi Province, China. The results show that selenium fractions in the soils mainly include sulfide/selenide and base-soluble Se, and ligand-exchangeable Se is also high for five soils in which paddy was planted. For water-soluble Se, Se (IV) is main Se valence and almost no Se (VI) was determined about five soils in which paddy was planted, while almost 1:1 of Se (IV) and Se (VI) coexist about five soils in which maize was planted. For exchangeable Se, similar results were found. For the first time, two typical high-Se soils (W1 soil and H1 soil) were chosen to measure the pH-dependent solid-solution distribution of selenite in the pH range 3–9, and the results were explained using LCD (ligand and charge distribution) adsorption modeling. The desorbed selenite concentrations from the two soils are in general underestimated by the model due to a comparable binding affinity of phosphate and selenite on goethite and much lower amount of total selenite than total reactively adsorbed phosphate. The pH dependency of adsorption of selenite added to the soil can be successfully described with the LCD model for W1 soil. Whereas considering the influence of Al-oxides, by lowering selenite adsorption affinity constant K of Se adsorption on goethite by 16 times, the LCD model can describe the adsorption much better. The results can help to understand selenium cycling, flux, and balance in typical high-Se soils.
A total of 11 sediment samples were collected from the sites along Haihe River?CBohai Bay, with site 1 at the beginning of Haihe River and site 11 in Bohai Bay, about 150 km away from site 1. Quinone profiles were used for the analysis of microbial community as influenced by pollutants in water and sediments, such as heavy metals, and other environmental factors. Nineteen species of quinones were found at site 1 while only six species at sites 10 and 11. Both the diversity of quinone species (DQ) and the number of quinones were higher in the sediments from Haihe River and the near-sea area of Bohai Bay than in those from the deep-sea area. The ?? diversity values were significantly higher, while Jaccard indexes of similarity were much lower among non-contiguous pairs of sites as compared with the contiguous ones. Cluster analysis indicated that quinone profiles may be grouped into two main clusters (sites 1?C7 and sites 8?C11), and there were higher similarities within the groups than between groups. Quinone species composition varied at different sites. Ubiquinones such as UQ-8, UQ-9, and UQ-10 and menaquinones such as MK-6, MK-7, MK-8 were isolated from all the sites and accounted for the largest proportions. Pearson correlation analysis revealed that both the number of quinone species and DQ correlated positively with total organic carbon contents in water and sediments, but negatively correlated with salinity and electroconductivity and did not correlate significantly with heavy metal contents in water. 相似文献
Anti-estrogenic activity in wastewater is gaining increased attention because of its endocrine-disrupting function. In this study, the level and removal efficiency by coagulation of anti-estrogenic activity in secondary effluents of domestic wastewater treatment plants were studied. Anti-estrogenic activity was detected in secondary effluent samples at a tamoxifen (TAM) equivalent concentration level of 0.38–0.94 mg-TAM L−1. Dissolved organic matters (DOM) with the molecular weight (MW) less than 3000 Da in hydrophobic acids (HOA) and hydrophobic neutrals (HON) fractions of the secondary effluent were the key fractions related to anti-estrogenic activity. Coagulation with FeCl3 and polyaluminium chloride (PAC) can remove the anti-estrogenic activity of the secondary effluents, but the removal efficiency was limited. The removal efficiency using FeCl3 coagulant was higher than that induced by PAC. Dissolved organic carbon was continuously removed with increased coagulant dose (0–120 mg L−1 FeCl3 or 0–60 mg L−1 PAC). However, the removal of anti-estrogenic activity was not enhanced further when the coagulant concentration was beyond a critical value (30 mg L−1 FeCl3 or 10 mg L−1 PAC). The highest removal of anti-estrogenic activity was about 36% by FeCl3 and 20% by PAC. Size exclusion chromatography results indicated difficulty in removing DOM with MW less than 3000 Da in the secondary effluent during coagulation even at a high coagulant concentration, which led to low removal efficiency of anti-estrogenic activity. 相似文献
Abstract: his paper explored the relationships among nonagricultural population, employment and land in an integrated framework, taking account of rural-urban land conversion into Carlino-Mills's model on the regional growth. Two-stage-leastsquares and ordinary-least-squares were employed. Recent data for district (grade) cities in China (from 1999 to 2005) were used. Our results showed that: first, urban population influenced non-agricultural employment, and vice versa, but the evidence that non-agricultural employment influenced urban population was stronger than the evidence that urban population influenced non-agricultural employment; second, urban population and non-agricultural employment both influenced ruralurban land conversion, but the evidence that urban population influenced rural urban land conversion was more stronger than the evidence that non-agricultural employment did. We also found that: first, the employment from the secondary industry influenced urban population in a positive way, and vice versa, but the employment from the tertiary industry influenced urban population in a negative way, and vice versa; second, the employment from the secondary industry influenced rural-urban land conversion in a positive way, but the employment from the tertiary industry influenced rural-urban land conversion in a negative way. We can conclude that the key of urbanization is to speed up the process of non-agricultural employment, especially the employment from the tertiary industry, which might promote non-agricultural population, employment and land harmoniously. 相似文献
Scientists have aimed at exploring land use and land cover change (LUCC) and modeling future landscape pattern in order to
improve our understanding of the causes and consequences of these phenomena. This study addresses LUCC in the upper reaches
of Minjiang River, China, from 1974 to 2000. Based on remotely sensed images, LUCC and landscape pattern change were assessed
using cross-tabulation and landscape metrics. Then, using the CLUE-S model, changes in area of four types of land cover were
predicted for two scenarios considering forest polices over the next 20 years. Results showed that forestland decreased from
1974 to 2000 due to continuous deforestation, while grassland and shrubland increased correspondingly. At the same time, the
farmland and settlement land increased dramatically. Landscape fragmentation in the study area accompanied these changes.
Forestland, grassland, and farmland take opposite trajectories in the two scenarios, as does landscape fragmentation. LUCC
has led to ecological consequences, such as biodiversity loss and lowering of ecological carrying capacity. 相似文献