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991.
992.
Bojidarka Ivanova Michael Spiteller 《Environmental science and pollution research international》2014,21(2):1548-1563
Since primary environmental concept for long storage of nuclear waste involved assessment of water in uranium complexes depending on migration processes, the paper emphasized solid-state matrix-assisted laser desorption/ionization (MALDI) mass spectrometric (MS) and IR spectroscopic determination of UO2(NO3)2·6H2O; UO2(NO3)2·3H2O, α-, β-, and γ-UO3 modifications; UO3·xH2O (x?=?1 or 2); UO3·H2O, described chemically as UO2(OH)2, β- and γ-UO2(OH)2 modifications; and UO4·2H2O, respectively. Advantages and limitation of vibrational spectroscopic approach are discussed, comparing optical spectroscopic data and crystallographic ones. Structural similarities occurred in α–γ modifications of UO3, and UO2(OH)2 compositions are analyzed. Selective speciation achieved by solid-state mass spectrometry is discussed both in terms of its analytical contribution for environmental quality assurance and assessment of radionuclides, and fundamental methodological interest related the mechanistic complex water exchange of UO3·H2O forms in the gas phase. In addition to high selectivity and precision, UV-MALDI-MS, employing an Orbitrap analyzer, was a method that provided fast steps that limited sample pretreatment techniques for direct analysis including imaging. Therefore, random and systematic errors altering metrology and originating from the sample pretreatment stages in the widely implemented analytical protocols for environmental sampling determination of actinides are significantly reduced involving the UV-MALDI-Orbitrap-MS method. The method of quantum chemistry is utilized as well to predict reliably the thermodynamics and nature of U–O bonds in uranium species in gas and condensed phases. 相似文献
993.
Many think doing animal ethics demands we see moral humanism as a speciesist prejudice of the kind found with sexism and racism. The only serious case for this rests on the Argument from Marginal Cases. We find that argument to the point, but show that properly understood it supports humanism. Understanding why it does this lets us see how we ought to go on in animal ethics. 相似文献
994.
A supportive attitude of residents towards protected areas is crucial for successful implementation and management, particularly in densely populated regions such as Central Europe. While previous studies have revealed that emotional and cultural drivers, as well as information level and group membership, can influence attitudes towards protected areas, the effect of place-attachment dimensions remains unclear. A postal survey among local residents (N = 460) explored factors influencing attitudes towards the Lungau (-Nockberge) Biosphere Reserve in Austria before its official recognition. Results indicated societal support throughout all socio-demographic strata. A logistic regression showed that, besides socio-demographics and information level, place attachment had a significant influence on the acceptance of the biosphere reserve. Supporters and opponents showed both high place identity and dependence, while waverers scored low on these dimensions. Results indicate that place attachment is relevant for the design of participatory processes as well as for developing management policies for biosphere reserves. 相似文献
995.
Coastal environments, such as marshes, dunes, or estuaries, are characterized by their high natural values that usually cause them to be subjected to high protection levels, affecting activities taking place within them. This is why the action in these spaces must be based on the use of proper techniques and approaches, which integrate ecology with practical engineering necessities. In this context, the Department of Sciences and Techniques of the Water and Environment of the University of Cantabria, through methods developed in the natural reserve of the Salt Marshes of Santoña and Noja, proposes the use of a working methodology based on the discipline of “ecosystem management” combined with the “adaptive management” methodologies; the application of mathematical, statistical, and specific predictive instruments; and the utilization of an “ecologic niche” as a union between the scientific knowledge of the littoral environments and the true actuation scale of the projects and activities carried out within them. 相似文献
996.
Evaluation of olive oil mill wastewater toxicity on spinach 总被引:1,自引:1,他引:0
Asfi M Ouzounidou G Moustakas M 《Environmental science and pollution research international》2012,19(6):2363-2371
Background, aim, and scope
Olive oil mill wastewater (OMW), a by-product of the olive oil extraction process, is annually produced in huge amounts in olive-growing areas and represents a significant environmental problem in Mediterranean areas. We studied the impact of OMW dilutions (1:20 and 1:10) on spinach plants in order to evaluate OMW dilutions as a low-cost alternative method for the disposal of this waste.Materials and methods
The effects of OMW dilutions were evaluated on seed germination, shoot and root elongation, biomass production, nutrient uptake and translocation, ascorbic acid content, polyphenols, photosynthetic pigments, and photosynthetic performance of spinach.Results
Plant biomass was more affected than plant height and total chlorophyll; carotenoid and ascorbic acid content progressively decreased with decreasing OMW dilution. Exposure to both OMW dilutions resulted in overaccumulation of total polyphenols, which were negatively correlated to plant biomass and nutrients. Nutrient (Fe, Ca, and Mg) content was insufficient leading to reduced growth. Water use efficiency decreased mainly due to decreased CO2 assimilation rate rather than to a decline of transpiration rate. Disturbances in photosystem II (PSII) photochemical efficiency could be better envisaged by the ratio between variable fluorescence and initial fluorescence (Fv/Fo), which showed much greater amplitude than the maximal photochemical efficiency of PSII photochemistry (Fv/Fm).Conclusions
From the data obtained, it is suggested that 1:20 OMW dilutions are still phytotoxic and that higher OMW dilutions should be used in order to use this waste for the irrigation of spinach plants. 相似文献997.
Karakaya and Sultansuyu Dam Lakes, located in the eastern part of Turkey, are important water sources, both for irrigation
and fishery. The main goal of the study was to investigate water qualities of dam lakes using a set of biomarkers in the fish
Cyprinus carpio. For this aim, field sample and laboratory-acclimated fish were compared to identify changes in selected biomarkers. The
activities of ethoxyresorufin-O-deethylase, glutathione S-transferase, glutathione reductase, and carboxylesterase were determined in liver samples. Also, plasma and liver lactate
dehydrogenase, aspartate aminotransferase, and alanine aminotransferase activities were assayed. Brain acetylcholinesterase
and carboxylesterase activities were also determined. The hepatosomatic index and condition factors were calculated. Plasma
vitellogenin assays were evaluated for the presence of xenoestrogen. Physicochemical values of water samples showed the existence
of eutrophication risk, and also, some chemicals in both lakes were determined to be over tolerable limits. The comparisons
of samples from both dam lake and laboratory-acclimated fish showed that the lakes may be at risk of pollution by some xenobiotics,
namely xenoestrogens and acetylcholinesterase-inhibiting agents. 相似文献
998.
999.
Candice DeLeo Caio Augusto Pinotti Maria do Carmo Gonçalves Sachin Velankar 《Journal of Polymers and the Environment》2011,19(3):689-697
Plasticized starch (PLS) is a renewable, degradable, and inexpensive polymer, but it suffers from poor mechanical properties.
The mechanical properties can be improved by blending PLS with polyolefins, nonetheless, at high PLS content, the mechanical
properties remain poor. Here we show that addition of clay can greatly improve the mechanical properties of PLS/polypropylene
blends at high starch content. Unmodified and organically modified montmorillonite clays, MMT and Cloisite 30B respectively,
were added to blends of glycerol-plasticized starch and polypropylene, compatibilized using maleated polypropylene. TEM indicates
that MMT is well dispersed in the PLS phase of the blends, while Cloisite 30B is located both within the PLS phase as well
as at the interface between PLS and PP. At high PLS content, the addition of clay increased the tensile strength and tensile
modulus by an order of magnitude, while reducing the ultimate elongation only slightly. Such improvements are attributable
to both the addition of clay as a reinforcing component, as well as to the change in the two phase morphology due to addition
of clay. 相似文献
1000.
A 2D analytical turbulent diffusion model for particle dispersion and deposition at different heights along the pipe flow
and circumferential deposition has been developed. This liquid–solid turbulent diffusion model presented in this paper has
emanated from an existing gas–liquid turbulent diffusion model. This model can be used as a handy tool for quick estimation
one and two-dimensional deposition fluxes of particles in water distribution networks. A comprehensive 3D numerical investigation
has been carried out using multiphase mixture model available in “Fluent 6.2” to verify the above analytical model. Different
particles sizes and densities were used for 3D numerical investigations. The deposition was studied as a function of particle
diameter, density, and fluid velocity. The deposition of particles, along the periphery of the pipe wall and at different
depths, was investigated. Both the models findings matched with qualitative phenomena such as deposition of heavier particles
at the bottom of the pipe wall were higher at lower velocities and lower at higher velocities. The lighter particles were
found mostly suspended with homogeneous distribution. Smaller particles were also suspended with marginal higher concentration
near the bottom of the pipe wall. This marginal higher concentration of the smaller particles was found to be slightly pronounced
for lower velocity. These analogies of particles are well discussed with the ratio between free-flight velocity and the gravitational
settling velocity. Extended analytical model results were compared with the 3D computational fluid dynamics simulation results.
Discrepancies in the model results were discussed. 相似文献