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61.
62.
徐海林  童仕唐 《化工环保》2011,31(6):486-489
利用脱硫废碱液对酸化后的含铬废水进行处理,研究了废水初始pH、脱硫废碱液加入量和静置时间等对Cr(Ⅵ)转化率的影响.实验结果表明,在废水初始pH为1.4、静置时间为30 min的条件下,处理30 mL Cr(Ⅵ)质量浓度为126.5 mg/L的含铬废水,适宜的脱硫废碱液加入量为6 mL,此条件下Cr(Ⅵ)转化率接近10...  相似文献   
63.
城市污水成分复杂,含有多种有毒有害物质,使其能对生物体产生各种不良生物效应,其中,内分泌干扰物,尤其是雌激素类物质以及具有雌激素活性的污染物,因能影响生物的生殖系统并造成受纳水体鱼类性别转变等危害而备受关注,城市污水的雌激素活性也一直是污水处理领域的研究热点.当前,城市污水回用是缓解全球水资源危机的重要途径之一,在此背...  相似文献   
64.
Environmental Science and Pollution Research - The aim of this work was to explore the potential application of biochar from distillers’ grains anaerobic digestion residue pyrolyzed at...  相似文献   
65.
Environmental Science and Pollution Research - The pollution of heavy metals is a severer problem for the ecosystems in waters. The toxicity of Cd2+ on phycocyanin (PC) is studied in molecular...  相似文献   
66.
Xu N  Christodoulatos C  Braida W 《Chemosphere》2006,64(8):1325-1333
The mobility of Mo in soils and sediments depends on several factors including soil mineralogy and the presence of other oxyanions that compete with Mo for the adsorbent's retention sites. Batch experiments addressing Mo adsorption onto goethite were conducted with phosphate, sulfate, silicate, and tungstate as competing anions in order to produce competitive two anions adsorption envelopes, as well as competitive two anions adsorption isotherms. Tungstate and phosphate appear to be the strongest competitors of Mo for the adsorption sites of goethite, whereas little competitive effects were observed in the case of silicate and sulfate. Mo adsorption isotherm from a phosphate solution was similar to the one from a tungstate solution. The charge distribution multi-site complexation (CD-MUSIC) model was used to predict competitive adsorption between MoO(4)(2-) and other anions (i.e., phosphate, sulfate, silicate and tungstate) using model parameters obtained from the fitting of single ion adsorption envelopes. CD-MUSIC results strongly agree with the experimental adsorption envelopes of molybdate over the pH range from 3.5 to 10. Furthermore, CD-MUSIC prediction of the molybdate adsorption isotherm show a satisfactory fit of the experimental results. Modeling results suggest that the diprotonated monodentate complexes, FeOW(OH)(5)(-0.5) and FeOMo(OH)(5)(-0.5), were respectively the dominant complexes of adsorbed W and Mo on goethite 110 faces at low pH. The model suggests that Mo and W are retained mainly by the formation of monodentate complexes on the goethite surface. Our results indicate that surface complexation modeling may have applications in predicting competitive adsorption in more complex systems containing multiple competing ions.  相似文献   
67.
Organochlorine pesticides in soil profiles from Tianjin, China   总被引:17,自引:0,他引:17  
Wang X  Piao X  Chen J  Hu J  Xu F  Tao S 《Chemosphere》2006,64(9):1514-1520
Soil cores were collected from soils at five sites in Tianjin area for the determination of hexachlorocyclohexane isomers (HCHs, including alpha-HCH, beta-HCH, gamma-HCH and delta-HCH), dichlorodiphenyltrichloroethane and metabolites (DDXs, including p,p'-DDT, p,p'-DDE and p,p'-DDD) and total organic carbon (TOC). The levels and vertical distributions of HCHs and DDXs are studied. Results show that the application of pesticides in the past years was the major contributor of HCHs and DDXs accumulation in the sampling areas. Significant positive correlations were seen between the residual and application amounts of HCHs and DDXs. Wastewater irrigation did not bring a significant contribution of HCHs or DDXs into the soils. HCHs and DDXs concentrations peak at the surface and decline in soil profile with depth, while fluctuations were observed in the plow layers of some cultivated soils caused by frequent cultivation activities and batch irrigation. Positive correlations were observed between the contents of TOC and HCHs and DDTs. Although the amounts of HCHs application in all sampling sites are larger than DDXs, at surface and near surface layers of most sampling sites, the concentrations of summation operatorHCHs are lower than summation operatorDDXs. The composition of DDXs in the applied pesticides and sampled soils indicates that there is no recent DDT input at the sample areas.  相似文献   
68.
Several methods to prepare a biodesulfurization (BDS) biocatalyst were investigated in this study using a strain of Rhodococcus sp. 1awq. This bacterium could selectively remove sulfur from dibenzothiophene (DBT) via the "4S" pathway. DBT, dimethylsulfoxide (DMSO), sodium sulphate and mixed sulfur sources were used to study their influence on cell density, desulfurization activity, desulfurization ability, and the cost of biocatalyst production. In contrast to that observed from bacteria cultured in DBT, only partial desulfurization activity of strain 1awq was induced by DBT after cultivation in a medium containing inorganic sulfur as the sole sulfur source. The biocatalyst, prepared from culture with mixed sulfur sources, was found to possess desulfurization activity. With DMSO as the sole sulfur source, the desulfurization activity was shown to be similar to that of bacteria incubated in medium with DBT as the sole sulfur source. The biocatalyst prepared by this method with the least cost could remove sulfur from hydrodesulfurization (HDS)-treated diesel oil efficiently, providing a total desulfurization percent of 78% and suggesting its cost-effective advantage.  相似文献   
69.
利用粉煤灰中活性炭的吸附能力治理含铬废水   总被引:4,自引:0,他引:4  
通过实验研究指出,运用粉煤灰可同时治理含铬废水中Cr(Ⅲ)和Cr(Ⅵ)。结果表明,粉煤灰用量、废液酸度、振荡时间和温度等均对铬的去除效果存在一定影响。研究揭示,在常温(15~35℃)下,当粉煤灰的掺人比例为1:650、含铬废液pH为4.0~5.5、接触时间为40min时,粉煤灰可同时治理含铬废水中Cr(Ⅲ)和Cr(Ⅵ),其中Cr(Ⅵ)的去除率在88%左右,Cr(Ⅲ)的去除率可达99%以上。该方法工艺简单,成本低廉,效果优良,具有较好的应用前景。  相似文献   
70.
钛白副产硫酸亚铁的综合利用研究   总被引:3,自引:0,他引:3  
以钛白副产硫酸亚铁、氯化钾和氨水为原料,采用硫酸钾铵法制取硫酸钾。实验结果表明,该工艺生产的产品,其质量达到ZBG-21006-89国家标准,且此工艺流程简单、操作方便、条件易控制,无二次污染。  相似文献   
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