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991.
Experimental Characterization of Atmospheric Diffusion in Complex Terrain with Land-Sea Interactions
M. M. Mill´n E. Otamendi L. A. Alonso I. Ureta 《Journal of the Air & Waste Management Association (1995)》2013,63(7):807-811
The body of information presented in this paper is directed to scientists working in atmospheric dispersion research and model development. Two years of field measurements in the coastal area of Bilbao in northern Spain show that the diffusion behavior in this complex terrain can be classified into several well defined patterns, which correspond to certain meteorological conditions. The approach taken has been the systematic use of SO2 remote sensors (COSPEC) and ground level monitors in moving platforms which are used to follow and document the flow of the air mass. Results to date show that complex reentry cycles can occur and that synoptically different flows may be indistinguishable by wind sensors at ground level (affected by channeling), and yet result in totally different observed pollution levels by a fixed monitoring network (affected by topographical effects). These results are being used to parameterize the cause-effect relationships and guide the modeling efforts in this area of complex terrain. 相似文献
992.
J. L. Jones E. A. Sckuck R. W. Eldridge N. Endow F. W. Cranz 《Journal of the Air & Waste Management Association (1995)》2013,63(2):73-77
While snowflakes fell and Christmas carols heralded the imminent holiday, over 3000 delegates to the Third National Conference on Air Pollution were told to “Control Now for Clean Air.” They were told this in many ways by many people—by the Vice President of the United States; by the Secretary of the Department of Health, Education, and Welfare who summoned the Conference; and by senators, congressmen, governors, and mayors. Then eight panel sessions convened to discuss and to determine how to control now for clean air. Speakers from every section of American life addressed themselves to this subject; when they were finished, the eight session chairmen summarized what had been said, what had been, learned. These summaries appear on the following pages. 相似文献
993.
F. Sarasini D. Puglia E. Fortunati J. M. Kenny C. Santulli 《Journal of Polymers and the Environment》2013,21(3):881-891
In the present study, Phormium Tenax fiber reinforced PLA composites were processed by injection molding and twin screw compounding with a fiber content ranging from 10 to 30 wt%. Three surface treatment methods have been used to improve the Phormium Tenax fiber-matrix interfacial bonding that are as follows: (1) aqueous alkaline solution, (2) silane coupling agent, and (3) a combination of alkaline and silane treatment. The mechanical, thermal and morphological properties of the resulting composites were investigated. The results have shown that the moduli of surface treated fiber reinforced composites are lower than the ones obtained for untreated composites (as a consequence of the decrease in fiber modulus caused by the chemical treatments) and no significant increase in strength was observed for any of the composites compared to neat PLA. SEM micrographs of composite fractured surfaces confirmed an improvement in the interfacial strength, which was insufficient nonetheless to significantly enhance the mechanical behavior of the resulting composites. Results from thermogravimetric analysis and differential scanning calorimetry suggest that surface treatment of Phormium affects the ability of PLA to cold crystallize, and the thermal stability of the composites at the different fiber contents was reduced with introduction of alkali and silane treated Phormium fibers. 相似文献
994.
Charles S. Maneri P. E. William H. Megonnell P. E. 《Journal of the Air & Waste Management Association (1995)》2013,63(5):374-377
The proposed By-law changes have been suggested over the last two years. They are basically housekeeping changes which correct the language, eliminate duplications, and clarify the dates for the receipt and acceptance of the ballots for nominees for the Board. The major revision proposed is in Article XV of the Technical Council which was necessitated by the new structure of the Technical Council approved by the Board of Directors in June 1970. 相似文献
995.
Jason A. Dittman James B. Shanley George R. Aiken Janet E. Towse 《Environmental pollution (Barking, Essex : 1987)》2009,157(6):1953-1956
Stream water samples were collected over a range of hydrologic and seasonal conditions at three forested watersheds in the northeastern USA. Samples were analyzed for dissolved total mercury (THgd), DOC concentration and DOC composition, and UV254 absorbance across the three sites over different seasons and flow conditions. Pooling data from all sites, we found a strong positive correlation of THgd to DOC (r2 = 0.87), but progressively stronger correlations of THgd with the hydrophobic acid fraction (HPOA) of DOC (r2 = 0.91) and with UV254 absorbance (r2 = 0.92). The strength of the UV254 absorbance-THgd relationship suggests that optical properties associated with dissolved organic matter may be excellent proxies for THgd concentration in these streams. Ease of sample collection and analysis, the potential application of in-situ optical sensors, and the possibility for intensive monitoring over the hydrograph make this an effective, inexpensive approach to estimate THgd flux in drainage waters. 相似文献
996.
Ivan Kourtchev Iustinian Bejan John R. Sodeau John C. Wenger 《Atmospheric environment (Oxford, England : 1994)》2009,43(20):3182-3190
The gas-phase ozonolysis of (E)-β-farnesene was investigated in a 3.91 m3 atmospheric simulation chamber at 296 ± 2 K and relative humidity of around 0.1%. The relative rate method was used to determine the reaction rate coefficient of (4.01 ± 0.17) × 10?16 cm3 molecule?1 s?1, where the indicated errors are two least-squares standard deviations and do not include uncertainties in the rate coefficients for the reference compounds (γ-terpinene, cis-cyclooctene and 1,5-cyclooctadiene). Gas phase carbonyl products were collected using a denuder sampling technique and analyzed with GC/MS following derivatization with O-(2,3,4,5,6-pentafluorobenzyl) hydroxylamine (PFBHA). The reaction products detected were acetone, 4-oxopentanal, methylglyoxal, 4-methylenehex-5-enal, 6-methylhept-5-en-2-one, and (E)-4-methyl-8-methylenedeca-4,9-dienal. A detailed mechanism for the gas-phase ozonolysis of (E)-β-farnesene is proposed, which accounts for all of the products observed in this study. The results of this work indicate that the atmospheric reaction of (E)-β-farnesene with ozone has a lifetime of around 1 h and is another possible source of the ubiquitous carbonyls, acetone, 4-oxopentanal and 6-methylhept-5-en-2-one in the atmosphere. 相似文献
997.
Ohne Zusammenfassung
Verantwortliche Herausgeber: Jan Schwarzbauer · Peter Heininger · Evelyn Claus 相似文献
998.
The use of transparency as camouflage in the epipelagic realm is complicated by the presence of ultraviolet radiation, because
the presence of UV-protective pigments decreases UV transparency and may reveal transparent zooplankton to predators and prey
with UV vision. During July 1999, September 1999, and June 2000, transparency measurements (from 280 to 500 nm) were made
on living specimens of 15 epipelagic (collection depth: 0–20 m, average: 11 ± 1 m) and 19 mesopelagic (collection depth: 150–790 m,
average: 370 ± 40 m) species of transparent zooplankton from Oceanographer Canyon and Wilkinson Basin in the Northwest Atlantic
Ocean. In addition, measurements of downwelling irradiance (from 330 to 500 nm) versus depth were made. The tissues from epipelagic
zooplankton had lower UV transparency than those from mesopelagic zooplankton, while the average visible transparency (at
480 nm) of the two groups was not significantly different. Percent transparency was positively correlated with wavelength
over most of the measured range, with a rapid decrease below a certain cutoff wavelength. In mesopelagic tissues, the cutoff
wavelength was generally 300 nm. In epipelagic tissues, the cutoff wavelength was between 300 and 400 nm. Twelve out of 19
epipelagic tissues had transparencies at 320 nm that were half or less than their 480 nm transparency values, versus only
4 out of 21 mesopelagic tissues. The effects of UV absorption on UV visibility and minimum attainable depth were modeled using
contrast theory and the physics of light attenuation. Because UV absorption was generally significantly greater in the UVB
than in the UVA spectrum (where UV vision occurs), and because the highest UV absorption was often found in less transparent
individuals, its modeled effects on visibility were slight compared to its effects on minimum attainable depth.
Received: 14 April 2000 / Accepted: 16 November 2000 相似文献
999.
1000.
James Burdon Michael H.B. Hayes Malcolm E. Pick 《Journal of environmental science and health. Part. B》2013,48(1):37-51
Abstract Charge distributions in 1, 1'‐ethylene‐2, 2'‐bipyridylium (diquat), 1,1'‐dimethyl‐4,4'‐bipyridylium (paraquat) and 1‐methylpyridinium organocations were calculated by a Complete Neglect of Differential Overlap semi‐empirical quantum mechanical procedure. The data show that the positive charges in the organocations are distributed around the molecules and are greatest in the positions ortho and para to the heterocyclic nitrogen atoms. Earlier interpretations of the mechanisms of adsorption of paraquat and diquat by soils and clays assumed that the charges were located in the heterocyclic nitrogen atoms. Here some consideration is given to the influence of the charge delocalizations on the processes of adsorption by montmorillonite and vermiculite clay preparations. 相似文献