Is BDE-175 an important enough component of commercial octabromodiphenyl ether mixtures to be listed in Annex A of the Stockholm Convention?

Commercial octabromodiphenyl ether mixtures, containing hexabromodiphenyl ethers and heptabromodiphenyl ethers were listed in Annex A of the Stockholm Convention on May 2009 (Fourth Conference of the Parties) (UNEP, 2009a). Four compounds are specifically mentioned: 2,2′,4,4′,5,5′-hexabromodiphenyl ether (BDE-153), 2,2′,4,4′,5,6′-hexabromodiphenyl ether (BDE-154), 2,2′,3,3′,4,5′,6-heptabromodiphenyl ether (BDE-175), and 2,2′,3,4,4′,5′,6-heptabromodiphenyl ether (BDE-183). Presumably they were identified as key components of commercial mixtures and found to be present in environmental samples. However, since BDE-175 and BDE-183 co-elute on common HRGC columns, the presence of BDE-175 as an important component in technical octa-BDE mixtures has not been illustrated. The successful HRGC/LRMS separation of a 1:1 mixture of BDE-175 and BDE-183, as well as ¹H NMR analysis of technical material, has allowed us to confirm that this congener is not present in technical products (e.g. Great Lakes DE-79™) in quantifiable amounts.     

Chlorothalonil binding to aquatic humic substances assessed from gas purge studies

Abstract

Fate of the fungicide chlorothalonil (TCIN) binding to dissolved organic acid fractions was quantified using gas‐purge desorption studies. Binding studies were conducted to measure the dissolved organic carbon partition constant (K_DOC) with aquatic fulvic and humic acid fractions purified from cranberry bog water. Desorption studies at DOC concentrations up to 50 mg L^‐1 resulted in mean log K_DOC values of 4.63 (s.d.=0.5, n=8) and 4.81 (s.d.=0.7, n=7) for fulvic and humic acids, respectively. These values deviated from reported K_OC (organic carbon) values by 0.5 to 1.5 orders of magnitude. The relationship between K_OC and K_DOC did not conform to accepted ratios of 10: 1 to 3: 1, although these studies were conducted with the strong hydrophobic fraction of DOC. Binding was rapid suggesting hydrophobic partitioning or weak Van Der Waals forces as binding mechanisms. The strong binding potential for TCIN to aquatic humic substances corresponds to increased solubility in the aqueous system. Sorption to DOC suggests a possible transport mechanism which may result in elevated concentrations of TCIN in cranberry bog systems.     

Resource partitioning by four species of elasmobranchs (Batoidea: Urolophidae) in coastal waters of temperate Australia

Four species of stingarees (Urolophus lobatus, U. paucimaculatus, Trygonoptera personata and T. mucosa) were abundant in samples collected from over sandy substrates in four regions along ∼200 km of the lower west coast of Australia in each season between summer 1990/1991 and winter 1992. The main aim of this study was to determine whether these four species were segregated by habitat, size, sex and/or diet, thereby reducing the potential for intra- and interspecific competition. The densities of U. lobatus and T. personata were almost invariably greater in deep, offshore waters (20 to 35 m) than in shallow, inshore waters (5 to 15 m), while those of U. paucimaculatus were greatest in the southernmost region, irrespective of depth, and those of T. mucosa were highest at the single inshore site at which the water was deep. None of these species was segregated by either size or sex. The volumetric dietary compositions of the two Urolophus species, which consisted predominantly of various crustaceans, and those of the two species of Trygonoptera, which consisted mainly of different polychaetes, were significantly different from each other. The two Urolophus species initially fed largely on amphipods, mysids and carid decapods but, with increasing size, U. lobatus started to ingest teleosts and U. paucimaculatus commenced feeding on errant polychaetes and penaeid decapods. The contribution of errant polychaetes to the diets of T. personata rose progressively from 0% in the smallest fish to 90% in the largest fish, thereby accounting for a concomitant progressive decline in dietary breadth and for intraspecific dietary overlap typically to occur only between successive size classes. In contrast, the volumetric contribution of sedentary polychaetes to the diets of T. mucosa remained high (65 to 80%) throughout life, which accounts for the relatively low and constant dietary breadth of most size classes and a significant overlap in the diets of all but one pair of size classes. The diets of each of the four stingaree species occasionally differed between sites and sometimes underwent seasonal changes, presumably reflecting spatial and temporal differences in the types of prey in the environment. Since the ratios of benthic to epibenthic prey in the diets of the two Trygonoptera species were greater than in those of the two Urolophus species, the first two species apparently forage deeper into the substrate. The combination of partial segregation of the four stingaree species among habitats and the differences in the dietary compositions and feeding strategies of these species, would presumably facilitate the co-existence of these batoid elasmobranchs when they are abundant in the same general region. Received: 29 October 1997 / Accepted: 25 March 1998     

Nitrogen and phosphorus runoff losses from variable and constant intensity rainfall simulations on loamy sand under conventional and strip tillage systems

Further studies on the quality of runoff from tillage and cropping systems in the southeastern USA are needed to refine current risk assessment tools for nutrient contamination. Our objective was to quantify and compare effects of constant (Ic) and variable (Iv) rainfall intensity patterns on inorganic nitrogen (N) and phosphorus (P) losses from a Tifton loamy sand (Plinthic Kandiudult) cropped to cotton (Gossypium hirsutum L.) and managed under conventional (CT) or strip-till (ST) systems. We simulated rainfall at a constant intensity and a variable intensity pattern (57 mm h(-1)) and collected runoff continuously at 5-min intervals for 70 min. For cumulative runoff at 50 min, the Iv pattern lost significantly greater amounts (p < 0.05) of total Kjeldahl N (TKN) and P (TKP) (849 g N ha(-1) and 266 g P ha(-1) for Iv; 623 g N ha(-1) and 192 g P ha(-1) for Ic) than did the Ic pattern. However, at 70 min, no significant differences in total losses were evident for TKN or TKP from either rainfall intensity pattern. In contrast, total cumulative losses of dissolved reactive P (DRP) and NO3-N were greatest for ST-Ic, followed by ST-Iv, CT-Ic, and CT-Iv in diminishing order (69 g DRP ha(-1) and 361 g NO3-N ha(-1); 37 g DRP ha(-1) and 133 g NO3-N ha(-1); 3 g DRP ha(-1) and 58 g NO3-N ha(-1); 1 g DRP ha(-1) and 49 g NO3-N ha(-1)). Results indicate that constant-rate rainfall simulations may overestimate the amount of dissolved nutrients lost to the environment in overland flow from cropping systems in loamy sand soils. We also found that CT treatments lost significantly greater amounts of TKN and TKP than ST treatments and in contrast, ST treatments lost significantly greater amounts of DRP and NO3-N than CT treatments. These results indicate that ST systems may be losing more soluble fractions than CT systems, but only a fraction the total N (33%) and total P (11%) lost through overland flow from CT systems.     

Horizontal movement of ocean sunfish, <Emphasis Type="Italic">Mola mola</Emphasis>, in the northwest Atlantic

Data were retrieved from 25 ocean sunfish (Mola mola) that were tagged with pop-up satellite archival tags in the southern Gulf of Maine (n = 6), off Nantucket Island (n = 17), and off the coast of Georgia (n = 2) between September 2005 and March 2008. Tags remained attached from 7 to 242 days, with a mean attachment period of (X ± SD) 107.2 ± 80.6 days. Ocean sunfish tagged in the Gulf of Maine and southern New England left those areas in the late summer and early autumn and moved south along the continental shelf break. Fish traveled as far south as the Bahamas and the Gulf of Mexico. By moving south, sunfish experienced similar mean sea surface temperatures throughout the tagging period. The maximum straight-line distance traveled by a tagged Mola mola was 2,520 km in 130 days. Two tagged ocean sunfish entered the Gulf of Mexico, one in the December and one in July. Movements were associated with frontal features created by the Gulf Stream and fish moved farther offshore in 2007 when the Gulf Stream was deflected from the shelf break.     

SEQUENT PEAK PROCEDURE: MINIMUM RESERVOIR CAPACITY SUBJECT TO CONSTRAINT ON FINAL STORAGE1

ABSTRACT: When the sequent peak procedure is used to size a reservoir, two cycles of inflows and drafts are analyzed. The use of two cycles results in the identification of the minimum reservoir capacity which, when simulated with the design inflows and drafts, will not only meet demands, but will also result in a final storage which equals or exceeds the initial storage. Demonstration of optimality follows from consideration of a method which is equivalent to the sequent peak procedure.     

Cotton defoliant runoff as a function of active ingredient and tillage

Cotton (Gossypium hirsutum L.) defoliant runoff was recently identified as an ecological risk. However, assessments are not supported by field studies. Runoff potential of three defoliant active ingredients, dimethipin (2,3-dihydro-5,6-dimethyl-1,4-dithiin 1,1,4,4-tetraoxide), thidiazuron (N-phenyl-N-1,2,3-thidiazol-5-yl-urea), and tribufos (S,S,S-tributyl phosphorotrithioate) was investigated by rainfall simulation on strip (ST) and conventionally tilled (CT) cotton in south central Georgia. Simulated rainfall timing relative to defoliant application (1 h after) represented an extreme worst-case scenario; however, weather records indicate that it was not unrealistic for the region. Thidiazuron and tribufos losses were 12 to 15% of applied. Only 2 to 5% of the more water soluble dimethipin was lost. Although ST erosion rates were less, loss of tribufos, a strongly sorbing compound, was not affected. Higher sediment-water partition coefficients (kd) were measured in ST samples. This likely explains why no tillage related differences in loss rates were observed, but it is unknown whether this result can be generalized. The study was conducted in the first year following establishment of tillage treatments at the study site. As soil conditions stabilize, ST impacts may change. Data provide an estimate of the maximum amount of the defoliants that will run off during a single postapplication storm event. Use of these values in place of the default value in runoff simulation models used in pesticide risk assessments will likely improve risk estimate accuracy and enhance evaluation of comparative risk among these active ingredients.