Thyroid ultrasound volume, structure and function after long-term high exposure of large population to polychlorinated biphenyls, pesticides and dioxin

We examined 2,046 adults (834 males and 1,212 females aged 20-75 years) from polluted district in East Slovakia (POLL) and two neighboring upstream and upwind located districts of background pollution (BCGR). By ultrasound we estimated the thyroid volume (ThV), hypoechogenicity (HYE), nodules and cysts. Serum levels of thyrotropin (TSH), thyroperoxidase antibodies (TPOab) and thyroglobulin were estimated by electrochemiluminiscent assay and these of 15 PCB congeners, p,p'-DDE, p,p'-DDT, hexachlorobenzene (HCB) and hexachlorocyclohexane by high-resolution gas chromatography. In 320 subjects also selected hydroxylated and methylsulfonated PCB metabolites, polychlorinated dibenzo-dioxins (PCDDs), -furans (PCDFs), five dioxin-like coplanar and eight mono-ortho PCB congeners were estimated. Urinary iodine was measured by automatic microplate method. Reciprocal positive association was found between three major POPs (PCBs, DDE and HCB), the levels of these and also PCDDs plus PCDFs in polluted area being considerably higher than in background pollution area. ThV in groups of males and females from POLL with high PCBs level was significantly higher (p<0.001 by t-test) then in age and sex matched groups from BCGR with low PCBs level. In 1,048 males and females aged <60 years with serum PCBs level >1,000 ng g(-1) lipid (median=1,756 ng g(-1)) a significant effect of age on ThV was found (p<0.01 by ANOVA), while in 921 respective subjects with PCBs level <1,000 ng g(-1) (median=661 ng g(-1)) it was not. These findings supported the view on the additional effect of PCBs on ThV other than that of age. Since the urinary iodine in both districts showed optimal range, any interfering effect of unsatisfactory iodine intake on ThV may be excluded. The frequency of autoimmune thyroiditis signs such as HYE, increased serum level of TPOab and TSH resulting in subclinical or overt thyroid hypofunction was positively associated with sex, age and organochlorine levels. The increase of such frequency in males with POPs levels was much more abrupt than that in females. No considerable differences in the frequency of thyroid nodules as related to PCBs level were found.     

Using phytoremediation technologies to upgrade waste water treatment in Europe

Goal, Scope and Background One of the burning problems of our industrial society is the high consumption of water and the high demand for clean drinking water. Numerous approaches have been taken to reduce water consumption, but in the long run it seems only possible to recycle waste water into high quality water. It seems timely to discuss alternative water remediation technologies that are fit for industrial as well as less developed countries to ensure a high quality of drinking water throughout Europe. Main Features The present paper discusses a range of phytoremediation technologies to be applied in a modular approach to integrate and improve the performance of existing wastewater treatment, especially towards the emerging micro pollutants, i.e. organic chemicals and pharmaceuticals. This topic is of global relevance for the EU. Results Existing technologies for waste water treatment do not sufficiently address increasing pollution situation, especially with the growing use of organic pollutants in the private household and health sector. Although some crude chemical approaches exist, such as advanced oxidation steps, most waste water treatment plants will not be able to adopt them. The same is true for membrane technologies. Discussion Incredible progress has been made during recent years, thus providing us with membranes of longevity and stability and, at the same time, high filtration capacity. However, these systems are expensive and delicate in operation, so that the majority of communities will not be able to afford them. Combinations of different phytoremediation technologies seem to be most promising to solve this burning problem. Conclusions To quantify the occurrence and the distribution of micropollutants, to evaluate their effects, and to prevent them from passing through wastewater collection and treatment systems into rivers, lakes and ground water bodies represents an urgent task for applied environmental sciences in the coming years. Recommendations Public acceptance of green technologies is generally higher than that of industrial processes. The EU should stimulate research to upgrade existing waste water treatment by implementing phytoremediation modules and demonstrating their reliability to the public.     

A novel method for reducing acid mine drainage using green liquor dregs

When exposed to the weather, sulfidic minerals release sulfuric acid, metals and metalloids. This leachate can devastate nearby ecosystems for centuries. This article reports a novel barrier system based on green liquor dregs that reduces acid generation, is inexpensive, and is practical for implementation at operational mines. Two waste rock piles were constructed. One pile was left open to the atmosphere, and the other was sealed with green liquor dregs and partially capped with a polyethylene liner. This test was designed in collaboration with personnel from Boliden Mineral AB, a Swedish mining company in order to ensure that the results would be practical to implement at an operational mine. Leachate flow and chemistry were monitored in both piles over a period of 12 months. Effluent volume was 40 % lower in the test pile, while thirteen of the twenty elements assessed showed average concentrations that were 50 % lower in the test pile than in the control pile. For the most environmentally toxic elements As, Cd, Pb and Hg, reductions were even more significant, ranging between 67 and 87 %. These positive results are hypothesized to be primarily due to the chemical and physical characteristics of the green liquor dregs. The novelty of this result is that it is the first barrier system that fulfills the multiple needs of the Swedish mining industry: It is effective in reducing acid mine drainage while remaining both economical and practical. No other barrier system meets these requirements.     

Ecological Impact of Economic Development on Sardinian Herpetofauna

The link between ecology and economies is manifest over the world as a result of long-term processes. But because these processes are long term, it is hard to prove the link. On Sardinia serious economic development was late to arrive, having occurred only over the last few decades. As a case study, research was carried out for 10 years on the state of nature as well as the economic growth in one of the least developed areas abutting the Gulf of Orosei on the east coast. Based on research and lasting attention to political affairs concerning the project, we formulate general recommendations for the area. In 1995, the Italian Government will be asked by the European Government to undertake serious steps to save endemics (especially herpetofauna) of Europe's last pristine areas.     

Costs of food waste along the value chain: Evidence from South Africa

In a previous paper (Nahman et al., 2012), the authors estimated the costs of household food waste in South Africa, based on the market value of the wasted food (edible portion only), as well as the costs of disposal to landfill. In this paper, we extend the analysis by assessing the costs of edible food waste throughout the entire food value chain, from agricultural production through to consumption at the household level. First, food waste at each stage of the value chain was quantified in physical units (tonnes) for various food commodity groups. Then, weighted average representative prices (per tonne) were estimated for each commodity group at each stage of the value chain. Finally, prices were multiplied by quantities, and the resulting values were aggregated across the value chain for all commodity groups. In this way, the total cost of food waste across the food value chain in South Africa was estimated at R61.5 billion per annum (approximately US$7.7 billion); equivalent to 2.1% of South Africa’s annual gross domestic product. The bulk of this cost arises from the processing and distribution stages of the fruit and vegetable value chain, as well as the agricultural production and distribution stages of the meat value chain. These results therefore provide an indication of where interventions aimed at reducing food waste should be targeted.     

Real-time monitoring of water quality using fish and crayfish as bio-indicators: a review

Water quality monitoring using fish and crayfish as bio-indicators requires an understanding of the state of pollution of waters, choice of bio-indicators, physiological and behavioral endpoints of fish and crayfish, and principles of the methodology and their potential applications. Here, we discuss telemetry, acoustic monitoring, vision-based monitoring, measures of ventilatory activity, electrocardiography, and fiber-optic plethysmography. Assessment of water quality must be based, not only on physicochemical characteristics of the current environment as determined by chemical analyses, but also on observations of the physiology and behavior of its inhabitants. Real-time biomonitoring is suggested as the most reliable method, since it incorporates living organisms into the system to serve as biosensors. The potential application of the methods discussed includes use at water treatment plants and water supply stations for prevention of hazardous toxicological events, and, for aquaculture, in ponds, lakes, and aquariums for monitoring growth, population size, and behavior traits.