Electrokinetic extraction of lead from kaolinites: I. Numerical modeling

Experimental results obtained to date indicate electrokinetic extraction is viable in removing organic and inorganic contaminants from fine-grained soils. However, electrochemical reactions and soil-contaminant interactions that occur simultaneously may enhance or reduce the removal efficiency of the hazardous waste site remediation process. Many sites worldwide are contaminated by lead and its compounds, resulting in lead poisoning. It is difficult to remove lead from fine-grained soil because of the existence of a great variety of lead complexes and their pH-dependent and reversible physicochemical properties. The feasibility of electrokinetic extraction of lead from kaolinites is investigated theoretically, numerically, and experimentally in this study. This is the first paper of two companion papers presenting the theoretical and numerical modeling of the transport of lead species, and electrochemical reactions and soil-contaminant interactions occurring during the electrokinetic extraction process. The comparison between simulation results and experimental results is presented in the second paper.     

Laboratory experiments on waveform inversion of an internal solitary wave over a slope-shelf

Internal solitary waves (ISWs) have been detected in many parts of the world oceans, particularly over slope-shelf topography, on which signature of waveform inversion has been identified. The effects of these waves on engineering operations and ecological process have also been reported in the literature. This article reports the results of a series of numerical modeling and laboratory experiments on waveform evolution of a depression ISW in a nearly stratified two-layer fluid system, in which specific water depth ratios above the horizontal plateau of the trapezoidal obstacle were arranged to facilitate the occurrence of waveform inversion. Classifications of waveform instability (no instability, shear instability and overturning with breaking) on the slope are confirmed in the present laboratory study. Numerical results for waveform variation are also found in fair agreement with the laboratory measurements for cases without waveform inversion and minor internal breaking. Moreover, laboratory results revealed that the depth ratio of the stratified two-layer fluid above the plateau and the magnitude of the incident ISW were the two most important factors for promoting waveform inversion beyond a turning point, in addition to the requirement of a sufficient distance from the shoulder of the trapezoidal obstacle. These factors also influenced the outcome of the shoaling process, energy dissipation, internal wave breaking and turbulent mixing on the front slope, as well as the likelihood of waveform inversion on the horizontal plateau. Contrary to the common perception, it was also observed, at least from the results of the present laboratory experiments, that not all the incident ISWs of depression would produce waveform inversion on the plateau, where the upper layer was physical greater than the bottom layer, unless moderate incident wave was provided. The outcome might also be attributed to the limited distance from the shoulder onto the plateau in the present laboratory setup. However, once waveform inversion occurred on the plateau, it was found, among others, that: (1) the amplitude of the transmitted leading crest and trough might be as low as 30 and 20%, respectively, to the amplitude of the incident wave in depression; (2) the characteristic wavelength of the transmitted leading trough doubled while that of the crest was asymptotically one-half of the incident wavelength, despite the wide range variation in the depth ratios above the plateau; and (3) the transmitted potential wave energy of the leading crest contained 30% of the incident energy. Based on the results of present laboratory experiments, the range for the non-dimensional parameter α, which indicates the effect of nonlinearity and the promotion of waveform inversion on horizontal plateau, will be proposed.     

Does environmental engineering help rural industry development? Discussion on the impact of Taiwan’s “special act for forward-looking infrastructure” on rural industry development

Environmental Science and Pollution Research - This study investigated the impact of environmental engineering on existing venues, venues and operations management. First, the literature analysis...     

A comparison of PCDD/PCDFs exposure in infants via formula milk or breast milk feeding

Food is the major source for polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) accumulation in human body. In infant period, breast milk and formula milk are the major food sources. Congener-specific analyses of 17 PCDD/PCDFs were performed on 10 brands of formula milk samples which were milk-based and 37 breast milk samples collected from women living in southern Taiwan. The levels of 17 PCDD/PCDFs in 10 formula milk samples ranged from 0.468 to 0.962 pg WHO-TEQ/g lipid, with a mean value of 0.713+/-0.163 pg WHO-TEQ/g lipid. For the 37 breast milk samples, their PCDD/PCDF levels were 14.7+/-9.36 pg WHO-TEQ/g lipid, with a range between 4.21 and 52.8 pg WHO-TEQ/g lipid. At 12th month of age for infants, average daily intakes (ADI) of PCDD/PCDFs were 2.1 pg WHO-TEQ/kg/day for the formula-feeding infants, and 13 pg WHO-TEQ/kg/day for the breast-feeding infants. The present data may provide useful information for risk-benefit evaluation of formula- and breast-feeding.     

Lack of mtDNA and morphological differentiation between two acorn barnacles <Emphasis Type="Italic">Tetraclita japonica</Emphasis> and <Emphasis Type="Italic">T. formosana</Emphasis> differing in parietes colours and geographical distribution

Tetraclita japonica and T. formosana are common intertidal barnacles with similar morphology, which leads to uncertainty in their species status. In the present study, we try to elucidate the taxonomic status of the two taxa using morphology and mitochondrial control region and cytochrome c oxidase subunit I (COI) sequences of the barnacles in their distribution range. The two taxa were found to be morphologically similar; a diagnostic difference between them was only observed in the colour of the parietes and opercular plates. Little genetic differentiation was detected in the control region and COI (Φ_CT < 0.025 for both markers) between two taxa, but differentiation was found between the southern (Taiwan and Hong Kong) and northern (Japan) populations of T. japonica/T. formosana, which might be the result of isolation by distance and upwelling in summer. Our data suggest that the two presently recognized species probably represent two colour morphotypes of the same species exhibiting different geographical distribution. T. japonica is abundant in Japan and southeast coast of China, whereas T. formosana is only abundant in Taiwan. The heterogeneous environment might exert a divergent selection pressure leading to asymmetric distribution of the two colour morphotypes. The different colours might be a result of either phenotypic plasticity adaptive to environmental variables or genetic hitchhiking of local adaptive genotypes. Electronic supplementary material Supplementary material is available in the online version of this article at and is accessible for authorized users.     

A high loading overland flow system: Impacts on soil characteristics, grass constituents, yields and nutrient removal

The objectives of this paper are to determine effects of different grass species and their harvests on pollutant removal, elucidate impacts on soil characteristics and grass constituents, observe grass yield and quantify nutrient uptake by vegetation in an overland flow system (OLFS). Polluted creek water was applied to eight channels in the OLFS, which were planted with Paragrass, Nilegrass, Cattail, and Vetiver, with each two channels being randomly planted with a given grass species. The grass in one channel was harvested while that in the other channel was not. At a high rate of 27.8 m d(-1) hydraulic loading, the removal efficiencies of conventional pollutants such as BOD, COD, suspended solids (SS), and total coliforms in wastewater are not affected by the type of the grasses species, but those of nitrogen and phosphorus are affected by different species. Overall average removal efficiencies of BOD, COD, SS, ammonia, total nitrogen, total phosphorus and total coliforms through the OLFS are 42%, 48%, 78%, 47%, 40%, 33% and 89%, respectively. The concentration of nitrate, however, increases due to nitrification. Soil characteristics in OLFS have been changed significantly; specific conductivity, organic matter, exchangeable magnesium, extractable copper and zinc in soils all increase with time while pHs decrease. During the winter season, there is a significant accumulation of nitrate in grass with the subsequent reduction during the active growing season (Spring). The contents of nitrate and phosphorus in grass tissue are higher than those of grass in general pastureland, probably due to nutrient luxury uptake by grass. The overall grass yield, growth rate and nutrient uptake are quantified and implication of such high rate OLFS discussed.     

A total diet study to estimate PCDD/Fs and dioxin-like PCBs intake from food in Taiwan

Concentrations of 17 dibenzo-p-dioxins/dibenzofurans (PCDD/Fs) and 12 dioxin-like polychlorinated biphenyls (dl-PCBs) were measured in total diet study samples of 14 food groups of animal origin from 11 locations in Taiwan, collected in 2003. Pork meat possessed the lowest background concentration level of 0.058 pg WHO-TEQ(PCDD/Fs+dl-PCBs)/g fresh weight. The dl-PCBs contribution were 31%, 59%, 36%, 46%, and 13% for meat and meat products, muscle meat of fish, milk and dairy products, fat and oil, and egg, respectively. The estimated monthly intake (EMI) was 44.7 and 39.5 pg WHO-TEQ(PCDD/Fs+dl-PCBs)/kg b.w./month for a male and female adult weighing 64.8 kg and 56.3 kg, respectively. Muscle meat of fish contributes 46% to the mean EMI. Factors affecting the EMI, in order of increasing importance are analytical method uncertainty, sample compositional difference, and food consumption data. In addition to the continuous efforts to identify and reduce the source of PCDD/Fs and dl-PCBs releases into the environment and the food-chain, the practice of a healthy dietary habit, i.e., eating foods of lower TEQ levels, was suggested to effectively reduce human exposure to PCDD/Fs and dl-PCBs.     

A mathematical model for predicting the flash point of binary solutions

A mathematical model which may be used for predicting the flash point of binary solutions has been proposed and subsequently verified by experimentally-derived data, such data pertaining to an almost-ideal solution as also to highly non-ideal solutions. The results reveal that the model is able to precisely predict the flash point over the entire composition range of binary solutions for both ideal solutions and non-ideal solutions by way of utilizing the flash point of the individual components. The highly non-ideal solution like octane+ethanol exhibits the minimum flash-point behavior, which leads to the minimum on the flash point vs composition curve.     

Work as good‐minded undertakings and effortless assignments: Chinese meaning of working for hospitality workers and its motivational implications

Meaning of working (MOW) or the understanding of the purpose of working is a cornerstone in organizational behavior. This study answers the call to explain the MOW in Eastern contexts characterized by interdependent identities. We collect our data from hospitality workers in Taiwan, where Chinese Confucian and Taoist cultural precepts are strong. Our findings reveal that our informants use 25 typical vocabularies of motive in establishing and maintaining five salient identities that gain significance through two Chinese work meanings (i.e., good‐minded undertakings and effortless assignments). These meanings demonstrate the theoretical contributions of our findings to the MOW literature. We also explore the interplay between our emic findings (grounded in Taoism and Confucianism Chinese cultures) with etic motivation theory to advance understanding of prevention and promotion foci.