Toxicity,degradation and analysis of the herbicide atrazine

Excessive use of pesticides and herbicides is a major environmental and health concern worldwide. Atrazine, a synthetic triazine herbicide commonly used to control grassy and broadleaf weeds in crops, is a major pollutant of soil and water ecosystems. Atrazine modifies the growth, enzymatic processes and photosynthesis in plants. Atrazine exerts mutagenicity, genotoxicity, defective cell division, erroneous lipid synthesis and hormonal imbalance in aquatic fauna and nontarget animals. It has threatened the sustainability of agricultural soils due to detrimental effects on resident soil microbial communities. The detection of atrazine in soil and reservoir sites is usually made by IR spectroscopy, ELISA, HPLC, UPLC, LC–MS and GC–MS techniques. HPLC/LC–MS and GC–MS techniques are considered the most effective tools, having detection limits up to ppb levels in different matrices. Biodegradation of atrazine by microbial species is increasingly being recognized as an eco-friendly, economically feasible and sustainable bioremediation strategy. This review presents the toxicity, analytical techniques, abiotic degradation and microbial metabolism of atrazine.     

Are Investments in Groundwater Irrigation Profitable? A Case of Rice Farms from South India1

Varghese, Shalet Korattukudy, Jeroen Buysse, Aymen Frija, Stijn Speelman, and Guido Van Huylenbroeck, 2012. Are Investments in Groundwater Irrigation Profitable? A Case of Rice Farms from South India. Journal of the American Water Resources Association (JAWRA) 1‐15. DOI: 10.1111/j.1752‐1688.2012.00690.x Abstract: This article examines the profitability of cultivating double rice under bore well irrigation, given the cumulative interference of and reduced life span of wells, and thus increases the cost of groundwater extraction and use. The overexploitation of groundwater is a common stock problem and the cultivation of water intensive crops, such as rice, further exacerbates the overdraft of groundwater. Under these circumstances, we quantify the marginal benefit of irrigation investments in rice farming by estimating the probability of having a double rice crop as a function of the investment made in wells. Using this information, we explore profit maximization behavior of farms with a mathematical programming model to derive individual economic optima of irrigation costs. The results demonstrate that the ongoing overexploitation of groundwater, and its use to cultivate an economically inefficient crop, such as rice, has resulted in low profitability at farm level. A sensitivity analysis found that even when the investment in irrigation wells is reduced by 70%, small farms are still not economically efficient, thereby confirming the Tragedy of the Commons. Raising awareness amongst farmers with regard to the economics of irrigation would facilitate the participatory implementation of control mechanisms to regulate groundwater extraction.     

Implications of endocrine-disrupting chemicals on polycystic ovarian syndrome: A comprehensive review

Environmental Science and Pollution Research - Polycystic ovarian syndrome (PCOS) is a complex multifactorial disorder of unknown pathogenesis in which genetic and environmental factors contribute...     

Integration of pen aquaculture into ecosystem-based enhancement of small-scale fisheries in a macrophyte dominated floodplain wetland of India

Environmental Science and Pollution Research - The rapid degradation, overexploitation, and encroachment of floodplain wetlands have led to considerable decline in fish diversity and production...     

Chitosan/Hydroxyethyl Cellulose Gel Immobilized Polyaniline/CuO/ZnO Adsorptive-Photocatalytic Hybrid Nanocomposite for Congo Red Removal

Journal of Polymers and the Environment - Advanced photocatalytic degradation based on polymer/metal oxide hybrid composites can convert organic and related pollutants into an environmentally...     

Seasonal Variations of PM10 and TSP in Residential and Industrial Sites in an Urban Area of Kolkata, India

The objective of the study is to investigate seasonal and spatial variations of PM₁₀ (particulate matter with aerodynamic diameter less than or equal to 10 μm) and TSP (total suspended particulate matter) of an Indian Metropolis with high pollution and population density from November 2003 to November 2004. Ambient concentration measurements of PM₁₀ and TSP were carried out at two monitoring sites of an urban region of Kolkata. Monitoring sites have been selected based on the dominant activities of the area. Meteorological parameters such as wind speed, wind direction, rainfall, temperature and relative humidity were also collected simultaneously during the sampling period from Indian Meteorological Department, Kolkata. The 24 h average concentrations of PM₁₀ and TSP were found in the range 68.2–280.6 μg/m³ and 139.3–580.3 μg/m³ for residential (Kasba) area, while 62.4–401.2 μg/m³ and 125.7–732.1 μg/m³ for industrial (Cossipore) area, respectively. Winter concentrations of particulate pollutants were higher than other seasons, irrespective of the monitoring sites. It indicates a longer residence time of particulates in the atmosphere during winter due to low winds and low mixing height. Spread of air pollution sources and non-uniform mixing conditions in an urban area often result in spatial variation of pollutant concentrations. The higher particulate pollution at industrial area may be attributed due to resuspension of road dust, soil dust, automobile traffic and nearby industrial emissions. Particle size analysis result shows that PM₁₀ is about 52% of TSP at residential area and 54% at industrial area.     

Estimation of health risks due to copper-based nanoagrochemicals

Environmental Science and Pollution Research - This study estimated health risks due to two types of copper-based nanoagrochemicals (Cu (OH)2 and CuO nanoparticles (NPs)), during inadvertent...     

Carbon dissipation from surgical cotton production wastewater using macroalgae,microalgae, and activated sludge microbes

Surgical cotton production has drastically been increased in the past few years due to excessive use by medical health professionals especially in countries like India, which is among the top three exporters of cotton worldwide. The effluent generated from surgical cotton industries differ from textile effluents by the conspicuous absence of dyeing chemicals. This wastewater has a high concentration of suspended particles, COD, dissolved ions, organic carbon, and alkaline pH. Several studies have been published on the treatment of textile effluents and the degradation of dyeing chemicals, while the treatment studies on surgical cotton wastewater have been rarely reported in spite of their potential to cause pollution in receiving land/water bodies. Activated sludge microbes have been extensively studied and well documented in the treatment of several industrial effluent but does not match to the production of valuable biomass from algae. The global energy demand has prompted the scientific community to investigate and explore the possibility of using algae for energy production with simultaneous wastewater treatment. To the best of the authors’ knowledge, no research articles have been published which compare the effectiveness of activated sludge microorganisms, microalgae, and macroalgae in removing contaminants from real wastewater. To date, there is a knowledge gap in understanding and selecting the right choice of biological system for effective and economical effluent treatment. In an attempt to minimize this gap, carbon removal by microalgae, macroalgae, and activated sludge microbes were investigated on real effluent from surgical cotton industries. It was observed that the strain of Chlorella vulgaris could dissipate 83% of COD from real wastewater, while consortia of macroalgae (consisting predominantly of Ulvaceae and Chaetomorpha) and activated sludge microbes could remove 81% and 69% of the carbon, respectively. The microalgal growth (in terms of wet weight) increased from 0.15 to 0.3 g, whereas the macroalgal wet weight increased from 1.5 to 3 g in over 7 days of batch experiments conducted in triplicates. This indicated the superlative performance of microalgae over activated sludge microbes in carbon dissipation.

     

Designing a community-based insurance scheme to reduce human–wildlife conflict

Environment, Development and Sustainability - Globally, human–wildlife conflict (HWC) is a burning issue, which the conservationists have attempted to address through various conservation...     

Estimating combined health risks of nanomaterials and antibiotics from natural water: a proposed framework

Environmental Science and Pollution Research - Nanoparticles (NPs) are one of the major class of emerging contaminants identified in aquatic environment. There is a probability that they can...