Sources of PCDD/Fs, non-ortho PCBs and PAHs in sediments of high and low impacted transboundary rivers (Belgium-France)

PAHs, PCDD/Fs and non-ortho PCBs have been assessed in Yser and Upper-Scheldt river sediments. Higher contamination levels were observed in the Upper-Scheldt sediments: maximum concentrations for the 16 US-EPA PAHs, PCDD/Fs and non-ortho PCBs respectively amount to 8.9 mg kg⁻¹, 12 ng TEQ kg⁻¹ and 5.1 ng TEQ kg⁻¹. Diagnostic PAH ratios in sediments and atmospheric samples suggest that the PAH compounds are from pyrolytic origin, more specifically combustion processes. The huge consumption of coal in cokes-ovens and smelters and its use for house-heating in Northern France, although decreasing during the last decades, are in support of that suggestion. PCDD/F fingerprints in sediments and deposition material indicate that OCDD is the dominant congener. In addition use of pentachlorophenol (PCP) in the past led to a minor contribution of PCDD/Fs in our sediment samples. Non-ortho PCBs form a substantial fraction of the total TEQ concentrations observed in the sediments. Since the 1980s and 1990s a substantial reduction of the PCDD/F sediment concentrations is observed, but this is not the case for the PAHs.     

Accuracy Assessment of NOAA Gridded Daily Reference Evapotranspiration for the Texas High Plains

The National Oceanic and Atmospheric Administration (NOAA) provides daily reference evapotranspiration (ET_ref) maps for the contiguous United States using climatic data from North American Land Data Assimilation System (NLDAS). This data provides large‐scale spatial representation of ET_ref, which is essential for regional scale water resources management. Data used in the development of NOAA daily ET_ref maps are derived from observations over surfaces that are different from short (grass — ET_os) or tall (alfalfa — ET_rs) reference crops, often in nonagricultural settings, which carries an unknown discrepancy between assumed and actual conditions. In this study, NOAA daily ET_os and ET_rs maps were evaluated for accuracy, using observed data from the Texas High Plains Evapotranspiration (TXHPET) network. Daily ET_os, ET_rs and the climatic data (air temperature, wind speed, and solar radiation) used for calculating ET_ref were extracted from the NOAA maps for TXHPET locations and compared against ground measurements on reference grass surfaces. NOAA ET_ref maps generally overestimated the TXHPET observations (1.4 and 2.2 mm/day ET_os and ET_rs, respectively), which may be attributed to errors in the NLDAS modeled air temperature and wind speed, to which reference ET_ref is most sensitive. Therefore, a bias correction to NLDAS modeled air temperature and wind speed data, or adjustment to the resulting NOAA ET_ref, may be needed to improve the accuracy of NOAA ET_ref maps.     

Hydrogen sulfide generation in simulated construction and demolition debris landfills: impact of waste composition

Hydrogen sulfide (H2S) generation in construction and demolition (C&D) debris landfills has been associated with the biodegradation of gypsum drywall. Laboratory research was conducted to observe H2S generation when drywall was codisposed with different C&D debris constituents. Two experiments were conducted using simulated landfill columns. Experiment 1 consisted of various combinations of drywall, wood, and concrete to determine the impact of different waste constituents and combinations on H2S generation. Experiment 2 was designed to examine the effect of concrete on H2S generation and migration. The results indicate that decaying drywall, even alone, leached enough sulfate ions and organic matter for sulfate-reducing bacteria (SRB) to generate large H2S concentrations as high as 63,000 ppmv. The codisposed wastes show some effect on H2S generation. At the end of experiment 1, the wood/drywall and drywall alone columns possessed H2S concentrations > 40,000 ppmv. Conversely, H2S concentrations were < 1 ppmv in those columns containing concrete. Concrete plays a role in decreasing H2S by increasing pH out of the range for SRB growth and by reacting with H2S. This study also showed that wood lowered H2S concentrations initially by decreasing leachate pH values. Based on the results, two possible control mechanisms to mitigate H2S generation in C&D debris landfills are suggested.     

Haematology, genotoxicity, enzymatic activity and histopathology as biomarkers of metal pollution in the shrew Crocidura russula

Haematological (WBC, RBC, Hgb and Hct) and genotoxicity (MNT) parameters, hepatic enzymatic activities (GST, GPx and GR), and a histopathological evaluation of liver, kidneys and gonads were assessed as general biomarkers of metal pollution in the shrew Crocidura russula inhabiting a pyrite mining area. Specimens exposed to metals presented a few significant alterations when compared with reference animals: GST activity decreased; micronuclei increased; and evident liver alterations related to metal exposure were observed. On the basis of all the parameters studied, age was an important factor that partly explained the observed variation, whereas sex was the least important factor. Significant correlations were also found between heavy metal concentrations and biomarkers evaluated, demonstrating the great influence of these metals in the metabolic alterations. To the best of our knowledge, these data constitute the first measurements of a battery of biomarkers in shrews from a mine site and are among the few available for insectivorous mammals.     

Temporal pessimism and spatial optimism in environmental assessments: An 18-nation study

The personal assessments of the current and expected future state of the environment by 3232 community respondents in 18 nations were investigated at the local, national, and global spatial levels. These assessments were compared to a ranking of each country's environmental quality by an expert panel. Temporal pessimism (“things will get worse”) was found in the assessments at all three spatial levels. Spatial optimism bias (“things are better here than there”) was found in the assessments of current environmental conditions in 15 of 18 countries, but not in the assessments of the future. All countries except one exhibited temporal pessimism, but significant differences between them were common. Evaluations of current environmental conditions also differed by country. Citizens' assessments of current conditions, and the degree of comparative optimism, were strongly correlated with the expert panel's assessments of national environmental quality. Aside from the value of understanding global trends in environmental assessments, the results have important implications for environmental policy and risk management strategies.     

The need for integration of drought monitoring tools for proactive food security management in sub‐Saharan Africa

Reducing the impact of drought and famine remains a challenge in sub‐Saharan Africa despite ongoing drought relief assistance in recent decades. This is because drought and famine are primarily addressed through a crisis management approach when a disaster occurs, rather than stressing preparedness and risk management. Moreover, drought planning and food security efforts have been hampered by a lack of integrated drought monitoring tools, inadequate early warning systems (EWS), and insufficient information flow within and between levels of government in many sub‐Saharan countries. The integration of existing drought monitoring tools for sub‐Saharan Africa is essential for improving food security systems to reduce the impacts of drought and famine on society in this region. A proactive approach emphasizing integration requires the collective use of multiple tools, which can be used to detect trends in food availability and provide early indicators at local, national, and regional scales on the likely occurrence of food crises. In addition, improving the ability to monitor and disseminate critical drought‐related information using available modern technologies (e.g., satellites, computers, and modern communication techniques) may help trigger timely and appropriate preventive responses and, ultimately, contribute to food security and sustainable development in sub‐Saharan Africa.     

Annual Estimates of Recharge,Quick‐Flow Runoff,and Evapotranspiration for the Contiguous U.S. Using Empirical Regression Equations

This study presents new data‐driven, annual estimates of the division of precipitation into the recharge, quick‐flow runoff, and evapotranspiration (ET) water budget components for 2000‐2013 for the contiguous United States (CONUS). The algorithms used to produce these maps ensure water budget consistency over this broad spatial scale, with contributions from precipitation influx attributed to each component at 800 m resolution. The quick‐flow runoff estimates for the contribution to the rapidly varying portion of the hydrograph are produced using data from 1,434 gaged watersheds, and depend on precipitation, soil saturated hydraulic conductivity, and surficial geology type. Evapotranspiration estimates are produced from a regression using water balance data from 679 gaged watersheds and depend on land cover, temperature, and precipitation. The quick‐flow and ET estimates are combined to calculate recharge as the remainder of precipitation. The ET and recharge estimates are checked against independent field data, and the results show good agreement. Comparisons of recharge estimates with groundwater extraction data show that in 15% of the country, groundwater is being extracted at rates higher than the local recharge. These maps of the internally consistent water budget components of recharge, quick‐flow runoff, and ET, being derived from and tested against data, are expected to provide reliable first‐order estimates of these quantities across the CONUS, even where field measurements are sparse.     

Urban stress and helping behavior: Effects of environmental overload and noise on behavior

The effects of environmental overload and noise on helping behavior is assessed through a 2 × 3 experimental design including two levels of environmental overload and three conditions on each site: without roadworks, roadworks without noise, and noisy roadworks.Results are analysed in terms of the cognitive appraisal of the situation and the narrowing of attention. The subject's behavior when confronted with explicit and implicit helping requests shows that noise appears to be the most important component of overload, affecting both the subjects' attentiveness in implicit helping demands, as well as the refusal to engage in verbal interaction.