Biohydrogen production through fermentation using liquid swine manure as substrate

In this paper, continuous production of hydrogen through fermentation with liquid swine manure as substrate was researched using a semi-continuously fed fermenter (8 L in total volume and 4 L in working volume). The pH and temperature for the fermenter were controlled at 5.3 +/- 0.1 and 35 +/- 1 degrees C, respectively, throughout the experiment. Three hydraulic retention times (16, 20, and 24 h) were investigated for their impact on the efficiency and performance of the fermenter in terms of hydrogen yields. The results indicate that hydraulic retention time (HRT) has a strong influence on the fermenter performance. An increasing HRT would increase the variation in hydrogen concentration in the offgas. To produce hydrogen with a fairly consistent concentration, the HRT of the fermenter should not exceed 16 h, which, however, did not appear to be short enough to control methanogenesis because the offgas still contained about 5% methane. When methane content in the offgas exceeded 2%, an inverse linear relationship between hydrogen and methane was observed with a correlation coefficient of 0.9699. To increase hydrogen content in the offgas, methane production has to be limited to below 2%. Also, keeping oxygen content in the fermenter below 1.5% would increase the hydrogen concentration to over 15%. The product to substrate ratio was found to be around 50% for the fermenter system studied, evidenced by the observation that for every 6 liters of manure fermented, 3 liters of pure hydrogen were produced, which was significant and encouraging.     

Source apportionment of fine particles in Tennessee using a source-oriented model

Source apportionment of fine particles (PM2.5, particulate matter < 2 microm in aerodynamic diameter) is important to identify the source categories that are responsible for the concentrations observed at a particular receptor. Although receptor models have been used to do source apportionment, they do not fully take into account the chemical reactions (including photochemical reactions) involved in the formation of secondary fine particles. Secondary fine particles are formed from photochemical and other reactions involving precursor gases, such as sulfur dioxide, oxides of nitrogen, ammonia, and volatile organic compounds. This paper presents the results of modeling work aimed at developing a source apportionment of primary and secondary PM2.5. On-road mobile source and point source inventories for the state of Tennessee were estimated and compiled. The national emissions inventory for the year 1999 was used for the other states. U.S. Environmental Protection Agency Models3/Community Multi-Scale Air Quality modeling system was used for the photochemical/secondary particulate matter modeling. The modeling domain consisted of a nested 36-12-4-km domain. The 4-km domain covered the entire state of Tennessee. The episode chosen for the modeling runs was August 29 to September 9, 1999. This paper presents the approach used and the results from the modeling and attempts to quantify the contribution of major source categories, such as the on-road mobile sources (including the fugitive dust component) and coal-fired power plants, to observed PM2.5 concentrations in Tennessee. The results of this work will be helpful in policy issues targeted at designing control strategies to meet the PM2.5 National Ambient Air Quality Standards in Tennessee.     

Genetic, morphological, and chemical divergence in the sponge genus Latrunculia (Porifera: Demospongiae) from New Zealand

We undertook a comprehensive study of Latrunculia in New Zealand to determine the relationship between taxonomic, environmental, and chemical variation within the genus. Sponges were collected from five locations around New Zealand: Three Kings Islands, Tutukaka, Wellington, Kaikoura, and Doubtful Sound. Allozyme electrophoresis at nine polymorphic loci indicated that sponges from each geographic location were genetically distinct, and that they displayed genetic differences of the magnitude usually associated with reproductively isolated species (Nei's D between locations =0.375-2.476). Additionally, the comparisons revealed that the green and brown colour morphs of Latrunculia that are sympatric at Three Kings Islands and Kaikoura are distinct from each other, and that there are two genetic groups within the green sponges in Doubtful Sound. On the basis of genetic data we conclude that there are at least eight species of Latrunculia in New Zealand waters, not one to four as had been previously thought. Morphological comparisons of the eight genetic species based on skeletal characters (i.e. skeletal organisation of the choanosome, spicule composition, size, and geometry) indicated that the eight Latrunculia species fell into only two morphological groups that could be easily diagnosed on the basis of discorhabd type. Within these two primary morphological groups, skeletal characteristics among the eight species largely overlap and are not diagnostic. These findings emphasise the limitations of traditional taxonomic methods based solely on skeletal characters for distinguishing species of Latrunculia. However, multivariate analysis (MANOVA and CDA) based on six measured skeletal variables did reveal significant morphological variation among the species (Pillai's Trace=3.28, F=6.90, P<0.0001), supporting the division of the genus into eight species. Comparisons of chemical extracts from Latrunculia also showed that the amounts of five different bioactive compounds (discorhabdins A, B, C, D, and J) varied predictably among the eight species. This finding suggests that discorhabdin variation within Latrunculia, previously thought to be associated with intra-specific environmental variability, is more likely to reflect differences among species rather than phenotypic plasticity. Our results also highlight the importance of thorough taxonomic studies associated with marine natural products research to understand fully the variation in bioactive properties among individuals. The potential processes underlying the unusually high speciation rates in New Zealand Latrunculia that are indicated in our study are discussed.     

An ecological framework for contextualizing carnivore–livestock conflict

Carnivore predation on livestock is a complex management and policy challenge, yet it is also intrinsically an ecological interaction between predators and prey. Human–wildlife interactions occur in socioecological systems in which human and environmental processes are closely linked. However, underlying human–wildlife conflict and key to unpacking its complexity are concrete and identifiable ecological mechanisms that lead to predation events. To better understand how ecological theory accords with interactions between wild predators and domestic prey, we developed a framework to describe ecological drivers of predation on livestock. We based this framework on foundational ecological theory and current research on interactions between predators and domestic prey. We used this framework to examine ecological mechanisms (e.g., density-mediated effects, behaviorally mediated effects, and optimal foraging theory) through which specific management interventions operate, and we analyzed the ecological determinants of failure and success of management interventions in 3 case studies: snow leopards (Panthera uncia), wolves (Canis lupus), and cougars (Puma concolor). The varied, context-dependent successes and failures of the management interventions in these case studies demonstrated the utility of using an ecological framework to ground research and management of carnivore–livestock conflict. Mitigation of human–wildlife conflict appears to require an understanding of how fundamental ecological theories work within domestic predator–prey systems.     

Patterns of Giving and Receiving Help During Severe Winter Conditions: A Research Note

Severe winter conditions and blizzards may cause persons to be stranded, unable to move from one place to another. Being stranded under such conditions can be life-threatening and often requires help. This is a study of giving and receiving help among people who were stranded during severe winter conditions and blizzards in Bowling Green, Ohio, USA and the surrounding countryside in 1976–1977. Mail questionnaire data were collected from the Bowling Green, Ohio telephone directory which included listings from both rural and urban areas. The family, followed by friends and neighbors, were most important in the giving and receiving of help. There was little difference between the responses of rural and urban residents. Propinquity was found to be an important intervening variable.     

LAKE EVAPORATION STUDIES USING SATELLITE THERMAL INFRARED DATA1

Thermal infrared radiation data were acquired by the Heat Capacity Mapping Mission (HCMM) satellite over the surface area (385 km²) of Utah Lake during periodic overpasses in 1978 and 1979. The thermal infrared data were converted to lake surface temperatures which were subsequently used in correlations with lake evaporation. Correlations between HCMM surface temperature and pan-derived evaporation exceeded r = 0.90 when HCMM night and day/night average temperatures and two-day average evaporation values were tested. Similar regression studies were done using monthly data from a conceptual evaporation model and the evaporation pan versus monthly HCMM temperature data. In this test both the HCMM day and night monthly temperature versus the monthly model or pan evaporation had correlations exceeding r = 0.95. Empirical estimates of both short and long term lake evaporation using satellite thermal infrared data seem feasible. Attempts to use the HCMM thermal information as direct input to a theoretical approach to calculating evaporation were inconclusive; however, a definite potential seems to exist.     

Unraveling the mysteries of gender differences in intentions to leave the organization

The anticipated labor shortages of the 1990's will intensify organizational needs to retain their existing employees. Women represent an increasingly important segment of the labor force and their turnover rates are thought to exceed men's. Earlier studies of turnover and its psychological antecedent, the behavioral intention to leave, suggest that work-related factors may contribute to women's relatively higher turnover rates. The current paper reports the results of a study of the intentions of male and female executives, managers and professionals to leave their organizations. The results support the pattern of findings in earlier studies that gender differences disappear when job satisfaction is controlled in the analysis. Further analysis highlights the importance of two components of job satisfaction — meaningful work and opportunities for promotion. The authors conclude that organizations might improve their retention rates of female managers through job enrichment and by enhancing their advancement opportunities.     

INFILTRATION EVALUATION OF FOUR MECHANICAL RAINFALL SIMULATION TECHNIQUES IN SIERRA NEVADA WATERSHEDS1

ABSTRACT: Little quantitative site-specific infiltration, runoff and sediment transport data for Tahoe Basin soils under varying storm events or stage of development are available. Modular (Ml), F-type (M2), Impact nozzle (M3), and Impact-Fan nozzle (M4) rainfall simulators were evaluated as to their practicality and ability to characterize infiltration for the Cagwin Soil Series within the Tahoe Basin. Three slope (0–15,15–30, >30%) and four plot conditions (natural with duff [P1], natural without duff [P2], disturbed without duff [P3], and disturbed with duff [P4]) were studied. The measured data were incorporated into a modified Philip's infiltration model and multiple non-linear regression analyses were used to examine relationships between method, slope, plot condition, and infiltration characteristics.^t Simulation methods Ml and M4 produced statistically similar (P=0.01) infiltration data, as did M2 and M3 which produced lower infiltration rates. All were found suitable for use in Sierra Nevada watersheds. Ml was considered most practical. Slope had negligible effect on infiltration. The plot condition was found to significantly influence infiltration, and the effect of each plot condition was significantly different. Final infiltration rates ranged from 4.7 to 6.2 cm/hr. Thus, the Cagwin soil demonstrated moderate to high infiltration rates even when exposed to extreme storm conditions (8–10 cm/hr).