Artificial acidification of a non-acidic and an acidic headwater stream in Maine, USA

Two headwater streams with low DOC and different pHs (4.5-4.8 and 5-6.5) were acidified with H2SO4 to pH 4.1 and 4.5, respectively, for 24-h periods. Neutralization of the added acid occurred by protonation of ANC (HCO3-dominated in the higher pH stream), desorption of Ca (< 15 microeq litre(-1)) and Mg (<6 microeq litre(-1)), and desorption and dissolution of AL (<250 microg litre(-1)) from the stream bed. The concentrations of dissolved organic carbon (DOC) remained constant within the experimental reaches. The concentrations of Na, K an H4SiO4 also remained constant, indicating no detectable increase in the rate of chemical weathering in the stream bed. After acid addition was stopped, concentrations of Ca, Mg and Al decreased to below background, indicating reversible ion exchange as the principal mechanism for the mobility of Ca and Mg and to a lesser extent for Al. Repeated acidifications indicated that significant regeneration of cations on the exchange surfaces of the stream substrate occurs rapidly.     

Mechanisms of episodic acidification in low-order streams in Maine, USA

Five factors contribute to episodic depressions in pH and ANC during hydrologic events in low-order streams in Maine: (1) increases of up to 50 microeq litre(-1) NO3; (2) increases of up to 75 microeq litre(-1) organic acidity; (3) increases of as much as 0.3 in the anion fraction of SO4; (4) as much as 100 microeq litre(-1) acidity generated by the salt-effect in soils; and (5) typically < or = 40% dilution by increased discharge. In conjunction with increased discharge, factors 1, 2 or 4 appear necessary to depress pH to less than 5.0. The chemistry of individual precipitation events is irrelevant to the generation of acidic episodes, except those caused by high loading of neutral salts in coastal regions. Increases in discharge, but not necessarily in dilution of solutes, in combination with the chronically high SO4 from atmospheric deposition, provide the antecedent chemical conditions for episodic acidification. Differences in antecedent moisture conditions determine the processes that control output of either ANC or acidifying agents to aquatic systems.     

Nitrogen and Sulfur Input-Output Budgets in the Experimental and Reference Watersheds, Bear Brook Watershed in Maine (BBWM)

Dry (NH4)2SO4 (1,800 eq-1 ha-1 yr-1) has been applied to the western of two contiguous 10 ha catchments at the Bear Brook Watershed in Maine (BBWM) since November, 1989. The initial rapid and significant response in both S and N in West Bear, compared to the reference East Bear, slowed after three years. Annual S retention of the total experimental treatment decreased from 86 to 34%, with a seven year cumulative retention of 59%. Hydrology influences the export flux of S; S is retained more in dry seasons and dry years. The annual retention of N has decreased from 96 to 81%, with a cumulative retention of 82%. The export of N from the reference watershed has declined from 178 to 23 eq-1 ha-1 yr-1 during the treatment period. The treatment N (as NH4) initially stimulated nitrification, and caused pre-existing N to be lost in runoff, rather than the treatment N. Retention of the treatment N has decreased to approximately 80%. The majority of the retained N is stored in the soil, but the reasons for the decreased flux from the reference watershed are not known.     

Assessment of Air Quality, Emissions and Management in a Local Urban Environment

This paper describes one example of how the UK National Air Quality Strategy (NAQS) is implemented in a local urban environment. The paper reviews the beginning of this process, by examining the review and assessment procedures of the NAQS in the London Borough of Barnet. By the application of available UK tools of local air quality management (LAQM), the process began through analysis of the levels of local emissions and progressed onto modelling of current and future air quality. A map showing combined emission hotspot areas for the Borough indicated and higher emission rates occur in the south of the Borough and along the major transport corridors, as road sources dominate emissions. Dispersion modelling studies were also conducted for this purpose, using the screening models GRAM, PGRAM and ADMS Urban for an in-depth assessment. These analyses found that some local point sources and the majority of Borough roads with over 20,000 vehicles per day produced exceedances of the future objectives for air quality for some pollutants.Recommendations for the progression of LAQM in the Borough are made and include the update and expansion of the emissions information held for use in future modelling studies. The paper demonstrates the experience of implementing the Strategy, using the tools and procedures available for this purpose, in a local urban environment that is similar to many in the UK.