Biodegradation of Epoxy and MF Modified Polyurethane Films Derived from a Sustainable Resource

Mesua ferrea L. seed oil (MFLSO) modified polyurethanes blends with epoxy and melamine formaldehyde (MF) resins have been studied for biodegradation with two techniques, namely microbial degradation (broth culture technique) and natural soil burial degradation. In the former technique, rate of increase in bacterial growth in polymer matrix was monitored for 12 days via a visible spectrophotometer at the wavelength of 600 nm using McFarland turbidity as the standard. The soil burial method was performed using three different soils under ambient conditions over a period of 6 months to correlate with natural degradation. Microorganism attack after the soil burial biodegradation of 180 days was realized by the measurement of loss of weight and mechanical properties. Biodegradation of the films was also evidenced by SEM, TGA and FTIR spectroscopic studies. The loss in intensity of the bands at ca. 1735 cm⁻¹ and ca. 1050 cm⁻¹ for ester linkages indicates biodegradation of the blends through degradation of ester group. Both microbial and soil burial studies showed polyurethane/epoxy blends to be more biodegradable than polyurethane/MF blends. Further almost one step degradation in TG analysis suggests degradation for both the blends to occur by breakage of ester links. The biodegradation of the blends were further confirmed by SEM analyses. The study reveals that the modified MFLSO based polyurethane blends deserve the potential to be applicable as “green binders” for polymer composite and surface coating applications.     

Endorsement of Ethnomedicinal Knowledge Towards Conservation in the Context of Changing Socio-Economic and Cultural Values of Traditional Communities Around Binsar Wildlife Sanctuary in Uttarakhand, India

The study of the interrelationship between ethnomedicinal knowledge and socio-cultural values needs to be studied mainly for the simple reason that culture is not only the ethical imperative for development, it is also the condition of its sustainability; for their exists a symbiotic relationship between habitats and cultures. The traditional communities around Binsar Wildlife Sanctuary of Uttarakhand state in India have a rich local health care tradition, which has been in practice for the past hundreds of years. The present study documents the Ethnomedicinal uses of 54 medicinal and aromatic plants (MAPs) along with their botanical and vernacular names, family, habit, habitat, threat status, collection season, purpose of collection, quantity, conservation practices, market potential and part(s) used in traditional health care system. The documented species belonging to 38 families have been used to cure more than 47 different kinds of ailments. These MAPs collected from the wild in a particular season and used as per the method prescribed by traditional herbal healers (Vaidyas) that provide effective results. Perception of local people during field trips based on socio-demographic characters showed them to prefer herbal system of treatments and they understood the status of traditional health care systems in the region. The study reveals that approximately 70 % population of the study area depend on herbal systems of treatments and preferred to visit Vaidyas for curing a variety of ailments because the traditional system of medicine is one of the most important prevailing systems in the region where modern health care facilities are rare or in very poor conditions. The organic cultivation practices of selected MAPs were demonstrated to rural inhabitants through capacity building training program and participatory action research framework approaches for sustainability and enhancement of livelihood security. A series of workshops and village level meetings on traditional health care systems were organized and forming/registered a strong association of Vaidyas for making their traditional system of health care more practical and effective. The study emphasizes the potentials of the ethnomedicinal research, conservation practices, socio-cultural and religious ethics for promoting traditional plants based treatments and also the need to document the indigenous knowledge for scientific validation before its industrial application.     

Socioeconomics and sources of livelihood security in Central Himalaya,India: a case study

ABSTRACT

This case study was conducted in Himalayan watershed to understand traditional farming and socio-economic status of the people in Kumaon Himalaya, Uttarakhand, India. In spite of high literacy rate in this area, their livelihood security is reliant on traditional farming practices that include agroforestry beside forest produce. More than 85% farming is rainfed and managed in a traditional way. Land holding size owned by farmers in the area extended from 0.57 to 2.57 ha but majority of farmers (51–80%) had farms of size less than 0.50 ha. The study revealed that forests provided 73–79% of required energy from fuelwood and more than 81% fodder. Agroforestry, livestock (dairy and poultry/goat rearing) and labour employment are the major sources of income to the people in the watershed. The income of people was positively correlated with livestock rearing and traditional farming.     

Land-use planning for sustainable resource development in Kumaon Lesser Himalaya—a study of the Gomti watershed

SUMMARY

The Lesser Himalaya, as the most densely populated part of the tectonically active and ecologically sensitive Himalayan mountain ranges, deserves specific attention to the conservation of the environment and the sustainable development of natural resources. Rapid growth of the human population during recent years, and the absence of any viable means of livelihood other than uneconomic crop farming have led to the uncontrolled exploitation of land areas and the consequent degradation and depletion of critical biophysical resources in the region. The need for sustainable development in Himalaya, therefore, makes it imperative to adopt a comprehensive land-use policy based on land capacity analysis that is scientific and practical. The main objective of this paper is to evolve an optimal land-use framework for the Gomti Watershed, situated in Kumaon, Lesser Himalaya. A detailed study of the traditional land use, regional agricultural system and the areas prone to environmental hazards was made throughout the watershed, through the preparation of large scale topographical forest and land record maps, field surveys and mapping. The average slope was considered as the principal parameter of land capacity, the potential for landslides and the intensity of erosion. Recognising the drastic changes that have taken place in the traditional land use, the watershed area has been proposed to be defined as protected forests (33.41%), community forests (32.86%), cultivation (23.33%) and horticulture (8.30%).     

Environmental risk appraisement of disinfection by-products (DBPs) in plant model system: Allium cepa

The organic toxicants formed in chlorinated water cause potential harm to human beings, and it is extensively concentrated all over the world. Various disinfection by-products (DBPs) occur in chlorinated water are genotoxic and carcinogenic. The toxicity is major concern for chlorinated DBPs which has been present more in potable water. The purpose of the work was to evaluate genotoxic properties of DBPs in Allium cepa as a plant model system. The chromosomal aberration and DNA laddering assays were performed to examine the genotoxic effect of trichloroacetic acid (TCAA), trichloromethane (TCM), and tribromomethane (TBM) in a plant system with distinct concentrations, using ethyl methanesulfonate (EMS) as positive control and tap water as negative control. In Allium cepa root growth inhibition test, the inhibition was concentration dependent, and EC₅₀ values for trichloroacetic acid (TCAA), trichloromethane (TCM), and tribromomethane (TBM) were 100 mg/L, 160 mg/L, and 120 mg/L respectively. In the chromosome aberration assay, root tip cells were investigated after 120 h exposure. The bridge formation, sticky chromosomes, vagrant chromosomes, fragmented chromosome, c-anaphase, and multipolarity chromosomal aberrations were seen in anaphase–telophase cells. It was noticed that with enhanced concentrations of DBPs, the total chromosomal aberrations were more frequent. The DNA damage was analyzed in roots of Allium cepa exposed with DBPs (TCAA, TCM, TBM) by DNA laddering. The biochemical assays such as lipid peroxidation, H₂O₂ content, ascorbate peroxidase, guaiacol peroxidase, and catalase were concentration dependent. The DNA interaction studies were performed to examine binding mode of TCAA, TCM, and TBM with DNAs. The DNA interaction was evaluated by spectrophotometric and spectrofluorometric studies which revealed that TCAA, TCM, and TBM might interact with Calf thymus DNA (CT- DNA) by non-traditional intercalation manner.

     

Sustainability analysis of organic fraction of municipal solid waste conversion techniques for efficient resource recovery in India through case studies

Worldwide solid waste generation is nearly 1.3 billion tonnes/year, whereas in India 62 million tonnes of solid waste is generated per year by 377 million urban people. The increasing amount of solid waste in India, nearly 50% of which is organic matter, is the major concern for treatment and waste management. Several technologies are already in practice for the treatment of organic fraction of municipal solid waste (OFMSW) in India. It is important to assess the sustainability of these processes. In this study, the existing OFMSW technologies in India were examined. Case-study approach was taken for this purpose along with some published secondary reports. It was found that the selection of technology quite depends on the composition of the OFMSW. Food waste rich fractions are recommended for biomethanation, whereas the fractions rich in market waste and household waste are suitable for composting. Fractions rich in lignin and lignocellulosic materials are suitable for pyrolysis and gasification, whereas the rejects are to be sent for RDF preparation. Based on the findings, a sustainable framework has also been proposed, implementation of which may result in better waste management.     

Cold plasma technology: advanced and sustainable approach for wastewater treatment

Environmental Science and Pollution Research - Cold plasma has been a potent energy-efficient and eco-friendly advanced oxidation technology which has gained attention in recent decades as a...     

Evaluation of remediation process with soapberry derived saponin for removal of heavy metals from contaminated soils in Hai-Pu, Taiwan

The use of a biodegradable natural plant-based surfactant extracted from soapberry is proposed for the remediation of Ni, Cr and Mn from industrial soil site in Hai-Pu, Taiwan. Batch experiments were performed under variation of fundamental factors (saponin concentration, pH, and incubation time) for metal remediation. Removal of Ni and Mn were increased with increasing saponin concentration (0.015-0.150 g/L), whereas the removal of Cr was increased upto 0.075 g/L saponin. The Ni, Cr and Mn were removed significantly (p ≤q 0.05) at near to the neutral and slightly acidic (pH 5 to 8) conditions. Removal efficiency of Ni (99%) from the soil was found to be greater than that of Cr (73%) or Mn (25%) in the presence of saponin at a concentration of 0.150 g/L at pH 5. The removal percentage increased with incubation time where the removal of Ni was faster than that of Cr and Mn. The result indicates the feasibility of eco-friendly removal of heavy metal (Ni, Cr and Mn) from industrial soil by soil washing process in presence of plant derived saponin.     

Contribution of anthropogenic aerosols in direct radiative forcing and atmospheric heating rate over Delhi in the Indo-Gangetic Basin

Introduction  

The present work is aimed to understand direct radiation effects due to aerosols over Delhi in the Indo-Gangetic Basin (IGB) region, using detailed chemical analysis of surface measured aerosols during the year 2007.