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51.
M. A. Tantawy Salwa A. Ahmed Elham M. Abdalla Mostafa I. Qassim 《Journal of Material Cycles and Waste Management》2016,18(2):263-272
This work aims to study the influence of thermal treatment of Cu2+ laden kaolin wastes on its immobilization efficiency in cement paste. Compressive strength and toxicity characteristic leaching procedure (TCLP) of 5–20 % kaolin waste blended cement pastes were tested. X-ray diffraction (XRD) results illustrate that adsorption of Cu2+ ions modify the crystal structure of kaolinite mineral. Fourier transform infrared (FTIR) results indicate that the adsorption sites on the kaolin surface that were occupied with free water molecules have been replaced with Cu2+ ions adsorbed from aqueous solutions. The thermal treatment of kaolin waste improves fixation ratio of Cu2+ in cement pastes containing up to 20 % of thermally treated waste. This is due to: pozzolanic activity of calcined kaolin, conversion of leachable adsorbed Cu2+ ions into encapsulated unleachable phase that does not retard the hydration of cement as well as adsorption of much of leachable Cu2+ ions on surfaces of hydration products and occlusion in its lattice structure as illustrated from XRD, FTIR, thermogravimetric, scanning electron microscopy and TCLP results. The fixation ratio of Cu2+ in cement paste blended with 20 % of thermally treated kaolin waste, reaches maximum value of about 97 % compared to 82 % for cement paste blended with 20 % of untreated kaolin waste. 相似文献
52.
Messaoudi I Deli T Kessabi K Barhoumi S Kerkeni A Saïd K 《Environmental monitoring and assessment》2009,156(1-4):551-560
The present study illustrates an analysis of spinal deformities associated with metal accumulation in natural populations of Zosterisessor ophiocephalus derived from polluted (S1) and unpolluted (S2) areas in the Gulf of Gabès in Tunisia. Three basic types of spinal deformities were detected: kyphosis, scoliosis and lordosis. These basic deformities frequently co-occur. Spinal deformities were observed in 10.72% of the total examined fish (n = 494). Deformed fish were 3.85 times more frequent in S1 than in S2. In both sexes, the highest occurrence of deformities was observed in the 111-120 mm class decreasing thereafter with fish length. Hepatic concentrations of cadmium (Cd), copper (Cu) and zinc (Zn) were significantly higher in Z. ophiocephalus from S1 than those from S2. Comparisons between fish in each site showed that liver concentrations of Cd and Zn were significantly higher in deformed fish than in normal fish. The relationship between metals accumulation and observed spinal deformities as well as the suitability of this kind of studies for environmental monitoring are discussed. 相似文献
53.
S.M.A.D. Zayed I.Y. Mostafa A.E. El‐Arab 《Journal of environmental science and health. Part. B》2013,48(1):169-175
Abstract 14C‐p,p'‐DDT‐bound residues in soil can be released by treatment with concentrated sulphuric acid at ambient temperatures. Within 6 days, about 70% of the bound residues was released. Bound residues released after 9 months incubation with 14C‐DDT showed the presence of DDT and DDE only while bound residues released after 18 months, contained in addition 13% DDD. Release of bound 14C‐residues also occurs readily following inoculation of the soil‐bound residues with fresh soil or with individual microorganisms. Almost complete release of bound residues was observed after incubation for 45 days. The rate of release was rapid during the first two weeks and decreased thereafter. TLC and HPLC analysis showed that the released residues contained DDE (about 80%) and a smaller amount of DDD. The disappearance of DDT from the released residues may be attributed to its microbiological degradation to DDE and DDD, shortly after its release. 相似文献
54.
Mostafa Lamhamdi Ahmed Bakrim Noureddin Bouayad Ahmed Aarab René Lafont 《Environmental science and pollution research international》2013,20(10):7377-7385
Spinach extracts contain powerful natural antioxidants and have been used to improve the response of animal cells to various stress factors. The aim of the present study was to assess the effects of a methanolic extract of spinach (SE) used at two concentrations (21.7 and 217 ppm) on the growth, certain enzymes and antioxidant systems in wheat seedlings under lead stress. When wheat seedlings were grown for 7 days in a solution containing Pb(NO3)2 (3 mM), germination and growth were impaired, while signs of oxidative stress were observed. SE (217 ppm) pretreatment was able to protect seedlings from Pb toxicity by both reducing Pb uptake and Pb-induced oxidative stress. As a consequence, almost normal germination, elongation, biomass and α-amylase activity were restored by SE (217 ppm) pretreatment of wheat seedlings, in spite of the presence of Pb. Our results support the protective role and the antioxidant effect of SE against Pb. These results show an amazing similarity to the effects of SE in animals, which suggests that providing “nutraceuticals” to plants could improve their “health” status. 相似文献
55.
L-Cysteine has protective efficacy in cases of oxidative tissue injury. Sodium valproate is widely used as an anticonvulsant and an antidepressant in spite of hepatotoxicity as side effect. The aim of this study was to evaluate the protective role of L-cysteine in liver toxicity induced by sodium valproate overdose. Release of the hepatic enzymes, aspartate aminotransferase and alanine aminotransferase, and levels of lipid profiles, as well as the oxidative, enzymatic, and non-enzymatic antioxidant were assessed. Liver damage was judged histologically. L-Cysteine decreased the activity of alanine aminotransferase and aspartate aminotransferase, as well as improved the level of lipid profile, increased the enzymatic antioxidant (catalase, superoxide dismutase, glutathione peroxidase and glutathione reductase), and decreased the lipid peroxidation. L-Cysteine administration inhibited liver injury of sodium valproate. 相似文献
56.
Nakhlé KF Cossa D Khalaf G Beliaeff B 《Environmental pollution (Barking, Essex : 1987)》2006,142(1):73-82
The mussel, Brachidontes variabilis, and the limpet, Patella sp., were used as indicators to monitor cadmium, lead and mercury concentrations along the Lebanese coast. Studies were carried out in order to define the best strategy for assessing and minimizing the effects of size and physiological condition on the metal contents of the molluscs, and corrective models were constructed. Metal concentrations in surface water were measured to estimate bioconcentration factors (BCFs). The BCFs varied from 8.3 x 10(3) to 3.4 x 10(4), from 7.5 x 10(3) to 8.0 x 10(3) and from 3.0 x 10(4) to 3.2 x10(4), for Cd, Pb and Hg, respectively. For limpets, BCFs varied from 1.7 x 10(4) to 7.4 x 10(4) for Cd, from 2.5 x 10(3) to 6 x 10(3) for Pb and remained fairly constant at around 10(4) for Hg. The highest BCFs were associated with lowest contamination levels. The results of the geographical survey exhibited a similar large-scale spatial pattern for the two species and followed the metal concentration distributions measured in the waters. 相似文献
57.
In this experimental program, the effects of non-methane organic compounds (NMOCs) on the biological methane (CH4) oxidation process were examined. The investigation was performed on compost experiments incubated with CH4 and selected NMOCs under different environmental conditions. The selected NMOCs had different concentrations and their effects were tested as single compounds and mixtures of compounds. The results from all experimental sets showed a decrease in CH4 oxidation capacity of the landfill bio-cover with the increase in NMOCs concentrations. For example, in the experiment using compost with 100% moisture content at 35 °C without any NMOCs the Vmax value was 35.0 μg . This value was reduced to 19.1 μg when mixed NMOCs were present in the batch reactors under the same environmental conditions. The experimental oxidation rates of CH4 in the presence of single and mixed NMOCs were modeled using the uncompetitive inhibition model and kinetic parameters, including the dissociation constants, were obtained. Additionally, the degradation rates of the NMOCs and co-metabolic abilities of methanotrophic bacteria were estimated. 相似文献
58.
59.
Distribution and Statistical Analysis of Leachable and Total Heavy Metals in the Sediments of the Suez Gulf 总被引:3,自引:0,他引:3
The concentrations of nine heavy metals (Cd, Co, Cr, Cu, Fe, Mn, Ni, Pd and Zn) in the labile and total fractions of muddy
and sandy sediment samples collected from twelve sites in Suez Gulf during April 1999 were studied to evaluate the pollution
status of the Suez Gulf. The enrichment factors (EF) for each element were calculated. There are extremely high concentrations
of Cd, Ni, Pb and slightly concentration of Cr and Cu in both muddy and sandy sediments. The concentration of Zn was moderately
high and can be considered as seriously contaminate Metal pollution index (MPI) shows high values ranged between 46 to 156
and 40 to 232 for both sandy and muddy sediments, respectively. Concentrations of heavy metals were normalized against iron
for total fraction in both of sandy and muddy sediments. Principal component analysis (PCA) was studied on the data matrix
obtained and represented three-factor model explaining 92.22% for labile and 88.82% for total fractions of muddy sediment.
The main source of contamination is the offshore oil fields and industrial wastes. This is largely a result of ineffective
and inefficient operation equipment, illegal discharge of dirty ballast water from tankers and lack of supervision and prosecution
of offenders. 相似文献
60.