Design and characterization of a two-stage human subject exposure chamber

A human subject exposure chamber, designed to hold six to eight subjects, coupled to an approximately 30-m3 Teflon reaction bag was designed and built to provide exposures that mimic the production and photochemical oxidation of atmospheric pollutants resulting from the combustion of coal or wood from a stove. The combustion products are introduced into the Teflon bag under atmospheric conditions. Photochemical oxidation of this mixture is accomplished by exposure to tropospheric sun-like radiation from an array of ultraviolet and black lamps. The aerosol in the Teflon reaction bag is then transferred into the exposure room to maintain a constant, lower exposure level. Continuous and semicontinuous monitoring of the gas and particulate matter (PM) pollution in the exposure room and the reaction bag is accomplished using a suite of instruments. This suite of instruments allows for the measurement of the concentrations of total and nonvolatile PM, nitric oxide, nitrogen dioxide, carbon monoxide, carbon dioxide, and ozone. The concentration of the particles was monitored by an R&P tapered element oscillating microbalance monitor. The chemical composition of the PM and its morphological characterization is accomplished by collecting samples in filter packs and conducting ion chromatography, elemental X-ray fluorescence, and scanning electron microscopy analyses. The concentration and composition of emissions from combustion of wood and coal is described. The results of this study suggest that although the bulk compositions of particulate emissions from the combustion of coal or wood in a stove have many similarities, the wood smoke aerosol is photochemically reactive, whereas the coal smoke aerosol is not.     

Removal of cationic dyes from aqueous solutions using microspherical particles of fly ash

Batch sorption experiments were carried out for the removal of cationic dyes (methylene blue and malachite green) from their aqueous solutions using sorbent made from fly ash-a waste material. Effects of various experimental parameters: initial dye concentration, contact time, pH, adsorbent dosage, solution temperature, surfactant addition and ionic strength on the fly ash sorption of dyes were evaluated. The isothermal data for sorption followed the Langmuir model. The maximum sorption capacity obtained for methylene blue and malachite green was 36.05 mg/g and 40.65 mg/g, respectively. Kinetic studies indicate that sorption on fly ash follows the pseudo-second order kinetics. Present research suggests that fly ash could be an appropriate adsorbent for the removal of basic dyes from aqueous solutions.     

Passive sampling of perfluorinated acids and sulfonates using polar organic chemical integrative samplers

The applicability of a polar organic chemical integrative sampler (POCIS) for detection and determination of perfluorinated acids and sulfonates in water was studied under field conditions. Standard POCIS configurations (i.e., pharmaceutical and pesticide) were deployed in effluent from a wastewater treatment plant for 1, 2, and 3 weeks. Ten of 15 target compounds were found in POCIS, five of which were quantified in wastewater. Pest-POCIS appeared more effective for the sampling, while Pharm-POCIS had a more rapid uptake kinetic, which leads to faster saturation or equilibrium. The results showed that the pesticide configuration is probably more suitable for the sampling of this class of compounds. Based on average concentration in water over the sampling period and amount of compound adsorbed in the POCIS, we calculated sampling rates for five studied compounds and obtained values of 0.034 to 0.222 L?day^?1.     

热解技术在有机固废能源化清洁利用方面的应用潜力分析

热解技术在有机固废能源化清洁利用方面具有巨大的应用潜力.通过对热解技术的工作原理、适用范围、工艺系统与设备等的阐述及其能量转化、产物分析,吸取国外成功经验,着重以污泥为例,论述了热解技术在有机固废处置及综合利用方面的优势,并建设性地提出了3种热解技术应用模式以及国产化应用热解技术的发展规划思路.     

Mathematical description, optimization and prediction of synergistic interaction of fluoride and xylitol

The potential ability of various physical or chemical agents to enhance their effect when they are applied simultaneously with each other is well-known. The purpose of this study was to adjust a simple mathematical model to describe, optimize and predict a synergistic interaction between fluoride and xylitol on acid production by mutans streptococci. The model suggests that the synergism is caused by the additional effective damage arising from an interaction of sublesions induced by each agent. These sublesions are considered to be ineffective when each agent is used individually. The predictions of the model were verified by comparison with experimental data published by other researchers. It was shown that the model describes the experimental data, predicts the greatest value of the synergistic effect and the condition under which it can be achieved. The synergistic effect appeared to decline with any deviation from the optimal value of the ratio of effective damages produced by each agent alone.     

Serum concentrations of indicator PCB congeners in the Czech adult population

In 2006, levels of seven indicator polychlorinated biphenyl congeners (PCB28, 52, 101, 118, 138, 153, and 180) in blood serum of 202 blood donors residing for more than 2 years in five urban areas included in the Czech Human Biomonitoring project were measured by GC/MS/MS method. PCB congeners 138, 153 and 180 accounted for about 97% of the sum of the indicator congeners analyzed. Overall, the median and 95th percentile of the most abundant congener PCB 153 were 438 ng/g lipid and 1079 ng/g lipid, respectively. The highest median levels were found in Uherské Hradiste (669 ng/g lipid) and Ostrava (672 ng/g lipid in males compared to 341 ng/g lipid in females). Serum PCB concentrations were significantly associated with age, gender, place of residence and smoking habit, but not with body mass index and education. The results suggest the importance of PCB body burden in the Czech general population and the existence of hot spots.     

Composition and secondary formation of fine particulate matter in the Salt Lake Valley: Winter 2009

Under the National Ambient Air Quality Standards (NAAQS), put in place as a result of the Clean Air Amendments of 1990, three regions in the state of Utah are in violation of the NAAQS for PM₁₀ and PM_2.5 (Salt Lake County, Ogden City, and Utah County). These regions are susceptible to strong inversions that can persist for days to weeks. This meteorology, coupled with the metropolitan nature of these regions, contributes to its violation of the NAAQS for PM during the winter. During January–February 2009, 1-hr averaged concentrations of PM_10-2.5, PM_2.5, NO_x, NO₂, NO, O₃, CO, and NH₃ were measured. Particulate-phase nitrate, nitrite, and sulfate and gas-phase HONO, HNO₃, and SO₂ were also measured on a 1-hr average basis. The results indicate that ammonium nitrate averages 40% of the total PM_2.5 mass in the absence of inversions and up to 69% during strong inversions. Also, the formation of ammonium nitrate is nitric acid limited. Overall, the lower boundary layer in the Salt Lake Valley appears to be oxidant and volatile organic carbon (VOC) limited with respect to ozone formation. The most effective way to reduce ammonium nitrate secondary particle formation during the inversions period is to reduce NO_x emissions. However, a decrease in NO_x will increase ozone concentrations. A better definition of the complete ozone isopleths would better inform this decision.

Implications: Monitoring of air pollution constituents in Salt Lake City, UT, during periods in which PM_2.5 concentrations exceeded the NAAQS, reveals that secondary aerosol formation for this region is NO_x limited. Therefore, NO_x emissions should be targeted in order to reduce secondary particle formation and PM_2.5. Data also indicate that the highest concentrations of sulfur dioxide are associated with winds from the north-northwest, the location of several small refineries.     

The consequences of (not) seeing eye-to-eye about the past: The role of supervisor–team fit in past temporal focus for supervisors' leadership behavior

This study seeks to advance our understanding of the leadership consequences that may ensue when supervisors and their teams have similar versus differing orientations toward the past. Integrating a leader–team fit perspective with functional leadership theory, we cast incongruence between supervisor and team past temporal focus as a key antecedent of supervisors' active (i.e., task-oriented and relationship-oriented) and passive (i.e., laissez-faire) leadership behaviors toward the team. We tested our hypotheses in a team-level study that included a field sample of 84 supervisors and their teams using polynomial regression and response surface analyses. Results illustrated that supervisors demonstrated more task-oriented and relationship-oriented leadership when supervisors' and their team's past temporal focus were incongruent rather than aligned. Furthermore, in situations of supervisor–team congruence, supervisors engaged in less task-oriented and relationship-oriented leadership and more laissez-faire leadership with higher (rather than lower) levels of supervisor and team past temporal focus. In sum, these findings support a complex (mis)fit model such that supervisors' attention to the past may hinder their productive leadership behaviors in some team contexts but not in others. Hence, this research advances a novel, multiple-stakeholder perspective on the role of both supervisors' and their team's past temporal focus for important leadership behaviors.     

Modeling a Carbon Capture,Transport, and Storage Infrastructure for Europe

In this paper, we develop a model to analyze the economics of carbon capture, transport, and storage (CCTS) in the wake of expected rising CO₂ prices. We present a scalable mixed integer, multiperiod, welfare-optimizing network model for Europe, called CCTS-Mod. The model incorporates endogenous decisions on carbon capture, pipeline and storage investments, as well as capture, flow and injection quantities based on given costs, CO₂ prices, storage capacities, and point source emissions. Given full information about future costs of CCTS-technology, and CO₂ prices, the model determines a cost minimizing strategy on whether to purchase CO₂ certificates, or to abate the CO₂ through investments into a CCTS-chain on a site by site basis. We apply the model to analyze different scenarios for the deployment of CCTS in Europe, e.g., under high and low CO₂ prices, respectively. We find that beyond CO₂ prices of €50 per t, CCTS can contribute to the decarbonization of Europe’s industry sectors, as long as one assumes sufficient storage capacities (onshore and/or offshore). We find that CCTS is only viable for the power sector if the CO₂ certificate price exceeds €75 per t.