Fine route for an efficient removal of 2,4-dichlorophenoxyacetic acid (2,4-D) by zeolite-supported TiO2

Zeolites HY, Hbeta and HZSM-5 with different physico-chemical properties were chosen as support for TiO2 to illustrate their adsorption, dispersion and electronic structure in photocatalysis. The extent of TiO2 loading was monitored by XRD and BET surface area measurements. The adsorption capacity of HY zeolite was found to be high and hence chosen for further modification to continue the investigation. Photodegradation kinetics were carried out with 2,4-dichlorophenoxyacetic acid (2,4-D) in aqueous solution. The extent of 2,4-D degradation on TiO2/HY loading revealed the importance of adsorption in photocatalysis. Mineralisation studies on all three zeolites with 1 wt.% TiO2 loading demonstrated the good dispersion properties of TiO2/HY. Its photocatalytic activity was found to be excellent with formulated 2,4-D. Comparison of relative photonic efficiencies demonstrated that supported photocatalysts exhibited higher activity than some of the commercial photocatalysts. The high activity of supported TiO2 is due to synergistic effects of improved adsorption of 2,4-D and efficient delocalisation of photogenerated electrons by zeolite support.     

Assessing the effects of changing demographic and consumption patterns on sea tenure regimes in the Roviana Lagoon,Solomon Islands

This paper investigates how sea tenure institutions in the Roviana Lagoon, Solomon Islands, mediate among population, consumption, and the environment. The focus is on explaining how growth in population and consumption alter sea tenure regimes, and the factors that shape either their institutional robustness or vulnerability. The paper also addresses the regional differences among sea tenure institutional arrangements, the processes that are producing them, and the social and environmental outcomes of these institutions as they engage external forces and internal changes. A major question is how existing forms of sea tenure respond comparatively when faced with parallel demographic and economic transformations? Two villages representing different sea tenure arrangements within the Roviana Lagoon are compared. Results show that inhabitants in these villages perceive their systems of sea tenure governance similarly; yet their managerial responses to changes brought about by growth in population and consumption differ, and the responses produce contrasting environmental effects.     

Investigation of work-related musculoskeletal disorders among male kitchen workers in South India

Objective. This study aims to quantify the prevalence of work-related musculoskeletal disorders (MSDs) and risks among male kitchen workers in the catering industry. Method. Data were collected with the help of the Nordic musculoskeletal questionnaire and by direct observations. Results. In total, 114 male kitchen workers from various hostels of a college in South India were considered for this study. The average age and mean years of employment of the workers are 26.4 (SD 7.7) and 7.8 respectively. The statistical analysis carried out reveals that 67.5% of male kitchen workers reported MSDs during the past 12 months. The highest prevalence rate has been found in the lower back (65.8%) and shoulder region (62.3%). Among different categories of kitchen work analyzed, it is evident that chief cooks suffer more from MSDs (79.2%) than assistant cooks (74.3%) and kitchen aides (30.0%). Workers in the older group, i.e., ≥41 years, and workers with 6–10 years of experience suffer with higher risk of MSDs, i.e., 93.9% and 87.5%, respectively. Conclusion. The male kitchen workers who participated in this research were found to possess both MSDs and ergonomic hazards.     

Photo-induced degradation of diuron in aqueous solution by nitrites and nitrates: kinetics and pathways

The photo-induced degradation of diuron (3-(3,4-dichlorophenyl)-1,1-dimethylurea) in aqueous solution under simulated solar irradiation has been investigated in the presence of NO3-/NO2- ions. The degradation rates were compared by varying environmental parameters including substrate and inducer concentrations, oxygen content and pH. The photoproducts were identified by extensive LC-ESI-MS and LC-ESI-MS-MS studies after SPE preconcentration on prepacked cartridges. In both NO3- and NO2- conditions, oxidation of the N-(CH3)2 terminus group is the main process leading to the N-monodemethylated (NHCH3), N-formyl (N(CH3)CHO) and the uncommon and unstable carbinolamine (N(CH3)CH2OH) by-products. Cl/OH substituted and nitrated phenylureas are formed minorily. Degradation pathways involving OH* and NO2* (or dimer) radicals as reactive species are proposed.     

Geochemical behaviour of dissolved trace elements in a monsoon-dominated tropical river basin,Southwestern India

The study presents a 3-year time series data on dissolved trace elements and rare earth elements (REEs) in a monsoon-dominated river basin, the Nethravati River in tropical Southwestern India. The river basin lies on the metamorphic transition boundary which separates the Peninsular Gneiss and Southern Granulitic province belonging to Archean and Tertiary–Quaternary period (Western Dharwar Craton). The basin lithology is mainly composed of granite gneiss, charnockite and metasediment. This study highlights the importance of time series data for better estimation of metal fluxes and to understand the geochemical behaviour of metals in a river basin. The dissolved trace elements show seasonality in the river water metal concentrations forming two distinct groups of metals. First group is composed of heavy metals and minor elements that show higher concentrations during dry season and lesser concentrations during the monsoon season. Second group is composed of metals belonging to lanthanides and actinides with higher concentration in the monsoon and lower concentrations during the dry season. Although the metal concentration of both the groups appears to be controlled by the discharge, there are important biogeochemical processes affecting their concentration. This includes redox reactions (for Fe, Mn, As, Mo, Ba and Ce) and pH-mediated adsorption/desorption reactions (for Ni, Co, Cr, Cu and REEs). The abundance of Fe and Mn oxyhydroxides as a result of redox processes could be driving the geochemical redistribution of metals in the river water. There is a Ce anomaly (Ce/Ce*) at different time periods, both negative and positive, in case of dissolved phase, whereas there is positive anomaly in the particulate and bed sediments. The Ce anomaly correlates with the variations in the dissolved oxygen indicating the redistribution of Ce between particulate and dissolved phase under acidic to neutral pH and lower concentrations of dissolved organic carbon. Unlike other tropical and major world rivers, the effect of organic complexation on metal variability is negligible in the Nethravati River water.     

Rice versus fish revisited: On the integrated management of floodplain resources in Bangladesh

Disproportionately little attention has been paid to the dry season trade‐off between rice and (inland capture) fish production on the floodplains of Bangladesh, compared to the same trade‐off during the flood season. As the rural economy grows increasingly dominated by dry‐season irrigated rice production, and floodplain land and water come under ever‐increasing pressure during the dry winter months, there is an urgent need to focus attention on these dry months that are so critical to the survival and propagation of the floodplain resident fish, and to the poor people that depend on these fish for their livelihood. This article examines three important dry‐season natural resource constraints to floodplain livelihoods in Bangladesh, and finds a common factor at the heart of all three: rice cultivation on lands at low and very low elevations. The article articulates the system interlinkages that bind these constraints and the long‐run trend towards irrigated rice cropping on lower‐lying lands, and suggests a management approach based on locally tailored strategies to arrest this trend. Apart from its direct relevance to the floodplains of Bangladesh, which support more than 100 million people, these lessons have relevance for river floodplain systems elsewhere in the developing world, notably the Mekong Delta.     

Somatic condition of the fish, Notopterus notopterus (Pallas) during different phases of the reproductive cycle

The study on the mathematical relationship between length and weight of fishes has considerable importance in fishery research especially for the study of fish population dynamics and patterns of growth in fish stocks. This aspect is useful in rationally managing the population of fishes, and is an index of relative robustness of the fish). Variations from expected weight or length of an individual fish or group of fish indicate the general well being and state of gonadal development. The condition of fish can be influenced by the onset of maturity. The results indicate that the overall condition of the female and male fish seems to get improved towards the approach of maturing and mature stages of the gonads during pre-spawning phases. The reduction in the condition factor (K) and somatic condition factor (Ks) during spawning phase may be because of the fish becoming exhausted due to spawning activity. Although improvement in the condition of the fish was observed on the approach of breeding period, the overall condition seems to be better in the aquatic body from which the fish was collected.     

人口学和消费形式的变化对所罗门群岛罗维安纳泻湖海洋保有权制度影响评价

本文探讨了所罗门群岛罗维安纳泻湖海洋保有权制度如何调解人口、消费和环境之间的相互关系.焦点在于解释人口和消费的增长如何改变海洋保有权制度以及形成其健全或脆弱的制度的诸因素.本文还论述了海洋保有权制度安排之间的区域性差异,产生这些差异的过程和当这些制度约束外部力量和内部变化时这些制度的社会和环境后果.主要问题是现有的海洋保有权形式当面对并行的人口学转型和经济转型时如何作出相对的反应.在罗维安纳泻湖区域内代表不同的海洋保有权安排的两个村庄作了比较.结果表明,这些村庄的居民发觉他们的海洋保有权统治体系相似,而他们对由于人口和消费的增长所带来的变化在管理上的反应却不同,这些反应产生了截然不同的环境影响.     

Tissue cholesterol and serum cortisol level during different reproductive phases of the female freshwater fish Notopterus notopterus (Pallas)

In the present study tissue cholesterol and serum cortisol changes during two reproductive phases have been correlated in the freshwater fish Notopterus notopterus. The reproductive cycle of N. notopterus has two phases such as breeding phase (April - August) and non breading phase (October - December). The cholesterol content of the ovary and liver increased during breeding phase. The serum cortisol estimated by radio immuno assay (RIA) technique indicates that the level of the hormone was high during breeding phase compared to non breading phase. The increase in cholesterol during breeding phase may be because of increase in cortisol synthesis needed for ovarian growth and vitellogenesis. The gonadosomatic index (GSI) also increases during breeding phase.     

Vermicomposting: A sustainable tool for environmental equilibria

Improperly managed organic waste constitutes a serious environment threat across the globe. This has led to a worldwide struggle to strike a balance between the rapid generation of such wastes and protection of the environment. With the unique advantages of lower operational and maintenance costs compared with other waste management technologies, the use of vermicomposting to manage organic wastes has been increasing rapidly in recent years. Still, some factors (e.g., characteristics of substrate composition before and after treatment) are in need of additional, specific studies so that researchers can better understand the metabolism involved in the process. Vermicomposting provides employment opportunities as it protects the environment, augmenting crop productivity when it is used as a fertilizer supplement and helping to maintain ecological balance. Thus, vermicompost plays an important role in the circular economy. This article provides an overview of the research activities that have been conducted on the use of vermicomposts to remove pollutants from the soil, in wastewater treatment, and in organic waste recycling throughout the world. Circular economic assessment has revealed that vermicomposting technology is usually feasible except in certain cases. Most other methods of waste disposal lead to soil deterioration, toxic effects, and increased pollution affecting land, air, water, and living beings, in addition to the sometimes considerable expense of their implementation. Thus, an eco‐friendly method that removes waste in one step is needed. Determining the long‐term performance and sustainable operation of vermicomposting systems still poses a challenge, however, as treatment performance is affected by design parameters, operational conditions, and environmental factors. This article summarizes the factors influencing pollutant removal through the vermicomposting process. Finally, this article highlights additional research that should be conducted on these issues to improve the performance of vermicomposting.