金属铁离子对农田土壤氮转化影响分析

以长春伊通河河谷阶地上部的农田土为研究对象,选用铁离子作为氮转化的一种影响因素,定性研究了不同浓度的铁离子对硝态氮、亚硝态氮、铵态氮三氮的变化影响。并且在建立方程组之后计算平衡常数,证明了铁的氧化作用,与实验所得相符合：铁促进铵态氮的吸附、促进硝化反应的进行。从实验和理论的角度说明了铁在三氮转化中起的作用,为进一步研究锰铁离子对氮转化的定量影响和氮素污染地下水的预测和定量评价提供科学依据。     

噻唑类缓蚀剂QADT的合成及缓蚀性能研究＊

以正丙醇、氯气和硫脲合成了2-氨基-5-甲基噻唑,将上述产物作为碱组分,与苯甲醛和苯乙酮反应得到曼尼希碱,最后采用溴代十二烷作为季铵化试剂,制得目标产物溴代2-氨基(1,4-二苯基-3-氧代丁基)-5-甲基噻唑铵(QADT)。静态失重法表明,QADT缓蚀效果显著。当温度为50℃,QADT的用量在200 mg/L时,缓蚀率达到95%以上。     

Effects of chemical modification on physicochemical properties and adsorption behavior of sludge-based activated carbon

This study aimed to explore the adsorption performance of sludge-based activated carbon (SBC) towards dissolved organic matters (DOMs) removal from sewage, and investigated the modification effect of different types of chemicals on the structure of synthesized SBC. Waste activated sludge (WAS) was used as a carbon source, and HCl, HNO₃, and NaOH were used as different types of chemicals to modify the SBC. With the aid of chemical activation, the modified SBC showed higher adsorption performances on DOMs removal with maximum adsorption of 29.05 mg/g and second-order constant (k) of 0.1367 (L/mol/sec) due to the surface elution of ash and minerals by chemicals. The surface elemental composition of MSBC suggested that the content of C-C and C-O functional groups on the surface of modified sludge-based activated carbon (MSBC) played an important role on the adsorption capacities of MSBC towards DOMs removal in sewage. Additionally, the residual molecular weight of DOMs in sewage was investigated using a 3-dimension fluorescence excitation-emission matrix (3D-EEM) and high-performance size exclusion chromatography (HP-SEC). Results showed that the chemical modification significantly improved the adsorption capacity of MSBC on humic acids (HA) and aromatic proteins (APN), and both of NaOH-MSBC and HCl-MSBC were effective for a wide range of different AMW DOMs removal from sewage, while the HNO₃-MSBC exhibited poorly on AMW organics of 2,617 Da and 409 Da due to the reducing content of macropore. In brief, this study provides reference values for the impact of the chemicals of the activation stage before the SBCs application.     

Effect of indole-3-acetic acid supplementation on the physiology of Lolium perenne L. and microbial activity in cadmium-contaminated soil

Environmental Science and Pollution Research - Cadmium (Cd) pollution has led to a serious deterioration in soil quality, plant growth, and human health. Therefore, restoration of soil quality is...     

What are the disease burden and its sensitivity analysis of workers exposing to Staphylococcus aureus bioaerosol during warm and cold periods in a wastewater treatment plant?

Environmental Science and Pollution Research - Biological treatment in wastewater treatment plants releases high amounts of pathogenic bioaerosols. Quantitative microbial risk assessment is a...     

废铜催化剂的综合利用

研究了以湿法回收利用废铜催化剂中的铜、锌制取氧化亚铜和氧化锌的原理以及最佳工艺条件。该工艺可同槽进行浸取、蒸氨、还原、中和水解等操作,生产成本低,产品质量好,工艺过程中无三废排放,具有很好的综合效益。     

SPECTRAL ANALYSIS OF TIDAL FLUCTUATIONS IN GROUND WATER LEVEL1

ABSTRACT: Water level data at 16 ground water wells and two sea water gauging stations, coupled with barometric measurements in an alluvial plain in the central‐west region of Taiwan, are analyzed using spectral analysis in the time and frequency domains. The semi‐diurnal component from water level station is observed to be the most noticeable signal while the diurnal component is the less distinct signal recorded at the water level stations. Both semidiurnal and diurnal components are coupled with atmospheric pressure measurements. From the atmospheric pressure data, spectral analysis indicates that both the raw and the pressure adjusted water levels are almost in phase and retain the same amplitude in this area. It implies that the effect of pressure variations is not significant for the sea water and ground water level nearby; the astronomical tidal components, as expected, are the main factor causing fluctuation of ocean water and ground water levels in the Choshuihsi alluvial plain.     

Transboundary hazardous waste management. Part I: Waste management policy of importing countries.

Mixed metal-containing waste, polychlorinated biphenyls (PCB) containing capacitors, printed circuit boards, steel mill dust and metal sludge were among the most common wastes exported from Taiwan. Before the implementation of the self-monitoring model programme of the Basel Convention (secretariat of the Basel Convention 2001) in the Asia region, Taiwan conducted a comprehensive 4-year follow-up project involving government authorities and the waste disposal facilities of the importing countries. A total of five countries and nine plants were visited in 2001-2002. The following outcomes can be drawn from these investigations. The Chinese government adopts the strategies of 'on-site processing' and 'relative centralization' on the waste management by tightening permitting and increasing site inspection. A three-level reviewing system is adopted for the import application. The United States have not signed the Basel Convention yet; the procedures of hazardous waste import rely on bilateral agreements. Importers are not required to provide official notification from the waste exporting countries. The operation, administration, monitoring and licensing of waste treatment plants are governed by the state environmental bureau. Finland, France and Belgium are members of the European Union. The procedures and policies of waste import are similar. All of the documents associated with transboundary movement require the approval of each government involved. Practically, the notification forms and tracking forms effectively manage the waste movement.     

Fetus in fetu—from prenatal ultrasound and MRI diagnosis to postnatal confirmation

We report a case of fetus in fetu presented as a complex intra-abdominal heterogeneous cystic lesion during ultrasound examination of the fetus at 25 weeks of gestation. Progressive growth of this mass was noted in the prenatal period. Fetal magnetic resonance imaging provided additional information to aid in the prenatal diagnosis. This allows proper counselling for the parents and helps to plan the postnatal management. Surgical excision was carried out in the early neonatal period and the diagnosis of fetus in fetu was confirmed. Copyright © 2007 John Wiley & Sons, Ltd.     

废水中磷的监测和处理

本文介绍了钼锑抗光度法测定污水中总磷在实际应用中应该注意的问题，并介绍了不同类型污水处理设施的除磷效率。则结果证明，常规二级污水处理工艺对总磷的去除率只能达到４０－５０％左右，迄今，化学混凝与生物过程一体化的处理系统可能是除灰最经济有效的办法。