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51.
This study examined the time series pattern of employment growth and stability in Fort Worth, Texas taking into account the March 28, 2000 tornado. The tornado is treated econometrically as an intervention and both the mean and conditional variance of employment growth were estimated. Overall, this regional labor market experienced a decline in the employment growth rate following the tornado. Among the sectors that exhibited differences in employment dynamics between the pre- and post-tornado periods, the mining sector experienced a significant increase in employment growth following the tornado while the service andwholesale, retail trade sectors experienced significant declines in employment growth in the post-tornado period. The manufacturing, service, and wholesale, retail trade sectors were characterized by greater stability (i.e., a lower level of employment growth volatility) in the post-tornado period than in the pre-tornado period. Interestingly, in several sectors, no differences in the time series dynamics of employment growth were detected between the pre- and post-tornado periods. These sectors included construction, finance, insurance, real estate, government, and transportation and public utilities.  相似文献   
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The Arctic marine ecosystem contains multiple elements that present alternative states. The most obvious of which is an Arctic Ocean largely covered by an ice sheet in summer versus one largely devoid of such cover. Ecosystems under pressure typically shift between such alternative states in an abrupt, rather than smooth manner, with the level of forcing required for shifting this status termed threshold or tipping point. Loss of Arctic ice due to anthropogenic climate change is accelerating, with the extent of Arctic sea ice displaying increased variance at present, a leading indicator of the proximity of a possible tipping point. Reduced ice extent is expected, in turn, to trigger a number of additional tipping elements, physical, chemical, and biological, in motion, with potentially large impacts on the Arctic marine ecosystem.  相似文献   
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A 168-day period field study, carried out in Sisimiut, Greenland, assessed the potential to enhance soil remediation with the surplus heating from an incineration facility. This approach searches a feasible ex situ remediation process that could be extended throughout the year with low costs. Individual and synergistic effects of biostimulation were also tested, in parallel. An interim evaluation at the end of the first 42 days showed that biostimulation and active heating, as separate treatments, enhanced petroleum hydrocarbon (PHC) removal compared to natural attenuation. The coupling of both technologies was even more effective, corroborating the benefits of both techniques in a remediation strategy. However, between day 42 and day 168, there was an opposite remediation trend with all treatments suggesting a stabilization except for natural attenuation, where PHC values continued to decrease. This enforces the “self-purification” capacity of the system, even at low temperatures. Coupling biostimulation with active heating was the best approach for PHC removal, namely for a short period of time (42 days). The proposed remediation scheme can be considered a reliable option for faster PHC removal with low maintenance and using “waste heating” from an incineration facility.  相似文献   
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Building on the broaden‐and‐build theory and research on the negativity bias, this study examines how trait affectivity, as a stable predisposition predicting the pattern of emotional responding, shapes newcomers' perceptions of supervisor support and experience of organizational commitment. Using latent growth modeling and data collected at four points in time from newcomers (N = 158), we found the initial level of perceived supervisor support to mediate a negative relationship between negative affectivity and the level of commitment. Moreover, although newcomers experienced a general decrease in perceived supervisor support and a related decrease in commitment, those with high positive affectivity experienced a weaker decrease in perceived supervisor support, which led to a weaker decrease in commitment. Incidentally, positive affectivity was also positively related to the initial level of commitment. Two post hoc studies indicated that positive and negative affectivity exerted their effects controlling for state affect and replicated the relationship between change in perceived support and commitment. We discuss how these findings inform our understanding of trait affectivity's influence on newcomers' work attitudes.  相似文献   
55.
The farming community is today faced with requests by various interest groups to implement environmental management systems (EMS). The series of items shows principle theoretical questions of the method and the advantages of EMS (part I and II), presents the practical outcome (part III) and give a recommendation for potential users of EMS in agricultural systems (part IV). The study conducted outlines the method of the implementing an EMS according to the Environmental Management and Audit System (EMAS) and ISO 14001. Further advantages and disadvantages for the agricultural industry are addressed. Even though terms such as site can not easily be defined or problems with open material cycles and structural particularity of agricultural farms there appears to be a benefit to implement. The transparency and documentation of the material flow as well as the economical benefits of an optimized organization count towards the EMS. Further EMS can be a means to strengthen the argumentative position for example with the public, authorities, banks or insurance. This concurs with minimizing company liabilities and obtaining governmental privileges (deregulation).  相似文献   
56.
Humic substances are natural compounds abundantly present in the environment. They play a significant role in the natural attenuation of pollution in surface water due to their capacity to generate reactive species upon solar light excitation. Finding physico chemical parameters related to this property would be of a great help in the prediction studies of the organic pollutants fate. In this work, we investigated relationships between the ability of the humic substances to produce singlet oxygen and their fluorescence properties. For this, a series of sixteen humic acids, fulvic acids, and water-extractable organic matter from soils were studied. The steady-state singlet oxygen concentrations in the irradiated humic substances solutions were measured by monitoring the loss of furfuryl alcohol added as a singlet oxygen scavenger. The emission spectra of the sixteen samples were also recorded. Values of the steady-state singlet oxygen concentrations and the emission intensities showed significant variations among the humic samples and a parallel increase. Thus, here we demonstrate that the rate of singlet oxygen production and the emission intensity of the humic samples are correlated, the best correlation being obtained for emission wavelengths between 500 and 580 nm. This correlation which was never reported until now can be used to estimate the singlet oxygen-production capacity of the humic substances based on their fluorescent properties.  相似文献   
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Air quality impacts of volatile organic compound (VOC) and nitrogen oxide (NOx) emissions from major sources over the northwestern United States are simulated. The comprehensive nested modeling system comprises three models: Community Multiscale Air Quality (CMAQ), Weather Research and Forecasting (WRF), and Sparse Matrix Operator Kernel Emissions (SMOKE). In addition, the decoupled direct method in three dimensions (DDM-3D) is used to determine the sensitivities of pollutant concentrations to changes in precursor emissions during a severe smog episode in July of 2006. The average simulated 8-hr daily maximum O3 concentration is 48.9 ppb, with 1-hr O3 maxima up to 106 ppb (40 km southeast of Seattle). The average simulated PM2.5 (particulate matter with an aerodynamic diameter <2.5 μm) concentration at the measurement sites is 9.06 μg m?3, which is in good agreement with the observed concentration (8.06 μg m?3). In urban areas (i.e., Seattle, Vancouver, etc.), the model predicts that, on average, a reduction of NOx emissions is simulated to lead to an increase in average 8-hr daily maximum O3 concentrations, and will be most prominent in Seattle (where the greatest sensitivity is??0.2 ppb per % change of mobile sources). On the other hand, decreasing NOx emissions is simulated to decrease the 8-hr maximum O3 concentrations in remote and forested areas. Decreased NOx emissions are simulated to slightly increase PM2.5 in major urban areas. In urban areas, a decrease in VOC emissions will result in a decrease of 8-hr maximum O3 concentrations. The impact of decreased VOC emissions from biogenic, mobile, nonroad, and area sources on average 8-hr daily maximum O3 concentrations is up to 0.05 ppb decrease per % of emission change, each. Decreased emissions of VOCs decrease average PM2.5 concentrations in the entire modeling domain. In major cities, PM2.5 concentrations are more sensitive to emissions of VOCs from biogenic sources than other sources of VOCs. These results can be used to interpret the effectiveness of VOC or NOx controls over pollutant concentrations, especially for localities that may exceed National Ambient Air Quality Standards (NAAQS).

Implications: The effect of NOx and VOC controls on ozone and PM2.5 concentrations in the northwestern United States is examined using the decoupled direct method in three dimensions (DDM-3D) in a state-of-the-art three-dimensional chemical transport model (CMAQ). NOx controls are predicted to increase PM2.5 and ozone in major urban areas and decrease ozone in more remote and forested areas. VOC reductions are helpful in reducing ozone and PM2.5 concentrations in urban areas. Biogenic VOC sources have the largest impact on O3 and PM2.5 concentrations.  相似文献   
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