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排序方式: 共有170条查询结果,搜索用时 15 毫秒
11.
Theoretical study of the dechlorination reaction pathways of octachlorodibenzo-p-dioxin 总被引:1,自引:0,他引:1
The dechlorination reaction pathways of 1,2,3,4,6,7,8,9-octachlorodibenzo-p-dioxin (OCDD) by the hydrogen atom are investigated by the density-functional theory B3PW91 method. The dechlorination reactions have large exothermicity and small activation energies. The activation energies (approximately 5 kcal/mol) of the sigma-complex formation due to the hydrogen addition are lower than those (approximately 9 kcal/mol) of the direct chlorine abstraction. It is suggested that the sigma-complex plays an important role in the reactions, although it has scarcely been shown in previous studies of the dechlorination of dioxins. The sigma-complex formation is favored at low temperatures and the chlorine abstraction is favored at high temperatures. Furthermore, it is found that the lateral positions have a marginal preference over the longitudinal positions. The dechlorination of OCDD by the hydrogen atom is thus not likely to result in a dominant formation of the laterally substituted toxic congeners. 相似文献
12.
Takashi Yamamoto Atsushi Ohara Yukio Noma Katsushi Nishizawa Akio Yasuhara Shin-ichi Sakai 《Journal of Material Cycles and Waste Management》2007,9(2):188-193
The photodegradation of tetraphenyltin (TePT) contained in polychlorinated biphenyl (PCB)-based transformer oil simulants
by ultraviolet (UV) irradiation in alkaline 2-propanol solutions was examined. In the absence of PCBs, the TePT level fell
to below 1% of the initial concentration within 30 min. In the absence of both PCBs and an alkali, the concentrations of tri-,
di-, and monophenyltins initially increased to a few milligrams per liter, and then reduced to below the detection limits
within 90 min. The addition of an alkali to the reaction solution slightly accelerated the photodecomposition of TePT. The
decomposition of other phenyltins (PTs) was also accelerated. When PCBs with concentrations of approximately 80 times the
initial TePT concentration were added, only a small fraction of the TePT decomposed within 100 min. Moreover, the levels of
PTs did not change during irradiation. TePT and other PTs did decompose when the level of PCBs was reduced to the same concentration
as that of TePT; however, the decomposition rates were slower than those in the absence of PCBs. In the actual treatment process,
TePT and other PTs in PCB-based transformer oil are decomposed by catalytic reduction, which is used after UV irradiation.
Therefore, in the actual treatment of PCB-based transformer oil wastes, pollution due to PTs can be prevented. 相似文献
13.
Teruo Yamamoto 《Journal of the American Water Resources Association》1974,10(3):531-546
ABSTRACT: An extensive hammer seismic refraction survey was carried out in three contiguous watersheds (217, 89, and 190 acres) on a laccolith near Sturgis, South Dakota to test its utility in rugged mountain terrain. Isopachs (lines connecting points of equal mantle thickness), area-elevation curves (hypsometry), and structure contours were used together with drill cores, petrography, hydrographs, and soil information to interpret the nature and role of porous mantle in the waterflow behavior of the watersheds. Refraction profiles produced only one geologically meaningful seismic contrast within the loccolith. Drill cores indicated a shallow stony profile on a sheeted horizon terminating on isotropic crystalline rock impervious except for tight joints. Means of refraction and core interpretations were not statistically different. Apparent seismic discontinuities deeper within the bedrock lacked geological identity. Storm hydrographs and water yields are better related to soil type differences and porous mantle distribution than to average porous mantle depth. On the other hand, slope of flow-duration curves correlate with average porous mantle depth. Porous mantle isopachs also indicate that measured flow from each basin is total area flow. Thus, porous mantle isopachs and hypsometry, and soil type delineation are complimentary in our interpretation of watershed behavior. 相似文献
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Inoue M Tanaka K Watanabe S Kofuji H Yamamoto M Komura K 《Journal of environmental radioactivity》2006,89(2):138-149
In this study, low-background gamma-spectrometry was used to determine the (228)Ra/(226)Ra ratio of 131 coastal water samples from various environments around Honshu Island, Japan (mainly around Noto Peninsula) at 1-3 month intervals from April 2003 until September 2005. Spatial variation in (228)Ra/(226)Ra ratios was also assessed by analyzing 34 coastal water samples from five areas within the Sea of Japan during May and June 2004. The (228)Ra/(226)Ra ratio of coastal water from all sites around Noto Peninsula shows seasonal variation, with minimum values during summer ((228)Ra/(226)Ra=0.7) and maximum values during autumn-winter ((228)Ra/(226)Ra=1.7-2). This seasonal variation is similar to that recorded for coastal water between Tsushima Strait and Noto Peninsula. The measured lateral variation in (228)Ra/(226)Ra ratios within coastal water between Tsushima Strait and Noto Peninsula is only minor (0.5-0.7; May-June 2004). Coastal waters from two other sites (Pacific shore and Tsugaru Strait, north Honshu) show no clear seasonal variation in (228)Ra/(226)Ra ratio. These measured variations in (228)Ra/(226)Ra ratio, especially the temporal variations, have important implications for seasonal changes in patterns of coastal water circulation within the Sea of Japan. 相似文献
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Rosales-Hurtado Miyanou Duvauchelle Valentin Bénimélis David Ogawa-Okada Maya Yamamoto Naofumi Meffre Patrick Szurmant Hendrik Benfodda Zohra 《Environmental Chemistry Letters》2023,21(1):47-53
Environmental Chemistry Letters - The rise of bacterial resistance to common clinical antibiotics is calling for alternative techniques to synthesize antibacterial drugs with high biodegradability.... 相似文献
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