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51.
Gerecke AC Schärer M Singer HP Müller SR Schwarzenbach RP Sägesser M Ochsenbein U Popow G 《Chemosphere》2002,48(3):307-315
Concentrations of pesticides in Swiss rivers and lakes frequently exceed the Swiss quality goal of 0.1 microg/l for surface waters. In this study, concentrations of various pesticides (e.g., atrazine, diuron, mecoprop) were continuously measured in the effluents of waste water treatment plants and in two rivers during a period of four months. These measurements revealed that in the catchment of Lake Greifensee, farmers who did not perfectly comply with 'good agricultural practice' caused at least 14% of the measured agricultural herbicide load into surface waters. Pesticides, used for additional purposes in urban areas (i.e. protection of materials, conservation, etc.), entered surface waters up to 75% through waste water treatment plants. 相似文献
52.
53.
Brent W. Hall Carl Singer Wojciech Jozewicz Charles B. Sedman Michael A. Maxwell 《Journal of the Air & Waste Management Association (1995)》2013,63(1):103-110
The following report discusses current bench- and pilot-plant advances in preparation of ADVAnced siliCATE (ADVACATE) calcium silicate sorbents for flue gas desulfurization. It also discusses current bench- and pilot-plant advances in sorbent preparation. Fly ash was ground in a laboratory scale grinder prior to slurring in order to decrease the slurring time needed for the sorbent to be reactive with SO2. Reactivity of ADVACATE sorbents with SO2 in the bench-scale reactor correlated with their surface area. ADVACATE sorbents produced with ground fly ash were evaluated in the 50 cfm (85 m3/h) pilot plant providing 2 s duct residence time. ADVACATE sorbent was produced by slurrying ground fly ash (median particle size of 4.3 µm) with Ca(OH)2 at the weight ratio of 3:1 at 90°C (194°F) for 3hto yield solids with 30 weight percent of initial free moisture. When this sorbent was injected into the duct with 1500 ppm SO2 and at 11°C (20°F) approach to saturation, the measured SO2 removal was approximately 60percent at a Ca/S stoichiometric ratio of 2. Previously, when ADVACATE sorbent was produced at 90°C (194°F) and at the same fly-ash-to-Ca(OH)2 weight ratio using unground fly ash, removal under the same conditions in the duct was approximately 50 percent following 12 h slurring. The report presents the results of pilot-scale recycle tests at the recycle ratio of 2. Finally, the report discusses future U.S. Environmental Protection Agency plans for commercialization of ADVACATE. 相似文献
54.
Irving A. Singer John A. Frizzola Maynard E. Smith 《Journal of the Air & Waste Management Association (1995)》2013,63(11):455-458
The rise of a hot cloud resulting from combustion of a solid propellant rocket fuel at ground level has been determined from lapse-time movies and visual aircraft observations. The field tests were conducted near the 420 foot meteorological tower under various atmospheric conditions. A method of predicting the maximum thermal rise of a cloud, based on source and meteorological parameters, is described. Comparisons with other theoretical formulations are presented. 相似文献
55.
Heinz Singer 《Environmental pollution (Barking, Essex : 1987)》2010,158(10):3054-3064
This study focused on the input of hydrophilic biocides into the aquatic environment and on the efficiency of their removal in conventional wastewater treatment by a mass flux analysis. A fully automated method consisting of on-line solid phase extraction coupled to LC-ESI-MS/MS was developed and validated for the simultaneous trace determination of different biocidal compounds (1,2-benzisothiazoline-3-one (BIT), 3-Iodo-2-propynylbutyl-carbamate (IPBC), irgarol 1051 and 2-N-octyl-4-isothiazolinone (octhilinone, OIT), carbendazim, diazinon, diuron, isoproturon, mecoprop, terbutryn and terbutylazine) and pharmaceuticals (diclofenac and sulfamethoxazole) in wastewater and surface water. In the tertiary effluent, the highest average concentrations were determined for mecoprop (1010 ng/L) which was at comparable levels as the pharmaceuticals diclofenac (690 ng/L) and sulfamethoxazole (140 ng/L) but 1-2 orders of magnitude higher than the other biocidal compounds. Average eliminations for all compounds were usually below 50%. During rain events, increased residual amounts of biocidal contaminants are discharged to receiving surface waters. 相似文献
56.
A tiered procedure for assessing the formation of biotransformation products of pharmaceuticals and biocides during activated sludge treatment 总被引:1,自引:0,他引:1
Kern S Baumgartner R Helbling DE Hollender J Singer H Loos MJ Schwarzenbach RP Fenner K 《Journal of environmental monitoring : JEM》2010,12(11):2100-2111
Upon partial degradation of polar organic micropollutants during activated sludge treatment, transformation products (TPs) may be formed that enter the aquatic environment in the treated effluent. However, TPs are rarely considered in prospective environmental risk assessments of wastewater-relevant compound classes such as pharmaceuticals and biocides. Here, we suggest and evaluate a tiered procedure, which includes a fast initial screening step based on high resolution tandem mass spectrometry (HR-MS/MS) and a subsequent confirmatory quantitative analysis, that should facilitate consideration of TPs formed during activated sludge treatment in the exposure assessment of micropollutants. At the first tier, potential biotransformation product structures of seven pharmaceuticals (atenolol, bezafibrate, ketoprofen, metoprolol, ranitidine, valsartan, and venlafaxine) and one biocide (carbendazim) were assembled using computer-based biotransformation pathway prediction and known human metabolites. These target structures were screened for in sludge-seeded batch reactors using HR-MS/MS. The 12 TPs found to form in the batch experiments were then searched for in the effluents of two full-scale, municipal wastewater treatment plants (WWTPs) to confirm the environmental representativeness of this first tier. At the second tier, experiments with the same sludge-seeded batch reactors were carried out to acquire kinetic data for major TPs that were then used as input parameters into a cascaded steady-state completely-stirred tank reactor (CSTR) model for predicting TP effluent concentrations. Predicted effluent concentrations of four parent compounds and their three major TPs were corroborated by comparison to 3-day average influent and secondary effluent mass flows from one municipal WWTP. CSTR model-predicted secondary effluent mass flows agreed within a factor of two with measured mass flows and confidence intervals of predicted and measured mass flows overlapped in all cases. The observed agreement suggests that the combination of batch-determined transformation kinetics with a simple WWTP model may be suitable for estimating aquatic exposure to TPs formed during activated sludge treatment. Overall, we recommend the tiered procedure as a realistic and cost-effective approach to include consideration of TPs of wastewater-relevant compounds into exposure assessment in the context of prospective chemical risk assessment. 相似文献
57.
Redox reactions in the Fe-As-O2 system 总被引:1,自引:0,他引:1
We have examined two redox reactions involving arsenic and iron at near-neutral pH: the reduction of As(V) by Fe(II) under anoxic conditions, and the co-oxidation of As(III) during Fe(II) oxygenation. We also considered the impact of goethite, pH buffers, and radical scavengers on these reactions. In a series of anoxic experiments, Fe(II) was found to reduce As(V) in the presence of goethite, but not in homogeneous solution. The reaction rate increased with increasing pH and Fe(II) concentration, but in all cases was relatively slow. In aerobic experiments, the kinetics of Fe(II) oxygenation at neutral pH, and the corresponding oxidation of As(III) were found to depend heavily on pH buffer type and concentration. The classic formulation of Fe(II) oxidation by oxygen, involving four single-electron transfers, was reviewed and found to be inadequate for explaining observed oxidation of Fe(II) and As(III). Widely cited rate constants for Fe(II) oxygenation originate from experiments conducted in carbonate buffer, and do not match observations made in phosphate, MES, or HEPES systems. In phosphate buffer, Fe(II) oxidation is rapid and dependent on phosphate concentration. In MES and HEPES buffers, Fe(II) oxidation is much slower due to the lack of labile ferrous iron species. Oxygenation of Fe(II) appears to proceed through different mechanisms in phosphate and MES or HEPES systems. In both cases, reactive intermediary species are produced which can oxidize As(III). These oxidants are not the hydroxyl radical, but may be Fe(IV) species. 相似文献
58.
Gregor Kalinkat Juliano S. Cabral William Darwall G. Francesco Ficetola Judith L. Fisher Darren P. Giling Marie‐Pierre Gosselin Hans‐Peter Grossart Sonja C. Jähnig Jonathan M. Jeschke Klaus Knopf Stefano Larsen Gabriela Onandia Marlene Pätzig Wolf‐Christian Saul Gabriel Singer Erik Sperfeld Ivan Jarić 《Conservation biology》2017,31(2):481-485
59.
Downs PW Singer MS Orr BK Diggory ZE Church TC Stella JC 《Environmental management》2011,48(4):847-864
The goal of restoring ecological integrity in rivers is frequently accompanied by an assumption that a comparative reference
reach can be identified to represent minimally impaired conditions. However, in many regulated rivers, no credible historical,
morphological or process-based reference reach exists. Resilient restoration designs should instead be framed around naturalization,
using multiple analytical references derived from empirically-calibrated field- and model-based techniques to develop an integrated
ecological reference condition. This requires baseline data which are rarely collected despite increasing evidence for systematic
deficiencies in restoration practice. We illustrate the utility of baseline data collection in restoration planning for the
highly fragmented and regulated lower Merced River, California, USA. The restoration design was developed using various baseline
data surveys, monitoring, and modeling within an adaptive management framework. Baseline data assisted in transforming conceptual
models of ecosystem function into specific restoration challenges, defining analytical references of the expected relationships
among ecological parameters required for restoration, and specifying performance criteria for post-project monitoring and
evaluation. In this way the study is an example of process-based morphological restoration designed to prompt recovery of
ecosystem processes and resilience. For the Merced River, we illustrate that project-specific baseline data collection is
a necessary precursor in developing performance-based restoration designs and addressing scale-related uncertainties, such
as whether periodic gravel augmentation will sustain bed recovery and whether piecemeal efforts will improve ecological integrity.
Given the numerous impediments to full, historical, restoration in many river systems, it seems apparent that projects of
naturalization are a critical step in reducing the deleterious impacts of fragmented rivers worldwide. 相似文献
60.