反相乳液聚合制备阳离子聚丙烯酰胺及其絮凝性能评价

研究了单体浓度、单体配比、反应温度、引发剂用量等因素对所制备的阳离子聚丙烯酰胺特性粘度、转化率、阳离子度的影响,并对产品的污水絮凝性能进行了评价。较佳的制备条件为:单体浓度为45%,单体配比为7∶3,引发剂用量m(引发剂)/m(单体)为0.5%,引发温度为45℃。用红外光谱对共聚物进行了结构表征,结果表明聚合物中有六元氮杂环的存在,达到预定要求。对共聚物进行了油田污水絮凝性能评价,研究表明单独使用自制阳离子聚丙烯酰胺(CPAM)时浊度的去除率为86.22%,COD去除率为87.95%,与聚合氯化铝复配使用时浊度去除率提高到92.91%,COD去除率提高到92.68%。     

Associations of residential greenness with obesity and BMI level among Chinese rural population: findings from the Henan Rural Cohort Study

In recent years, increasing evidence supports the notion that obesity risk is affected by residential greenness. However, limited studies have been established in low- and middle-income countries, especially in China. The study aimed to evaluate the associations of residential greenness with obesity and body mass index (BMI) level in Chinese rural-dwelling adults. A total of 39,259 adults from the Henan Rural Cohort Study (HRCS) were included in the analyses. According to the guideline for prevention and control of overweight and obesity in Chinese adults, obesity was defined as BMI?≥?28 kg/m². Residential greenness was measured by satellite-based normalized difference vegetation index (NDVI) and enhanced vegetation index (EVI). Generalized linear mixed models were used to study the associations between exposure to residential greenness with obesity and BMI level. Higher residential greenness was significantly correlated with lower odds of obesity and BMI level. For example, in the full-adjusted analyses, an interquartile range (IQR) increase in EVI_500-m was linked with reduced odds of obesity (OR?=?0.77, 95%CI 0.72–0.82) and BMI level (β?=????0.41 kg/m², 95%CI???0.48 to???0.33 kg/m²). Mediation analyses showed air pollution and physical activity could be potential mediators in these associations. Besides, we found that the association of NDVI_500-m with BMI was stronger in females and low-income populations. Higher residential greenness was associated with a lower prevalence of obesity and BMI level, particularly among females and the low-income population. These relationships were partially mediated by reducing air pollution and increasing physical activity.

     

矮塔斜拉桥单侧断索和双侧对称断索影响效应分析

为研究断索现象对矮塔斜拉桥力学性能和安全性的影响，以浙江某实际工程为背景，使用Midas/Civil建立有限元模型，研究单侧单束断索和双侧对称断索两种工况分别对斜拉索索力、塔顶DX位移和主梁跨中弯矩的影响。研究发现：单侧断索对断索侧索力和跨中弯矩、主塔塔顶DX位移的影响较大；双侧对称断索对主塔两侧索力和跨中弯矩影响趋势相同，对边塔塔顶DX位移影响较大；最外侧斜拉索断裂对3个力学指标的影响均为最大，故实际运营中应重视对外侧斜拉索的保护。