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21.
A fragment constant QSAR model for evaluating the EC50 values of organic chemicals to Daphnia magna.
Shu Tao Xiaohuan Xi Fuliu Xu Bengang Li Jun Cao R Dawson 《Environmental pollution (Barking, Essex : 1987)》2002,116(1):57-64
The quantitative relationship between the median effective concentration (EC50) of organic chemicals to Daphnia magna and the number of molecular fragments was investigated based on experimental EC50 values for 217 chemicals derived from the literature. A fragment constant model was developed based on a multivariate linear regression between the number of fragments and the logarithmically transformed reciprocal values of EC50. Functional correction factors were introduced into the model. The model was verified using an independent set of randomly selected data. The mean residual of the final model was 0.4 log-units. The robustness of the model was discussed based on the results of three jackknife tests. 相似文献
22.
A transition zone in the otoliths of orange roughy (Hoplostethus atlanticus) is described where annulus width decreases markedly. For fish sampled at spawning time, the relationship between gonad stage
and the presence or absence of a transition zone is consistent with the hypothesis that this zone marks the onset of maturity,
if allowance is made for some error in gonad staging and identification of the zone. Another data set from a non-spawning
area after the spawning season is not consistent with the hypothesis. However, these latter data are considered less reliable
because of the small size of the fish in the sample and difficulties in determining, outside the spawning season, whether
a fish has been reproductively active. This hypothesis was used to provide estimates of the median age (30 yr) and length
(31 cm) at the onset of maturity for the Chatham Rise, New Zealand population. These estimates are unaffected by the biases
associated with the usual ogive method of estimation.
Received: 27 June 1997 / Accepted: 1 July 1997 相似文献
23.
Heavy metal accumulation in Littoraria scabra along polluted and pristine mangrove areas of Tanzania
The periwinkle Littoraria scabra was collected at polluted and pristine mangrove sites along the Tanzanian coastline, including Msimbazi, Mbweni (i.e. Dar es Salaam) and Kisakasaka, Nyamanzi and Maruhubi (i.e. Zanzibar). Periwinkles were morphologically characterized, sexed and their heavy metal content was determined using ICP-MS. Analysis revealed that L. scabra from polluted areas contained higher soft tissue heavy metal levels, were significantly smaller and weighed less compared to their conspecifics from the unpolluted mangroves. The current morphological observations may be explained in terms of growth and/or mortality rate differences between the polluted and non-polluted sites. Although a variety of stressors may account for these adverse morphological patterns, our data suggest a close relationship with the soft tissue heavy metal content. Compared to soft tissue heavy metal levels that were measured in L. scabra along the same area in 1998, most metals, except for arsenic, chromium and iron have decreased dramatically. 相似文献
24.
Frank Eierdanz Joseph Alcamo Lilibeth Acosta-Michlik Dörthe Krömker Dennis Tänzler 《Regional Environmental Change》2008,8(4):197-205
This paper presents the technical aspects of a new methodology for assessing the susceptibility of society to drought. The
methodology consists of a combination of inference modelling and fuzzy logic applications. Four steps are followed: (1) model
input variables are selected—these variables reflect the main factors influencing susceptibility in a social group, population
or region, (2) fuzzification—the uncertainties of the input variables are made explicit by representing them as ‘fuzzy membership
functions’, (3) inference modelling—the input variables are used to construct a model made up of linguistic rules, and (4)
defuzzification—results from the model in linguistic form are translated into numerical form, also through the use of fuzzy
membership functions. The disadvantages and advantages of this methodology became apparent when it was applied to the assessment
of susceptibility from three disciplinary perspectives: Disadvantages include the difficulty in validating results and the
subjectivity involved with specifying fuzzy membership functions and the rules of the inference model. Advantages of the methodology
are its transparency, because all model assumptions have to be made explicit in the form of inference rules; its flexibility,
in that informal and expert knowledge can be incorporated through ‘fuzzy membership functions’ and through the rules in the
inference model; and its versatility, since numerical data can be converted to linguistic statements and vice versa through
the procedures of ‘fuzzification’ and ‘defuzzification’. 相似文献
25.
26.
Molly K. Chambers Daniel M. White Michael R. Lilly Larry D. Hinzman Kristie M. Hilton Robert C. Busey 《Journal of the American Water Resources Association》2008,44(2):316-327
Abstract: Lakes are important water resources on the North Slope of Alaska. Freshwater is required for oilfield production as well as exploration, which occurs largely on ice roads and pads. Since most North Slope lakes are shallow, the quantity and quality of the water under ice at the end of winter are important environmental management issues. Currently, water‐use permits are a function of the presence of overwintering fish populations, and their sensitivity to low oxygen concentrations. Sampling of five North Slope lakes during the winter of 2004‐2005 shed some light on the winter chemistry of four lakes that were used as water supplies and one undisturbed lake. Field analysis was conducted for oxygen, conductivity, pH, and temperature throughout the lake depth, as well as ice thickness and water depth. Water samples were retrieved from the lakes and analyzed for Na, Ca, K, Mg, Fe, dissolved‐organic carbon, and alkalinity in the laboratory. Lake properties, rather than pumping, were the best predictors of oxygen depletion, with the highest dissolved‐oxygen levels maintained in the lake with the lowest concentration of constituents. Volume weighted mean dissolved‐oxygen concentrations ranged from 4 to 94% of saturation in March. Dissolved oxygen and specific conductance data suggested that the lakes began to refresh in May. 相似文献
27.
28.
Daniel H Zitomer Prasoon Adhikari Craig Heisel Dennis Dineen 《Water environment research》2008,80(3):229-237
Codigestion of five wastes and municipal wastewater sludge was evaluated using full-scale testing. Synergistic, antagonistic, and neutral outcomes were observed depending on codigestate identity and concentration, highlighting the value of careful blending. Yeast waste resulted in notable synergism, increasing biogas production by over 50%, whereas aircraft deicing waste resulted in antagonism at high loadings and neutral outcomes at lower loadings. Restaurant waste codigestion resulted in neutral outcomes. The synergisim with yeast codigestates may have resulted from trace nutrients (i.e., iron, nickel, and cobalt) in the wastes that increased microbiological activity. Antagonist outcomes with deicing waste may have been the result of organic overload or inhibitory deicer constituents. Codigestion of wastes at the feed rates investigated was estimated to produce 0.50 ML/d of methane having an energy equivalent of 17 500 MJ/d. This was estimated to reduce net carbon dioxide emissions by 560 tonnes/y. 相似文献
29.
This study combined laboratory based microcosm systems as well as field experiments to evaluate the mobility of atrazine on a Ultisol under humid tropical conditions in Brazil. Results from sorption experiments fit to the Freundlich isotherm model [K(f) 0.99 mg kg(-1)/(mg l(-1))(1/n)], and indicate a low sorption capacity for atrazine in this soil and consequently large potential for movement by leaching and runoff. Microcosm systems using (14)C-atrazine to trace the fate of the applied herbicide, showed that 0.33% of the atrazine was volatilized, 0.25% mineralized and 6.89% was recorded in the leachate. After 60 d in the microcosms, 75% of the (14)C remained in the upper 5 cm soil layer indicating atrazine or its metabolites remained close to the soil surface. In field experiments, after 60 d, only 5% of the atrazine applied was recovered in the upper soil layers. In the field experiments atrazine was detected at a depth of 50 cm indicating leaching. Simulating tropical rain in field experiments resulted in 2.1% loss of atrazine in runoff of which 0.5% was adsorbed onto transported soil particles and 1.6% was in solution. Atrazine runoff was greatest two days after herbicide application and decreased 10 fold after 15 d. The use of atrazine on Ultisols, in the humid tropics, constitutes a threat to water quality, causing surface water and ground water pollution. 相似文献
30.
Oritani Marsh in the Hackensack Meadowlands of urbanized northeastern New Jersey USA was assessed in 2000 for vegetation,
soil/sediment chemistry, abundance/diversity of benthic invertebrates, and bird and mammal usage. Vegetatively, both marsh
and uplands are dominated by tall, dense Phragmites australis. Small patches (less than 2 hectares total) dominated by Spartina spp. were found at the lowest elevations. Soil/sediment cores were sliced into 5 intervals and analyzed for metals, pesticides
and volatile/semivolatile organic compounds. Thirteen locations had at least one chemical above Long et al.’s [Environmental Management, 19, 1995, 81--97] “Effects Range-Median” (ERM). Seven metals and nine organics exceeded ERM in at least one sample, with mercury
showing the most exceedances. The surface 15 cm interval was generally more contaminated with metals than the 15 to 30 cm
interval; the reverse was true for semivolatile organic compounds. Twenty taxa of benthic macroinvertebrates were collected,
with each location producing from 1 to 9 taxa. Abundance ranged from 11 to 3,889 individuals/m2. Number of taxa was moderately (r
2 between 0.40 and 0.70) negatively correlated with zinc, beryllium, nickel and arsenic concentrations; no other chemical’s
r
2 was above 0.25. Diversity was moderately negatively correlated with arsenic and beryllium. These correlations were unexpected:
zinc, beryllium, nickel and arsenic were not the chemicals found at the highest concentrations relative to benchmarks. Number
of taxa, abundance and diversity were moderately (negatively) correlated with elevation; organic carbon was moderately (positively)
correlated with abundance. All other correlations were weak (r
2 < 0.35). Live traps captured only one mammal species, the meadow jumping mouse. Bird observations revealed 39 species, dominated
by a few common species. 相似文献