Low-reactive circulating fluidized bed combustion (CFBC) fly ashes as source material for geopolymer synthesis

In this contribution, low-reactive circulating fluidized bed combustion (CFBC) fly ashes (CFAs) have firstly been utilized as a source material for geopolymer synthesis. An alkali fusion process was employed to promote the dissolution of Si and Al species from the CFAs, and thus to enhance the reactivity of the ashes. A high-reactive metakaolin (MK) was also used to consume the excess alkali needed for the fusion. Reactivities of the CFAs and MK were examined by a series of dissolution tests in sodium hydroxide solutions. Geopolymer samples were prepared by alkali activation of the source materials using a sodium silicate solution as the activator. The synthesized products were characterized by mechanical testing, scanning electron microscopy (SEM), X-ray diffractography (XRD), as well as Fourier transform infrared spectroscopy (FTIR). The results of this study indicate that, via enhancing the reactivity by alkali fusion and balancing the Na/Al ratio by additional aluminosilicate source, low-reactive CFAs could also be recycled as an alternative source material for geopolymer production.     

大型中心传动浓缩（刮泥）机的应用与发展

阐述了大型中心传动浓缩机与周边传动浓缩机的结构特点及国内外的应用现状，分析了周边传动浓缩机存在的结构性缺陷，介绍了中心传动浓缩机的分类、技术特点以及其在国内的推广应用前景。     

Elevated atmospheric deposition and dynamics of mercury in a remote upland forest of southwestern China

Mt. Gongga area in southwest China was impacted by Hg emissions from industrial activities and coal combustion, and annual means of atmospheric TGM and PHg concentrations at a regional background station were 3.98 ng m⁻³ and 30.7 pg m⁻³, respectively. This work presents a mass balance study of Hg in an upland forest in this area. Atmospheric deposition was highly elevated in the study area, with the annual mean THg deposition flux of 92.5 μg m⁻² yr⁻¹. Total deposition was dominated by dry deposition (71.8%), and wet deposition accounted for the remaining 28.2%. Forest was a large pool of atmospheric Hg, and nearly 76% of the atmospheric input was stored in forest soil. Volatilization and stream outflow were identified as the two major pathways for THg losses from the forest, which yielded mean output fluxes of 14.0 and 8.6 μg m⁻² yr⁻¹, respectively.     

室内空气中的气态多环芳烃的被动采样监测

利用自制被动采样装置,在2011年秋冬季对南京市部分地区室内空气中5种气态多环芳烃(PAHs)(萘、苊烯、苊、芴、菲)进行了为期100d的连续采样检测,被动采样器的采样速率为0.012m3/d,5种PAHs的回收率在63%～105%之间,方法检出限在1.1～2.4ng范围内。结果表明,南京市5处不同室内环境空气中萘的浓度最高,占总量的90%以上。室内环境空气中5种PAHs的总浓度为230～1564ng/m3。住宅内人体对5种PAHs的暴露速率为479～560ng/h。     

Effects of pH and ionic strength on sulfamethoxazole and ciprofloxacin transport in saturated porous media

Many antibiotics regarded as emerging contaminants have been frequently detected in soils and groundwater; however, their transport behaviors in soils remain largely unknown. This study examined the transport of two antibiotics, sulfamethoxazole (SMZ) and ciprofloxacin (CIP), in saturated porous media. Laboratory columns packed with quartz sand was used to test the effects of solution pH and ionic strength (IS) on their retention and transport. The results showed that these two antibiotics behaved differently in the saturated sand columns. In general, SMZ manifested a much higher mobility than CIP for all experimental conditions tested. Almost all SMZ transported through the columns within one pore volume in deionized water (i.e., pH=5.6, IS=0), but no CIP was detected in the effluents under the same condition after extended column flushing. Perturbations in solution pH (5.6 and 9.5) and IS (0 and 0.1M) showed no effect on SMZ transport in the saturated columns. When pH increased to 9.5, however, ~93% of CIP was eluted from the sand columns. Increase of IS from 0 to 0.1M also slightly changed the distribution of adsorbed CIP within the sand column at pH 5.6, but still no CIP was detected in the effluents. A mathematical model based on advection-dispersion equation coupled with equilibrium and kinetic reactions successfully simulated the transport of the antibiotics in water-saturated porous media with R(2)=0.99.     

中国省际碳排放极化格局研究

温室气体减排是减缓气候变化的重要途径.由于资源、劳动力、资本和技术等要素的差异,我国社会经济发展不平衡,碳减排的潜力也各不同.文章在计算中国雀际碳排放的基础上,运用基尼系数和空间自相关的方法,刻画了1990年到2007年中国省际碳排放时空分布格局和聚集程度,有利于设立合理的长期减排目标和战略,实现碳排放空间的公平分配,促进区域协调发展.研究表明,碳总量和碳强度都呈现正的空间自相关性,在局部空间上出现了高值的聚集现象.碳强度的极化现象比碳总量更加严重.文章最后根据区域经济发展,资源禀赋,碳排放聚集等,因地制宜地提出了碳排放区划方案.区划结果显示出资源丰裕程度与碳强度的关系,有利于实施差异化的减排战略,实现经济发展与碳排放脱钩.     

西安市灞河流域水环境现状分析及治理对策

基于大量的技术资料和监测数据,对西安市灞河流域的水环境进行了全面系统的分析,指出了面临的问题及其成因.在此基础上提出了灞河流域水环境治理的新思路、新方法,为流域的综合治理工作提供借鉴.     

广西喀斯特干旱农业区干旱遥感监测模型研究

广西中部喀斯特平原区是广西重要的粮食生产基地,但旱灾已成为该地区经济发展的障碍.利用EOS/MODIS数据,采用植被状态指数(IVC)和温度条件指数(ITC),构建了干旱指数ID的遥感监测模型, 统计分析了ID与农业受旱率的相关系数,从而确定了模型中各参数的权重系数.将该模型应用于2005年秋旱监测,经与旱情实况及前人研究成果进行对比分析,验证了干旱指数ID的有效性.通过对ID随ITC和IVC变化的敏感性评价,结果表明,ITC和IVC都能反映旱情变化,但ITC反映旱情的敏感性高于IVC,以ITC和IVC为因子构建的干旱遥感监测模型适用于广西中部喀斯特干旱农业区的旱情遥感监测.     

家具企业安全管理调查研究——运用行为抽样法调查分析不安全行为

为降低家具企业事故的发生概率,通过对家具企业机加工车间工人的不安全行为的观察,依据其主要表现,将工人的不安全行为分为静态和动态两类;运用行为抽样法对生产现场工人的不安全行为情况进行的抽查,并对其不安全行为进行现状评价;通过分析不安全行为发生的原因,提出相应的改进措施。     

微波-过氧乙酸联合作用处理剩余污泥的研究

采用微波-过氧乙酸(PAA)联合作用处理剩余污泥,考察了微波辐照时间、微波功率、PAA投加量对剩余污泥分解效果的影响.同时以单独微波作用为对比,考察了微波-PAA联合作用下剩余污泥性质的变化.结果表明,当微波功率为600 W,PAA投加量为0.24 g/g(以干质量SS计)时,微波辐照60 s后剩余污泥分解率可达35%...