基于测试数据的室内超宽带信道建模研究

基于室内超宽带信道测量研究建立了基于簇的时延抽头模型以及与距离和载频有关的新颖的路径损耗模型,建立了路径损耗同时与距离和频率的依赖关系.同时,研究发现视距和非视距接收信号幅度分别满足莱斯和瑞利分布.该模型对超宽带无线系统仿真和设计有重要的指导意义.     

Assessment of PAH pollution in the southern Baltic Sea through the analysis of sediment, mussels and fish bile

The concentrations of fifteen PAH compounds in samples of sediment and blue mussel tissue (Mytilus trossulus) were measured. In addition, the biliary polycyclic aromatic hydrocarbon metabolites present in flounder (Platichthys flesus) were analysed. Two methods were used in the analysis of PAH metabolites; high performance liquid chromatography (HPLC) and fixed wavelength fluorescence (FF). The major PAH metabolite which could be measured using the HPLC method was 1-OH pyrene. It was possible to detect 1-OH Phe and 3-OH B[a]P in 70 and 24 samples respectively, of the 87 samples analysed. However, the concentrations of 1-OH Phe and 3-OH B[a]P were below or near to the LOQ (0.002 μg ml(-1) bile). The bile of flounder samples from the Gulf of Gdańsk had 1-OH Pyr concentrations which ranged from 0.019 to 0.066 μg ml(-1) bile. The high linear correlation observed between the quantity of 1-OH pyrene determined by the HPLC-F method and the content of the sum of pyrene-type PAHs obtained by the FF method indicated the FF method of determination of pyrene-type PAH metabolites can be used as a screening method. The content of ∑(15)PAHs in sediments collected in the Gulf of Gdansk, in 2008, ranged from 29.3 to 103 μg kg(-1) dw. In mussel tissue ∑(15)PAHs concentrations were between 173.2 μg kg(-1) dw and 237.7 μg kg(-1) dw. All concentrations measured in the current study, in mussel tissue, were below the OSPAR toxicity threshold values.     

Determination of Kinetic Parameters for the Degradation of Chitosan/Silica Hybrid Nano Composites

The thermal degradation behavior of chitosan (CS) and chitosan–silica (CS–Si) nanocomposites were studied using a differential kinetic model. The influence of the heating rate in the non-isothermal degradation kinetics of CS and CS–Si nanocomposites are presented. Kinetic parameters, such as the activation energy (E) and pre-exponential factor (A), and thermodynamic parameters, such as the Gibbs free energy (ΔG), enthalpy (ΔH) and entropy (ΔS), were determined using the modified Arrhenius equation. It was shown that the rate constant for degradation (k), activation energy and pre-exponential factor depend on the heating rates. The order of reaction was found to be one. The isothermal stability of CS and CS–Si was determined from non-isothermal kinetics and was also found to be dependent on the heating rate. Thermogravimetric studies revealed that neat CS was less thermally stable than the CS–Si nanocomposites.     

Co-occurrence of three types of egg policing in the Norwegian wasp <Emphasis Type=Italic>Dolichovespula norwegica</Emphasis>

In insect societies, workers often try to challenge the reproductive monopoly of the queen by laying their own eggs. Successful worker reproduction, however, is frequently prevented by queen policing or worker policing, whereby either the mother queen or non-reproductive workers selectively kill worker-laid eggs. Recently, a third mechanism—“selfish” worker policing—has also been described in which the workers selectively police worker-laid eggs but also lay eggs themselves. Here, we present results from the monogynous wasp Dolichovespula norwegica, which show that all three kinds of policing—queen policing, worker policing and “selfish” worker policing—co-occur. The net effect of these three kinds of policing collectively favoured the queen’s reproduction, as within 1 day 44% of the worker-laid eggs versus only 8% of the queen-laid eggs were eaten. Of the worker-laid eggs that were killed by workers, approximately two thirds were eaten by the reproductive workers even though these made up only a small proportion, 8%, of the work force. This means that policing workers obtained both direct fitness benefits as well as indirect (inclusive) fitness. In addition, we show that worker policing was carried out by a limited, specialised set of workers that was estimated to constitute approximately one quarter of the whole colony and of which 66% were non-reproductive.     

New insight into defining the lakes of the southern Baltic coastal zone

There exist many classification systems of hydrographic entities such as lakes found along the coastlines of seas and oceans. Each system has its advantages and can be used with some success in the area of protection and management. This paper aims to evaluate whether the studied lakes are only coastal lakes or rather bodies of water of a completely different hydrological and hydrochemical nature. The attempt to create a new classification system of Polish coastal lakes is related to the incompleteness of lake information in existing classifications. Thus far, the most frequently used are classifications based solely on lake basin morphogenesis or hydrochemical properties. The classifications in this paper are based not only on the magnitude of lake water salinity or hydrochemical analysis but also on isolation from the Baltic Sea and other sources of water. The key element of the new classification system for coastal bodies of water is a departure from the existing system used to classify lakes in Poland and the introduction of ion-“tracking” methods designed to identify anion and cation distributions in each body of water of interest. As a result of the work, a new classification of lakes of the southern Baltic Sea coastal zone was created. Featured objects such as permanently brackish lakes, brackish lakes that may turn into freshwater lakes from time to time, freshwater lakes that may turn into brackish lakes from time to time, freshwater lakes that experience low levels of salinity due to specific incidents, and permanently freshwater lakes. The authors have adopted 200 mg Cl^? dm^?3 as a maximum value of lake water salinity. There are many conditions that determine the membership of a lake to a particular group, but the most important is the isolation lakes from the Baltic Sea. Changing a condition may change the classification of a lake.     

Evaluation of the impacts of mine drainage from a coal waste pile on the surrounding environment at Smolnica, southern Poland

Mine drainage impacts from a coal waste pile at Smolnica, Poland have been monitored. Groundwater in an unconfined aquifer downgradient from the pile has near-neutral pH, but high concentrations of sulfate (up to 3,827 mg/l), chloride (up to 903 mg/l), and sodium (up to 2,606 mg/l). Concentrations of iron and manganese are elevated only locally, and concentrations of other metals are low. The behavior of sulfate seems to be conservative in the downgradient aquifer, and gypsum may only be precipitating locally. Concentrations of iron and manganese seem to be controlled by the precipitation of ferric oxide and hydroxides and rhodochrosite, respectively. Complete neutralization of mine drainage by carbonates is consistent with high concentrations of calcium (up to 470 mg/l) and magnesium (up to 563 mg/l) and also with high strontium concentrations of up to 3.08 mg/l, observed in groundwater downgradient from the pile. Hydraulic head profiles at two sites within the river bottom sediments indicate upward flow toward the river with large local differences in groundwater recharge. Water chemistry profiles in the river bottom sediments and geochemical modeling suggest conservative behavior of Na, Cl, and SO₄ and precipitation of Fe and Mn at the groundwater/river water interface. Mine drainage enters the Bierawka River and causes increasing sulfate concentrations. In contrast, concentrations of sodium and chloride in the Bierawka River decrease downgradient from the pile because water in the river upgradient from the pile is already highly contaminated by these species from the discharge of mining waters. Concentrations of Fe and Mn in the river water are low, as a consequence of the precipitation of Fe and Mn oxide and hydroxides. Direct geochemical modeling was able to reproduce measured concentrations of conservative species (e.g., Na, Cl, and SO₄), but errors for metals and Ba were relatively large. In addition, calculated P_CO2 values in the river water are very high, suggesting that equilibrium with atmospheric P_CO2 and P_O2 has not been reached, and at least some reactions should be modeled as kinetic processes. High concentrations of Na, Cl, and SO₄ contribute to the contamination of the Odra River, which is joined by the Bierawka River farther downgradient, thus limiting the use of river water for recreation and other purposes.     

Evaluating a Canadian regional air quality model using ground-based observations in north-eastern Canada and United States

The simulated concentrations from a numerical 3-dimensional regional air quality model (MC2AQ) are compared to those of ground-based observations in north-eastern Canada and the United States. The model has oxidant chemistry for both inorganic and organic species and deposition routines driven online by a mesoscale compressible community meteorological model (MC2). A standard emission inventory of anthropogenic, natural and biogenic sources for the year 1990 for 21 atmospheric trace species was used in the simulation. The model was run for July 1999, because of the occurrence of a high ozone episode and the availability of the monitoring data for surface O3, SO2, NO, NO2 and NOx. The comparisons during the episode show that the model performs quite well for predicting concentrations and diurnal variations of the surface ozone. The predictions for other gaseous species show some discrepancies with observations, but they are consistent with the results from other models evaluated in the literature. The uncertainties in the emission inventory for these species might be the main causes of the discrepancies. Further studies are needed to improve the predictability of SO and NOx, especially as the model is developed to include particulate matter formation as a result of these gaseous precursors.     

Short-term effects of dimethoate on metabolic responses in Chrysolina pardalina (Chrysomelidae) feeding on Berkheya coddii (Asteraceae), a hyper-accumulator of nickel

Berkheya coddii Roessler (Asteraceae) is a hyper-accumulator of nickel, which can be used in phytomining and phytoremediation. Chrysolina pardalina Fabricius (Chrysomelidae) is a phytophagous leaf beetle, which may be useful in controlling population levels of B. coddii after it has been introduced into a new habitat. The aim of this study was to investigate the response of C. pardalina to topical application of dimethoate. Data recorded included the activity of acetylcholinesterase (AChE), the concentration of glutathione (GSH), and the activity of selected enzymes connected with GSH metabolism. Assays were carried out several times during the first 24h after exposure to dimethoate. At the dosages used in this study, dimethoate was not as toxic as expected. AChE activity was significantly decreased 14 and 24h after application. GST activity was significantly decreased 24h after application. GSTPx activity was significantly decreased 2, 14 and 24h after application. GR activity was significantly increased 4h after application. GSH concentration was significantly increased 24h after application. Long-term exposure to high levels of nickel may have caused adaptive changes in the enzymes that enable C. pardalina to deal with other stressors, including organophosphate pesticides.