Micropollutant removal during biological wastewater treatment and a subsequent ozonation step

The design criteria for wastewater treatment plants (WWTP) and the sludge retention time, respectively, have a significant impact on micropollutant removal. The upgrade of an Austrian municipal WWTP to nitrogen removal (best available technology, BAT) resulted in increased elimination of most of the analyzed micropollutants. Substances, such as bisphenol-A, 17α-ethinylestradiol and the antibiotics erythromycin and roxithromycin were only removed after the upgrade of the WWTP. Nevertheless, the BAT was not sufficient to completely eliminate these compounds. Thus, a pilot scale ozonation plant was installed for additional treatment of the effluent. The application of 0.6 g O₃ g DOC⁻¹ increased the removal of most of the micropollutants, especially for compounds that were not degraded in the previous biological process, as for example carbamazepine and diclofenac. These results indicated that the ozonation of WWTP effluent is a promising technology to further decrease emissions of micropollutants from the treatment process.     

Occurrence of currently used pesticides in ambient air of Centre Region (France)

Ambient air samples were collected, from 2006 to 2008 at three rural and two urban sites in Centre Region (France) and analyzed for 56 currently used pesticides (CUPs), of which 41 were detected. The four CUPs most frequently detected were the herbicides trifluralin, acetochlor and pendimethalin and the fungicide chlorothalonil, which were found with frequencies ranging between 52 and 78%, and with average concentrations of 1.93, 1.32, 1.84 and 12.15 ng m^?3, respectively. Among the detected pesticides, concentrations of eight fungicides (spiroxamine, fenpropimorph, cyprodinil, tolyfluanid, epoxiconazole, vinchlozolin, fluazinam, fludioxinil), two insecticides (propargite, ethoprophos), and one herbicide (oxyfluorfen) are, to our knowledge, reported for the first time in the literature.The majority of the CUPs showed a seasonal trend, with most of the detections and the highest concentrations occurring during the spring and early summer. The most important pesticides detected were related to arable crops and fruit orchards, the main cultures in this region, highlighting the fact that the main sources come from local applications. Minor differences were found in the profiles of pesticides within rural areas and between rural and urban areas.     

Greening the structural change process: ranking sustainability of countries in climate change

This paper proposes an analytical toolkit to measure the sustainability of industrialization across countries. Drawing from a methodology developed to analyze economic development as a process of modernization, it ranks countries on the basis of the emissions they produce and their stage of development. The proposed index penalizes environmental pressures taking into account the modernization level of a country. The paper also proposes an assessment of the environmental performance of countries at the same level of modernization. It introduces the notion of policy space as the difference between the best and worst environmental performer at a given level of modernization. An important finding of the paper is that the magnitude of the policy space is not homogenous across different levels of income and environmental targets.     

A hidden species-area curve

The species-area curve, which describes the relationship between the number of observed species in a geographical region and the area of the region, plays a central role in biogeography. Beyond its scientific importance, the species-area curve is commonly used to assess the loss of species due to habitat loss. When the species-area curve is estimated from spatial samples, the existence of species with low or highly spatially variable abundance exaggerates the true rate at which species accumulate with area. Here, a hidden species-area curve is defined that accounts for this sampling effect and its estimation by maximum likelihood is outlined. Both the species-area curve and the hidden species-area curve are conditioned on the observed species list; thus the analysis does not depend on the total number of observed and unobserved species, that is, species richness. The method is tested by sub-sampling some tropical forest data and found to work well. It is also applied to a classic data set from the deep sea. For these data, accounting for this sampling effect has a large impact.     

Integration of ozonation and an anaerobic expanded granular sludge bed reactor for micropollutant removal from sewage

Environmental Science and Pollution Research - Conventional sewage treatment systems are generally not designed to remove micropollutants, requiring the development of new technologies, such as the...     

Towards effective culvert design: monitoring seasonal use and behavior by Mediterranean mesocarnivores

Drainage culverts are known to be used by a diverse number of species. To date, most studies looking at culvert usage have been restricted to the dry season. This seasonal bias has limited our understanding of how different species respond to culverts and, consequently, our ability to find effective ways to promote the use of culverts as aids to species movement. The main goal of this study was to examine the role of highway culverts for mesocarnivores throughout the year. We addressed (1) the seasonality of culvert use, (2) the relative importance of culvert structure, highway features, and surrounding landscape on culvert use, (3) the influence of the water depth and cover on culvert use, and (4) the effect of culvert structure on individual behavior. Fifteen culverts were monitored along 2 highways in southern Portugal using video-surveillance cameras and marble dust for 10 consecutive days per season. We used generalized linear mixed models to determine which factors most affected the culvert use and behavior by mesocarnivores. Our results highlight the effect of seasonality and water on culvert use. Culvert use was positively related with species activity throughout the year. All species (except otters (Lutra lutra)) were less likely to use culverts that contained water more than 3 cm deep or covering more than 70 % of the culvert base. Based on our results, future surveys and culvert retrofit design should address (1) the importance of seasonality in the interpretation of results and (2) the complementarity of culvert-specific features (water, ledges, and naturalization).     

Possible use of Serratia marcescens in toxic metal biosorption (removal)

Background, aim and scope  

Metal pollution is a serious problem for environmental safety and programmes of monitoring and bioremediation are needed. Among the processes of bioremediation, the use of microbes to remove and degrade contaminants is considered a biotechnological approach to clean up polluted environments.     

Use of sulfadimethoxine in intensive calf farming: evaluation of transfer to stable manure and soil

After prophylactic treatment of 50 calves with 62mgkg(-1)day(-1) of sulfadimethoxine (SDM) for five days, the levels of the drug over time were followed in feces, bedding and stable manure, and then in the soil of a manured field and surrounding drainage courses. Analysis were done by HPLC after applying to the different matrices a quick and simple extraction procedure. The half-life of the drug in bedding was very short (24h). In stable manure the degradation rate of the drug slowed down and the calculated half-life was 64 days, with 390microgkg(-1) of SDM still detectable after three months maturation. However, in a five months matured stable manure obtained from other groups of calves subjected to the same prophylactic treatment, levels of SDM were <50muicrokg(-1) (LOD of the analytical method). After field fertilization with this manure, no traces of SDM were found in soil (LOD 10microgkg(-1)) or in the water (LOD 2microgl(-1)) from the surrounding drainage courses. Using the internationally recognised DAPHTOXKIT-Ftrade mark, a SDM toxicity test toward Daphnia magna was performed in the range 10-100mgl(-1). The test gave negative results both after 24 and 48h, confirming that microcrustaceans are less sensitive than other models to the toxicity of antibacterials. However, based on data from other authors, concerning algal toxicity and microbial inhibition, and on the analytical results from the current field study, the calculated worst-case EC50/PEC ratio for SDM both in freshwater and in soil was still >1000.     

Glacial-interglacial changes in the occurrence of Pb, Cd, Cu and Zn in Vostok Antarctic ice from 240 000 to 410 000 years BP

Lead (Pb), cadmium (Cd), copper (Cu) and zinc (Zn) have been measured by electrothermal atomic absorption spectrometry in various sections of the 3623 m deep ice core drilled at Vostok, in central East Antarctica. The sections were dated from 240 to 410 kyear BP (Marine Isotopic Stages (MIS) 7.5 to 11.3), which corresponds to the 3rd and 4th glacial-interglacial cycles before present. Concentrations are found to have varied greatly during this 170 kyear time period, with high concentration values during the coldest climatic stages such as MIS 8.4 and 10.2 and much lower concentration values during warmer periods, such as the interglacials MIS 7.5, 9.3 and 11.3. Rock and soil dust were the dominant sources for Pb, whatever the period, and for Zn and Cu and possibly Cd during cold climatic stages. The contribution from volcanic emissions was important for Cd during all periods and might have been significant for Cu and Zn during warm periods.     

Road trauma among young Australians: Implementing policy to reduce road deaths and serious injury

Objective: The objective of this study was to estimate the likely reduction in road trauma associated with the implementation of effective interventions to reduce road trauma among young Australians.

Methods: A desktop evaluation was conducted to model the likely reduction in road trauma (deaths and serious injuries resulting in hospitalization) among young people aged 17–24 years residing in Queensland, New South Wales, and Victoria. Potential interventions were identified using a rapid literature review and assigned a score based on evidence of effectiveness and implementation feasibility with the 3 highest scoring interventions included in the modeling. Likely reduction in road trauma was estimated by applying the average risk reduction effect sizes for each intervention to baseline risk (passenger or driver death or serious injury per 100,000 population) of road trauma for young Australians. Point estimates were calculated for the potential number of deaths and serious injuries averted in each state and per 100,000 population, with a one-way sensitivity analysis conducted using uncertainty ranges identified.

Results: Peer passenger and night driving restrictions as well as improved vehicle safety measures had the greatest potential to reduce road trauma. Peer passenger restrictions could avert 14 (range: 5–24) and 24 (range: 8–41) hospitalizations per year in Queensland and New South Wales, respectively, and night driving restrictions could avert 17 (range: 7–26), 28 (range: 12–45), and 13 (range: 6–21) hospitalizations annually in Queensland, New South Wales, and Victoria. These interventions reduced fatalities by less than 1 death annually in each state. Improved vehicle safety measures could avert 0–3, 0–4, and 0–3 deaths and 3–91, 4–156, and 2–75 hospitalizations in Queensland, New South Wales, and Victoria.

Conclusions: Key elements of graduated licensing (peer passenger and night driving restrictions) along with vehicle safety interventions offer modest but practically significant reductions in road trauma for young Australians. State governments need to revise current legislation to ensure that these reductions in road trauma can be realized.