Evaluation of three common alkaline agents for immobilization of multi-metals in a field-contaminated acidic soil

We investigated three common alkaline agents (NaOH, CaO, and Mg(OH)₂) for immobilization of four heavy metals (Pb, Zn, Cu, and Cd) in a field-contaminated soil and elucidated the underpinning principles. NaOH caused the highest pH spike in the soil, while CaO and Mg(OH)₂ served as a longer-lasting source of OH^-. Amending the soil with CaO or Mg(OH)₂ at ≥0.1 mol as OH^- (kg·soil)^?1 for 24 h was able to immobilize all four metals, while NaOH failed. NaOH leached up to 3 times more organic carbon than CaO and Mg(OH)₂, resulting in elevated leachability of the metals. Column elution tests showed that amendments by CaO and Mg(OH)₂ lowered the leachable Pb²⁺, Zn²⁺, Cu²⁺, and Cd²⁺ by 52–54%, 71–75%, 69–73%, and 68%, respectively, after 1440 pore volumes of elution. Sequential extraction revealed that the soil amendments converted the exchangeable fraction of the metals to the much less available forms. XRD and FTIR analyses indicated that formation of metal oxide precipitates and complexation with soil organic matter were responsible for the metals immobilization. Taken together the chemical cost, technical effectiveness, and environmental impact, CaO is the most suitable alkaline agent for remediation of soil contaminated with heavy metals.

     

The influence mechanism of dissolved organic matter on the adsorption of Cd (II) by calcite

Environmental Science and Pollution Research - Dissolved organic matter (DOM) has been widely existed in the soil, which has great influence on the adsorption of heavy metals by minerals. In this...     

浅谈可燃气体检测报警器管理及应用

报警器使用过程中经常出现准确度下降、零点漂移、检测器损坏等问题,严重影响着企业的安全生产.分析了可燃气体报警器使用过程中存在的问题,提出了相应的解决方案.     

High mineral adsorption of glyphosate versus diethyl phthalate and tetracycline,during visible light photodegradation with goethite and oxalate

Environmental Chemistry Letters - The increasing presence of pesticides, pharmaceuticals and plasticizers in environmental media is threatening public health and ecosystems. Remediation of...     

The impact of urbanization and consumption patterns on China’s black carbon emissions based on input–output analysis and structural decomposition analysis

Environmental Science and Pollution Research - Urbanization in China has dramatically increased from 39.10 in 2002 to 58.52% in 2017. Studies have discussed the impacts of urbanization and its...     

Main and added effects of heatwaves on hospitalizations for mental and behavioral disorders in a tropical megacity of Vietnam

Environmental Science and Pollution Research - Vietnam is highly vulnerable to climate change-related extreme weather events such as heatwaves. This study assesses the association between heatwaves...     

Phthalic acid esters (PAEs) in workplace and house dust from Vietnam: concentrations,profiles, emission sources,and exposure risk

Environmental Science and Pollution Research - The occurrence of nine phthalic acid esters (PAEs) were determined in indoor dust samples collected from vehicle repair shops, waste processing...     

An absence of aggression between non-nestmates in the bull ant <Emphasis Type="Italic">Myrmecia nigriceps</Emphasis>

The ability of social insects to discriminate against non-nestmates is vital for maintaining colony integrity, and in most social insect species, individuals act aggressively towards non-nestmates that intrude into their nest. Our experimental field data revealed that intra-colony aggression in the primitive bulldog ant Myrmecia nigriceps is negligible; our series of bioassays revealed no significant difference in the occurrence of aggression in trials involving workers from the same, a close (less than 300 m) or a far (more than 1.5 km) nest. Further, non-nestmate intruders were able to enter the nest in 60% of our trials; a similar level was observed in trials involving nestmates. These results suggest that workers of M. nigriceps are either unable to recognize alien conspecifics or that the costs of ignoring workers from foreign colonies are sufficiently low to favor low levels of inter-colony aggression in this species.     

液化天然气(LNG)接收站定量风险评估

介绍了定量风险评估的概念及其主要步骤,结合LNG接收站定量风险评估实例,阐述了定量风险评估技术的实施过程.