Solubilities of hydrophobic compounds in aqueous-organic solvent mixtures

Solubilities of several hydrophobic organic substances (paradichlorobenzene, endrin, naphthalene, and dibutyl phthalate) in aqueous solutions containing up to 0.10 mole fraction of common alcohols and ketones, were measured by gas chromatography. The solubilities are significantly increased by the alcohols and ketones. The results are interpreted in terms of the association of n molecules of alcohol or ketone with each hydrophobic organic molecule. Values of n and the equilibrium constant for this association are reported for each hydrophobic organic-alcohol and organic-ketone combination. The implications of these results for the disposal of toxic wastes by landfilling is discussed.     

Developing alternative land-use scenarios to facilitate natural resource management across jurisdictional boundaries

Scenario planning is an effective approach for examining possible futures by exploring the implications and consequences of different policy responses to landscape stressors. We present here a case study that explores plausible futures of urban growth in Southern Nevada, USA that illustrates how scenario analysis can be used to inform region-wide resource management by spatially modeling drivers of change, resource impacts, and potential policy responses. Using a suite of energy, water and biodiversity impact models, we assess the outcomes of the various futures on priority resources, resulting in a clear basis of comparison between alternative policies and their potential outcomes. This case study demonstrates the utility of scenario modeling for natural resource management by exploring crucial policy decisions that might be made in the near-term that could have lasting and sometimes conflicting influences on regional resources over the long term.     

Field and laboratory evaluation of the treatment of DNAPL source zones using emulsified zero‐valent iron

Emulsified zero‐valent iron (EZVI) is a surfactant‐stabilized, biodegradable emulsion that forms droplets consisting of a liquid‐oil membrane surrounding zero‐valent iron (ZVI) particles in water. This article summarizes the results obtained during the first field‐scale deployment of EZVI at NASA's Launch Complex 34 (LC34) located on Cape Canaveral Air Force Station, Florida, in August 2002 and presents the results of recent follow‐on laboratory tests evaluating the mechanisms, which contribute to the performance of the technology. The field‐scale demonstration evaluated the performance of EZVI containing nanoscale zero‐valent iron (NZVI) when applied to dense, nonaqueous phase liquid (DNAPL) trichloroethylene (TCE) in the saturated zone. Results of the field demonstration indicate substantial reductions in TCE soil concentrations (greater than 80 percent) at all but two soil boring locations and significant reductions in TCE groundwater concentrations (e.g., 60 percent to 100 percent) at all depths targeted with EZVI. Laboratory tests conducted in 2005 suggest that both NZVI particles and EZVI containing NZVI can provide significant reductions in TCE mass when used to treat TCE DNAPL in small test reactors. However, EZVI was able to reduce TCE concentrations to lower levels than were obtained with NZVI alone, likely as a result of the combined impact of sequestration of the TCE into the oil phase and degradation of the TCE with the NZVI. © 2006 Wiley Periodicals, Inc.     

Jointly estimating survival and mortality: integrating recapture and recovery data from complex multiple predator systems

Environmental and Ecological Statistics - Identifying where, when, and how many animals live and die over time is principal to understanding factors that influence population dynamics....     

Empowered to lead: the role of psychological empowerment in leadership

This study examines the relationship between psychological empowerment and leadership. Empowered supervisors are hypothesized to be innovative, upward influencing, and inspirational and less focused on monitoring to maintain the status quo. Tested on a sample of mid‐level supervisors from a Fortune 500 organization, the hypotheses were largely supported. Supervisors who reported higher levels of empowerment were seen by their subordinates as more innovative, upward influencing, and inspirational. No relationship was found between supervisory empowerment and monitoring behaviours. Implications for theory and practice are discussed, and future research directions are suggested. Copyright © 1999 John Wiley & Sons, Ltd.     

An assessment of public engagement for access management planning in southwestern Alberta,Canada

This paper describes efforts to bridge the gap between the existing research and proposed recreation access management for public lands in southwestern Alberta, Canada. Recreation access management has been identified as a complex problem and public consultation is one element in addressing the complexity. An Internet-based survey (n = 945) examined the acceptability and desirability of public consultation processes to assist with access management planning. Non-parametric tests indicate significant differences in desirability of public consultation types existed for all variables except gender. Respondents expressed the desire for a diversity of public consultation approaches with a strong preference for face-to-face field visits. Mechanisms for engagement in access management planning should be based on public consultation preferences to ensure broad, on going engagement and subsequent user acceptance and compliance.     

Digging Deeper: A Case Study of Farmer Conceptualization of Ecosystem Services in the American South

The interest in improved environmental sustainability of agriculture via biodiversity provides an opportunity for placed-based research on the conceptualization and articulation of ecosystem services. Yet, few studies have explored how farmers conceptualize the relationship between their farm and nature and by extension ecosystem services. Examining how farmers in the Southern Piedmont of South Carolina discuss and explain the role of nature on their farm, we create a detail-rich picture of how they perceive ecosystem services and their contributions to the agroeconomy. Using 34 semi-structured interviews, we developed a detail-rich qualitative portrait of these farmers’ conceptualizations of ecosystem services. Farmers’ conceptualization of four ecosystem services: provisioning, supporting, regulating, and cultural are discussed, as well as articulation of disservices. Results of interviews show that most interviewees expressed a basic understanding of the relationship between nature and agriculture and many articulated benefits provided by nature to their farm. Farmers referred indirectly to most services, though they did not attribute services to biodiversity or ecological function. While farmers have a general understanding and appreciation of nature, they lack knowledge on specific ways biodiversity benefits their farm. This lack of knowledge may ultimately limit farmer decision-making and land management to utilize ecosystem services for environmental and economic benefits. These results suggest that additional communication with farmers about ecosystem services is needed as our understanding of these benefits increases. This change may require collaboration between conservation biology professionals and extension and agriculture professionals to extended successful biomass provisioning services to other ecosystem services.     

Moving from agenda to action: evaluating local climate change action plans

Climate change is conventionally recognised as a large-scale issue resolved through regional or national policy initiatives. However, little research has been done to directly evaluate local climate change action plans. This study examines 40 recently adopted local climate change action plans in the US and analyses how well they recognise the concepts of climate change and prepare for climate change mitigation and adaptation. The results indicate that local climate change action plans have a high level of ‘awareness’, moderate ‘analysis capabilities’ for climate change, and relatively limited ‘action approaches’ for climate change mitigation. The study also identifies specific factors influencing the quality of these local jurisdictional plans. Finally, it provides policy recommendations to improve planning for climate change at the local level.     

Adaptive sampling and analysis programs for contaminated soils

Adaptive sampling and analysis programs (ASAPs) provide a cost-effective alternative to traditional sampling program designs. ASAPs are based on field analytical methods for rapid sample turnaround and field-based decision support for guiding the progress of the sampling program. One common objective of ASAPs is to delineate contamination present in soils, either to support feasibility studies or remedial action designs. An ASAP based on portable gas chromatograph/ mass spectrograph (GC/MS) technologies developed at Tufts University combined with decision support tools created at Argonne National Laboratory was used to delineate explosives contamination in soils at Joliet Army Ammunition Plant, Joliet, Illinois. Tufts' GC/MS technologies provided contaminant-specific identification and quantification with rapid sample turnaround and high sample throughput. Argonne's decision support tools estimated contamination extent, determined the uncertainty associated with those estimates, and indicated where sampling should continue to minimize uncertainty. In the case of Joliet, per sample analytical costs were reduced by 75 percent as compared to the cost of off-site laboratory analyses for explosives. The use of an ASAP resulted in a much more accurate identification and delineation of contaminated areas than a traditional sampling program would have with the same number of samples collected on a regular grid. While targeting explosives contamination in soils at Joliet, the ASAP technologies used in this demonstration have much broader application.