Mortality due to haematological cancer in cities close to petroleum refineries in Spain

Controversy exists as to whether working or living in the vicinity of a petroleum refinery (RF) increases the risk of haematological cancer (HC). The European Pollutant Release and Transfer Register obliges petroleum refineries to notify their emissions of toxic substances which include carcinogenic substances. Our objective is to determine if living in the proximity of an RF is associated with a greater risk of mortality due to HC in the census tracts (CTs) of the Spanish cities of Bilbao, Cartagena, Castellón, La Coruña, Huelva, and Santa Cruz de Tenerife. This is an ecological study of mortality in the years 1996–2007 which includes 968 CTs with 1,263,371 inhabitants. Exposure has been measured as the distance from the centroid of each CT to the RF. The Besag–York–Mollié autoregressive spatial model has been fitted by R-INLA to estimate the relative risk (RR) and 95 % credible intervals (95 % CrI) for distance in quintiles. The most distant quintile has been taken as the reference. A total of 2,574 persons died of HC. The distances from the CTs to RFs ranged from 0.5 to 22.5 km (median?=?7.6 km). All of the RRs for the quintiles of distances in Huelva were greater than 1. Statistically significant excess risk was shown in Cartagena in the nearest CT (1.8 to 6.8 km; RR?=?1.43, 95 % CrI 1.02 to 2.02). Radial effects have not been detected between the CT of residence and the petroleum RF in mortality due to HC in any of the cities.     

Precious metals and rare earth elements in municipal solid waste – Sources and fate in a Swiss incineration plant

In Switzerland many kinds of waste, e.g. paper, metals, electrical and electronic equipment are separately collected and recycled to a large extent. The residual amount of municipal solid waste (MSW) has to be thermally treated before final disposal. Efforts to recover valuable metals from incineration residues have recently increased. However, the resource potential of critical elements in the waste input (sources) and their partitioning into recyclable fractions and residues (fate) is unknown. Therefore, a substance flow analysis (SFA) for 31 elements including precious metals (Au, Ag), platinum metal group elements (Pt, Rh) and rare earth elements (La, Ce, etc.) has been conducted in a solid waste incinerator (SWI) with a state-of-the-art bottom ash treatment according to the Thermo-Re® concept. The SFA allowed the determination of the element partitioning in the SWI, as well as the elemental composition of the MSW by indirect analysis. The results show that the waste-input contains substantial quantities of precious metals, such as 0.4 ± 0.2 mg/kg Au and 5.3 ± 0.7 mg/kg Ag. Many of the valuable substances, such as Au and Ag are enriched in specific outputs (e.g. non-ferrous metal fractions) and are therefore recoverable. As the precious metal content in MSW is expected to rise due to its increasing application in complex consumer products, the results of this study are essential for the improvement of resource recovery in the Thermo-Re® process.     

Effects of site-specific climatic conditions on the radial growth of the lichen biomonitor <Emphasis Type="Italic">Xanthoria parietina</Emphasis>

The protocols commonly applied in surveys with lichens as biomonitors of airborne trace elements require analyses of samples derived from thalli or parts of thalli grown in the last year before sampling, under the postulation that samples of the same size are of the same age. Unfortunately, the influence of ecological site-specific factors on lichen growth is still largely ignored, so that samples of the same size collected in environmentally and climatically diverse sites might actually differ in age. This work aims at quantifying the influence of climatic conditions on the radial growth rates (RaGRs) of Xanthoria parietina, one of the most popular lichen biomonitors. RaGR was monitored in seven populations distributed along an altitudinal transect of 30 km in the Classical Karst (NE Italy), from 20 to 500 m above sea level. For c. 17 months, lobe growth was measured seasonally with a digital calliper, and site-specific climatic variables were monitored by means of thermo-hygrometric sensors and implemented by meteorological data. Finally, the lobe growth of X. parietina was modelled as a function of 18 environmental variables. Results revealed that thalli of relatively dry sites had significantly lower seasonal RaGR with respect to moister ones. Considering that cumulative precipitations were equally distributed along the transect, it was concluded that RaGR of X. parietina is affected negatively by high air temperatures and positively by high relative humidity. The importance of RaGR variation in lichen bioaccumulation studies is critically discussed.     

Orientation of sandhoppers at different points along a dynamic shoreline in southern Tuscany

Orientation experiments were carried out on Talitrus saltator (Crustacea Amphipoda) at four points along 3 km on a dynamic sandy beach inside the Maremma Regional Park (Grosseto, Italy) to highlight behavioural variation related to distance from a river mouth, to erosion or accretion of shoreline, and to human trampling on the beach. Tests were performed using circular transparent Plexiglas arenas, contemporaneously at the four points. Replicates were made in 2 different months (September 2002 and May 2003), on 2–3 successive days, in the morning and afternoon. The distributions of the angles of orientation were compared for the different points and seasons, and multiple regression analysis was performed to test the effects of environmental and intrinsic variables on orientation. Sandhoppers showed the highest scatter at the eroded shoreline, intermediate scatter at the accreting beach most distant from the river mouth, and consistent orientation seaward at the least disturbed point. Orientation of sandhoppers was significantly affected by season, global radiation, time of day, distance from the river mouth, and human trampling. Sex and air humidity were of minor significance in the multiple regression model. The results, on the one hand, confirm plasticity in orientation of sandhoppers living on a dynamic shoreline, and on the other hand, show that variation in orientation could potentially be used as a bioindicator of shoreline changes.Communicated by R. Cattanevo-Vietti, Genova     

Particle emissions of a railway line determined by detailed single particle analysis

The goal of this study was to identify and quantify particles emitted from railway traffic. For that purpose PM10 samples were collected near a busy railway line using a wind direction and speed controlled sampling equipment consisting of five devices. Measurements taken perpendicular to the railway lines at 10, 36 and 120 m distance enable an identification and separation of particles caused by the railway traffic from background particles. Morphology and chemistry of more than 11,000 particles were analysed by computer controlled scanning electron microscopy (CCSEM). Based on chemical composition five particle classes are defined and assigned to their sources. The mass of the individual particles is determined by multiplying their volumes, calculated based on their morphology with a density assigned specifically to each particle class. The density of the particle classes is derived from their chemical composition. To estimate the PM10 contributions of the railway lines, the mass of PM10 at 120 m (background, not influenced by the railway lines) is subtracted from the mass of PM10 at 10 m. The emissions of the railway lines are dominated by ‘iron’ particles, which contribute 2.9 μg m⁻³ or 67% to the railway related PM10. In addition, ‘aluminium’ and ‘calcium’ particles contribute also to the railway related PM10 (1.0 μg m⁻³ or 23% for the ‘aluminium’ and 0.4 μg m⁻³ or 10% for the ‘calcium’ particles). These particles are assigned to abrasion of the gravel bed and re-suspension of mineral dust.Long-term gravimetric results of the contribution of iron to the mass of railway related PM10 from a study performed earlier at the same site are in good agreement with the data presented in this study.     

Experimental study and modeling of the transfer of zinc in a low reactive sand column in the presence of acetate

Nowadays, it is necessary to understand and identify the reactions governing the fate of heavy metals introduced into the environment with low complexing organic compounds, particularly when they are transferred through soils in urban areas. In this work the concomitant influence of pH and acetate on the fate of zinc on siliceous sand was studied in batch and non-saturated column experiments. Total zinc concentrations varied between 2 and 20 mg/l, and total acetate concentrations were fixed at 22, 72, 132, and 223 mM to obtain solution pHs of 4, 5, 6 and 7, respectively. Natural sand (diameter, 0.3-2 mm), mainly constituted of silica, was used. In batch adsorption experiments, zinc adsorption is insignificant at pH 4, low and linear at pH 5, and increasingly nonlinear, of the Langmuir type, at pH 6 and 7 indicating near-saturation conditions of surface sites at these high pH values. In column experiments, Zn retardation increases and the maximum outlet concentration of Zn decreases with rising pH and acetate concentrations. Previous column tracer experiments revealed the occurrence of regionalized water transport in the column. Modeling these data was based on a non-electrostatic approach. Batch and column data modeling was based on the PHREEQC code that allows concomitant resolution of chemical speciation and regionalized water transport. The speciation calculation indicates that the ZnAcetate+ species is the dominant Zn species in the solutions used. Batch experimental curves are correctly modeled assuming the formation of the three surface species triple bond SiOZn+, triple bond SiOH-Zn Acetate+ and triple bond SiO-Zn(Acetate)2-. The column data could be adequately modeled assuming a two-region water transport and the formation of the same three species with the same thermodynamic constants determined in the batch experiments. The hypothesis of the modeling leads to a slight overestimation of the quantities of zinc eluted (10%) at pH 6 and 7, mostly in the desorption phase. These results show that the methodology used facilitates the correct modeling of both batch and transport experiments and formulation of the hypothesis on the interactions between the low reactive sand and a complex solution.     

A permutation-based combination of sign tests for assessing habitat selection

The analysis of habitat selection in radio-tagged animals is approached by comparing the portions of use against the portions of availability observed for each habitat type. Since data are linearly dependent with singular variance-covariance matrices, standard multivariate statistical tests cannot be applied. To bypass the problem, compositional data analysis is customarily performed via log-ratio transform of sample observations. The procedure is criticized in this paper, emphasizing the several drawbacks which may arise from the use of compositional analysis. An alternative nonparametric solution is proposed in the framework of multiple testing. The habitat use is assessed separately for each habitat type by means of the sign test performed on the original observations. The resulting p values are combined in an overall test statistic whose significance is determined permuting sample observations. The theoretical findings of the paper are checked by simulation studies. Applications to case studies previously considered in literature are discussed.     

Influence of climate on grape production and wine quality in the Rías Baixas, north-western Spain

Climate exerts an important role on grape production and wine quality. For one of the main areas protected under the denomination of origin Rías Baixas, in Galicia, Spain, we explore the relationships among grape production, wine quality, rainfall and temperature for the period 1987–2005. The influence of climatic variability was analysed in terms of the relationship between the productivity of the grapevines and the main meteorological teleconnection patterns affecting the North Atlantic region. We also investigate the daily variation in atmospheric circulation through the study of the influence of weather types derived using an automated daily classification. We consider three bioclimatic indices for viticultural zoning, Winkler and Huglin, and the hydrothermic index of Branas, Bernon and Levadoux. While significant trends were identified in the Winkler and Huglin indices, there were no significant trends in the Branas, Bernon and Levadoux index, for the period 1958–2005. For the coming decades, using the scenario A1B evaluated by the regional climate models used in the ENSEMBLES project, the positive trends of Winkler and Huglin indices continue, while Branas, Bernon and Levadoux implies a negative trend. In all cases, these trends induce significant changes in the viticulture of the region.