Electronic waste recycling: A review of U.S. infrastructure and technology options

The useful life of consumer electronic devices is relatively short, and decreasing as a result of rapid changes in equipment features and capabilities. This creates a large waste stream of obsolete electronic equipment, electronic waste (e-waste).Even though there are conventional disposal methods for e-waste, these methods have disadvantages from both the economic and environmental viewpoints. As a result, new e-waste management options need to be considered, for example, recycling. But electronic recycling has a short history, so there is not yet a solid infrastructure in place.In this paper, the first half describes trends in the amount of e-waste, existing recycling programs, and collection methods. The second half describes various methods available to recover materials from e-waste. In particular, various recycling technologies for the glass, plastics, and metals found in e-waste are discussed. For glass, glass-to-glass recycling and glass-to-lead recycling technologies are presented. For plastics, chemical (feedstock) recycling, mechanical recycling, and thermal recycling methods are analyzed. Recovery processes for copper, lead, and precious metals such as silver, gold, platinum, and palladium are reviewed. These processes are described and compared on the basis of available technologies, resources, and material input–output systems.     

Remediation of Persistent Organic Pollutants Using a Novel Two-Phase Soil Washing Biosorption Process

A two-phase soil washing biosorption process was developed for the remediation of p,p-DDT-contaminated soil. The process involved desorption of contaminants from soil using dilute primary alcohols (40% 1-propanol) followed by contaminant removal from cosolvent solutions using fungal biosorption. Bench scale remediation studies were preformed to simulate ex situ (recycling experiment) or in situ (soil column study) treatment strategies. Both systems were effective at cleaning the soil to below Australian regulatory p,p-DDT levels. After 50–80 hours of soil washing, over 93% of p,p-DDT was removed from the soil(990 mg kg^-1 to <65 mg kg^-1) using either of these methods.p,p-DDT was removed from the cosolvent phase by sorption onto the fungal biomass. This resulted in only low levels of p,p-DDT remaining in the cosolvent solution(<1.5 mg l^-1). The application of both treatment strategies resulted in the rapid clean up of p,p-DDT-contaminated soil and the potential to recycle cosolvent solutions. The ability to recycle cosolvent solutions provides a mechanism for cost reductions of the remediation strategy.     

THE LODGING VELOCITY FOR EMERGENT AQUATIC PLANTS IN OPEN CHANNELS1

ABSTRACT: The growth of aquatic plants in open‐channels has many adverse environmental effects including, but not limited to, impeding the transport of water, hindering navigation, increasing flood elevations, increasing sediment deposition, and degrading water quality. Existing control strategies include physical removal and chemical treatment. Physical removal is only a temporary solution and chemical treatment is unacceptable if the water will be consumed by humans. The hydrodynamic method can wash out the encroached aquatic plants by keeping flow velocity higher than the critical velocity required to bend and rupture (lodge) their stems. This approach is a promising, physically‐based, efficient, economic, and permanent solution for this problem. However, the success of this approach requires the accurate prediction of the critical lodging velocity. This paper presents an analytic study of the lodging velocity for the submerged portion of aquatic plants of narrow leaved emergent stems that are wider at bottom than the top. Based on the principles of engineering materials and the theory of turbulent flow, a semi‐empirical formula is derived for the prediction of the critical lodging velocity. It indicates that the lodging of aquatic plants is controlled not only by flow conditions but also the geometric and mechanical characteristics of the plants. These analytic results provide a satisfactory explanation of the lodging phenomena observed in the field and are verified by the available experimental data.     

Gender and Hurricane Mitch: reconstructing subjectivities after disaster

Much of the gender and disaster literature calls for more gender-sensitive disaster relief and research by focusing on the ways in which women are more vulnerable in a disaster or on their unique capabilities as community leaders or natural resource managers, which are often overlooked or underutilised in emergency management strategies. As well as seeking to overcome the (strategic) essentialism that is part of these calls and debates, this paper pays closer attention to gender identity and subjectivity as these are constructed and reworked through the disaster process to highlight the complexities and contradictions associated with women's responses to a disaster. This focus, while crucial to gaining a deeper understanding of the gendered dimensions of disaster, also complicates attempts to create more gender-sensitive frameworks for disaster response. It draws on qualitative research conducted with a number of women in the wake of Hurricane Mitch (1998) in Nicaragua.     

The contemporary Asian silver cycle: 1-year stocks and flows

The stocks and flows of silver throughout the Asian economy for 1997 have been quantified, with major flows examined over their entire life cycle, including mining, production, fabrication, and manufacture, product use, and waste management. By compiling the findings of 11 country-level material flow analyses, a regional analysis was created. The reliability and availability of the data varied, with the most confidence given to the earlier life stages and the most uncertainty existing later. Overall, Asia is a net importer of silver, requiring nearly 7000 Mg of silver in 1997. Approximately 2200 Mg Ag are mined, and production waste totals about 640 Mg Ag. The flow of silver into use equals 9900 Mg Ag, with a considerable build-up of 7100 Mg Ag entering in-use stock. Silver waste sent directly to the environment, in addition to landfilled waste, totals 1600 Mg Ag. Much variation exists when examining country-level silver flows on a per capita basis. India and Thailand’s fondness for silver jewelry greatly increases their silver flows into use and in-use stock. Japan’s high overall consumption reflects its high GDP per capita. Regionally, a significant potential exists to tap the silver contained in the in-use stocks and to enhance the recycling rates.     

Defining reference conditions for acidified waters using a modern analogue approach

Analogue matching is a palaeolimnological technique that aims to find matches for fossil sediment samples from a set of modern surface sediment samples. Modern analogues were identified that closely matched the pre-disturbance conditions of eight of the UK Acid Waters Monitoring Network (AWMN) lakes using diatom- and cladoceran-based analogue matching. These analogue sites were assessed in terms of hydrochemistry, aquatic macrophytes and macro-invertebrates as to their suitability for defining wider hydrochemical and biological reference conditions for acidified sites within the AWMN. The analogues identified for individual AWMN sites show a close degree of similarity in terms of their hydrochemical characteristics, aquatic macrophytes and, to a lesser extent, macro-invertebrate fauna. The reference conditions of acidified AWMN sites are inferred to be less acidic than today and to support a wider range of acid-sensitive aquatic macrophyte and macro-invertebrate taxa than that recorded in the AWMN lakes over the period of monitoring since 1988.     

Mass effects mediate coexistence in competing shrews

Recent developments in metacommunity theory have raised awareness that processes occurring at regional scales might interfere with local dynamics and affect conditions for the local coexistence of competing species. Four main paradigms are recognized in this context (namely, neutral, patch-dynamics, species-sorting, and mass-effect), which differ according to the role assigned to ecological or life-history differences among competing species, as well as to the relative time scale of regional vs. local dynamics. We investigated the patterns of regional and local coexistence of two species of shrews (Crocidura russula and Sorex coronatus) sharing a similar diet (generalist insectivores) over four generations, in a spatially structured habitat at the altitudinal limit of their distributions. Local populations were small, and regional dynamics were strong, with high rates of extinction and recolonization. Niche analysis revealed significant habitat differentiation on a few important variables, including temperature and availability of winter resting sites. In sites suitable for both species, we found instances of local coexistence with no evidence of competitive exclusion. Patterns of temporal succession did not differ from random, with no suggestion of a colonization-competition trade-off. Altogether, our data provide support for the mass-effect paradigm, where regional coexistence is mediated by specialization on different habitat types, and local coexistence by rescue effects from source sites. The strong regional dynamics and demographic stochasticity, together with high dispersal rates, presumably contributed to mass effects by overriding local differences in specific competitive abilities.     

Regulation of intertidal food webs by avian predators on New England rocky shores

Although there is a large body of research on food webs in rocky intertidal communities, most of the emphasis has been on the marine benthic components. Effects of avian predation on highly mobile predators such as crabs, remains practically unstudied in rocky shore ecosystems. The crab, Cancer borealis, is an important component of the diet of gulls (Larus marinus, L. argentatus) at the Isles of Shoals, Maine, USA. C. borealis prey include the predatory gastropod Nucella lapillus L., the herbivore Littorina littorea, and mussels Mytilus edulis L. We hypothesized that gulls reduce abundance of C. borealis in the low intertidal and shallow subtidal, thereby allowing C. borealis prey to persist in high numbers. A study of crab tidal migration showed that C. borealis density nearly doubled at high tide compared to low tide; thus, crabs from a large subtidal source population migrate into the intertidal zone during high tides and either emigrate or are removed by gulls during low tides. Results from a small-scale (1 m2) predator caging experiment in the low intertidal zone indicated that enclosed crabs significantly reduced L. littorea abundance when protected from gull predation. In a much larger-scale gull exclusion experiment, densities of C. borealis increased significantly during low and high tides in exclosures relative to the controls. C. borealis density was inversely correlated with changes in the abundance of two mesopredators Carcinus maenas and Nucella lapillus, and with the space-occupier M. edulis. There was a similar negative correlation between abundance of C. borealis and the change in abundance of the herbivore L. littorea, but the trend was not significant. Mortality of tethered L. littorea was associated with C. borealis density across sites. However, preferred algae did not change in response to L. littorea density during the experiment. Thus, we found suggestive, but not conclusive, evidence for a three-level cascade involving gulls, crabs, and L. littorea. Our studies strongly suggest that gulls, as apex predators, generate three-level trophic cascades in rocky intertidal food webs by preventing the highly mobile subtidal predator, C. borealis, from establishing substantial populations in the low-mid intertidal zone thereby indirectly enhancing densities of two key mesopredators (N. lapillus, Carcinus) and blue mussels (M. edulis).     

Ablagerung toxischer Chemieabfälle im August 2006 in Abidjan, Republik Côte d’Ivoire: Versuch einer Rekonstruktion

Background

Globally, every year several hundred million tons of problematic, e.g. chemical, wastes are generated stemming to more than 90% from the 25 OECD countries. Due to their partly considerable toxicity special and often expensive measures are required for their disposal. According to the Secretary of the ‘Basel Convention on the Control of Transboundary Movements of Hazardous Waste and Their Disposal’ annually at least 8.5 million tons of wastes are transboundarily traded. Although the ‘Basel Convention’ has set up rules how to handle international waste streams, certain waste amounts are illegally transported from the OECD countries to developing countries — basically for reasons of expenses. Often an environmental safe treatment of toxic waste is not ensured or even not possible in the receiving countries. As set forth in a report of the European Network for the Implementation and Enforcement of Environmental Law (IMPEL) published in 2006, the illegal trade with toxic waste has steadily increased. 3000 shipping documents of 17 European seaports were examined and 258 cargo holds were inspected showing that 68 of 140 waste shippings were illegal. Preventing illegal transports of waste meets with various obstacles. Controlling measures require considerable personal, technical, and logistic resources that are not sufficiently available in each country concerned. Missing or ineffective administrative structures hamper fast actions to stop illegal waste disposal. Partly, the political will to take the necessary steps is lacking. An additional problem is the fact that waste that is obtained from the regular shipping business is not subject to the Basel Convention but to the ‘International Convention for the Prevention of Pollution from Ships’. The implementing statures are summarized in the document MARPOL 73/78; the International Maritime Organization (IMO) is responsible. Identifying the origin of waste and thus defining the responsibility occasionally raises difficulties. This background provides a basis to try to reconstruct the course of events concerning the disposal of chemical waste in Abidjan.

Methods

Several information sources were utilized to reconstruct the course of events at Abidjan in August 2006; e.g. public press, declarations of international governmental organizations, especially of the UN and of its subsidiary organizations, communiqués of the Secretary of the Basel Convention, and statements of several NGOs. Nevertheless a complete reconstruction of the incident is impossible, since a detailed and reliable historical report is not available. Furthermore the responsible politicians have not undertaken significant efforts to shed light upon the incident. Additionally relevant documents of the participating companies are not available to the public.

Conclusions

The analyzed incident makes obvious that the control mechanisms of the Basel Convention can be circumvented. It remains unclear who has to take the political responsibility for the death of 10 people and for the health defects of thousands of humans. Possible civil and criminal consequences are not foreseeable for the actors and company owners involved in the illegal waste dumping. The people of Abidijan are confronted with unresolved questions regarding the occurrence of chronic diseases and possible long-term effects of remaining waste portions.

Recommendations and Perspectives

The incident demonstrates that the control of the transboundary transport and disposal of hazardous waste needs to be enforced and legal grey areas should be eliminated. It should be a task of the OECD countries and of all other economically and technically developed countries and organizations to support the developing countries’ efforts to build up the personal, technical, and infrastructural capacities for an efficient control of waste imports.