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101.
Ocon CS Rodrigues Capítulo A Paggi AC 《Environmental pollution (Barking, Essex : 1987)》2008,156(1):82-89
The objective of this work was to analyse zoobenthic assemblages in the coastal sector of the Río de La Plata, Argentina, after a petroleum spill. Sampling stations were located in representative sites of various landscapes. Structure, composition, physico-chemical parameters and seasonal changes were recorded in order to assess taxocenosis evolution during the period 1999–2003. Recovery signs were estimated by means of biotic indices and the presence of sensitive species. Tolerant species were dominant in heavily polluted sites, with low diversity and water quality values, according to the biotic indices used. In certain zones, sediment quality remains impoverished, with a visible oil film on the surface. However, during the last sampling, some points showed an increase in biotic indices, pointing to a slight improvement in environmental conditions. 相似文献
102.
103.
104.
Rodrigues S Antunes SC Brandão FP Castro BB Gonçalves F Nunes B 《Journal of environmental monitoring : JEM》2012,14(6):1638-1644
The presence of pharmaceutical residues in the aquatic environment has recently received great attention, as potential adverse effects may arise from their presence. Inhibition of cholinesterases (ChE) has been widely used as an environmental biomarker of exposure to organophosphates (OP) and carbamate (CB) pesticides. However, other widespread anthropogenic contaminants - including pharmaceutical drugs - can exert toxic effects through ChE inhibition. Studies with aquatic species have shown that inhibition of ChE is associated with behavioral changes. Bearing this in mind, this work aimed to study the effects on individual behavior and acetylcholinesterase (AChE) activity of selected tissues of Lepomis gibbosus, after exposure to the anticholinesterasic drugs neostigmine and pyridostigmine. Results revealed that neostigmine significantly decreased the activity of AChE in the head (LOEC = 100 mg L(-1)), but not in dorsal muscle. On the other hand, pyridostigmine significantly decreased the activity of AChE in both the head (LOEC = 0.001 mg L(-1)) and dorsal muscle homogenates (LOEC = 100 mg L(-1)). The impairment of this enzymatic form was attained at ecologically relevant concentrations (in the case of pyridostigmine, for head AChE), which is an interesting finding, specially considering that these toxic effects occurred for a pharmaceutical compound. Contrarily, there were no significant differences in the behavior of L. gibbosus in any parameter, for neither drug. These results suggest that the behavioral parameters analyzed (scototaxis and lethargy) in L. gibbosus could not be regarded as suitable markers to assess the effects of drugs such as neostigmine and pyridostigmine. In contrast, the pattern of response elicited by cholinesterasic inhibition showed the usefulness of this toxicological parameter for the assessment of pharmaceuticals in the environment, namely anticholinesterasics. 相似文献
105.
Hg transfer from contaminated soils to plants and animals 总被引:1,自引:0,他引:1
S. M. Rodrigues B. Henriques A. T. Reis A. C. Duarte E. Pereira P. F. A. M. R?mkens 《Environmental Chemistry Letters》2012,10(1):61-67
Understanding the transfer of mercury (Hg) from soil to crops is crucial due to Hg toxicity and Hg occurrence in terrestrial
systems. Previous research has shown that available Hg in soils contributes to plant Hg levels. Plant Hg concentrations are
related to soil conditions and plant characteristics. Mechanistic models describing such soil–plant interactions are however
difficult to quantify. Here we performed a field study in agricultural, mining and industrial areas in Portugal to evaluate
potential food chain risks. The uptake of Hg by Italian ryegrass, ryegrass, orchard grass, collard greens and rye was measured
to calculate daily intakes (DI) of Hg for cows and sheep grazing. A total of 136 soil samples and 129 plant samples were analysed.
Results show that total Hg concentrations ranged from 0.01 to 98 mg kg−1 in soils; 0.01–5.4 mg kg−1 in shoots and 0.01–42 mg kg−1 in roots. Calculated DI ranged from 0.18 to 132 mg d−1 for cows, and from 0.028 to 23 mg d−1 for sheep. In 27 grassland sites, daily intakes exceeded the acceptable daily intake of both cows and sheep in view of food
safety considering Hg in animal kidneys evidencing potential risks to human health. The transfer of Hg from soil to crops
was described using empirical Freundlich-type functions. For ryegrass, orchard grass and collard greens, the soil-to-root
or soil-to-shoot transfer of Hg appeared to be controlled by the total soil Hg concentration and levels of Alox and Feox. Empirical functions allowed us to obtain realistic estimates of Hg levels in crops and can be used as an alternative to
mechanistic models when evaluating food chain risks of Hg contamination in agricultural soils. 相似文献
106.
Aline A. Becaro Maria Célia Siqueira Fernanda C. Puti Marcia Regina de Moura Daniel S. Correa José Manoel Marconcini Luiz H. C. Mattoso Marcos David Ferreira 《Environmental monitoring and assessment》2017,189(7):352
Several mutagenic agents may be present in substances released in the environment, which may cause serious environmental impacts. Among these substances, there is a special concern regarding the widespread use of silver nanoparticles (AgNP) in several products due to their widely known bactericidal properties, including in the medical field and the food industry (e.g., active packaging). The assessment of the effects of AgNP released in the environment, having different concentrations, sizes, and being associated or not to other types of materials, including polymers, is therefore essential. In this research, the objective was to evaluate the genotoxic and cytotoxic effects of AgNP (size range between 2 and 8 nm) on root meristematic cells of Allium cepa (A. cepa). Tests were carried out in the presence of colloidal solution of AgNP and AgNP mixed with carboxymethylcellulose (CMC), using distinct concentrations of AgNP. As a result, when compared to control samples, AgNP induced a mitotic index decrease and an increase of chromosomal aberration number for two studied concentrations. When AgNP was in the presence of CMC, no cytotoxic potential was verified, but only the genotoxic potential for AgNP dispersion having concentration of 12.4 ppm. 相似文献
107.
Martins LD da Silva Júnior CR Solci MC Pinto JP Souza DZ Vasconcellos P Guarieiro AL Guarieiro LL Sousa ET de Andrade JB 《Environmental monitoring and assessment》2012,184(5):2663-2676
In this study, particulate matter (PM) were characterized from a place impacted by heavy-duty vehicles (Bus Station) fuelled
with diesel/biodiesel fuel blend (B3) in the city of Londrina, Brazil. Sixteen priority polycyclic aromatic hydrocarbons (PAH)
concentrations were analyzed in the samples by their association with atmospheric PM, mass size distributions and major ions
(fluorite, chloride, bromide, nitrate, phosphate, sulfate, nitrite, oxalate; fumarate, formate, succinate and acetate; lithium,
sodium, potassium, magnesium, calcium and ammonium). Results indicate that major ions represented 21.2% particulate matter
mass. Nitrate, sulfate, and ammonium, respectively, presented the highest concentration levels, indicating that biodiesel
may also be a significant source for these ions, especially nitrate. Dibenzo[a,h]anthracene and indeno[1,2,3,-cd]pyrene were the main PAH found, and a higher fraction of PAH particles was found in diameters lower than 0.25 μm in Londrina bus station. The fine and ultrafine particles were dominant among the PM evaluated, suggesting that biodiesel
decreases the total PAH emission. However, it does also increase the fraction of fine and ultrafine particles when compared
to diesel. 相似文献
108.
Bigliardi Ana Paula Fernandes Caroline Lopes Feijo Pinto Edlaine Acosta dos Santos Marina Garcia Edariane Menestrino Baisch Paulo Roberto Martins Soares Maria Cristina Flores Muccillo-Baisch Ana Luíza da Silva Júnior Flavio Manoel Rodrigues 《Environmental science and pollution research international》2021,28(2):1409-1416
Environmental Science and Pollution Research - Coal extraction and processing generate environmental contamination, which has several negative impacts on human health. Hematological and biochemical... 相似文献
109.
Pedro Gon?alves Rodrigues Lu��s Moreira Gon?alves Paulo Jorge Magalh?es Jo?o Grosso Pacheco Jos�� Ant��nio Rodrigues Aquiles Ara��jo Barros 《Environmental Chemistry Letters》2011,9(3):405-410
An major research area in environmental chemistry is the development of methods for the analysis of biomarkers. Metallothioneins
are used as biomarkers in studies of heavy metals exposure in water, because metallothioneins are synthesized and accumulated
when organisms are exposed to toxic concentrations of pollutants. In this work, simple and sensitive voltammetric methods
were developed for metallothionein and copper (II) determinations in fish liver Lepomis gibbosus. Both analytical methodologies were optimized and applied to samples extracted from individuals previously submitted to sub-lethal
toxicological trials with copper sulphate (CuSO4) and cadmium chloride (CdCl2). The obtained results showed that both methods are very precise, sensitive, and involve simple sample preparation processes.
Moreover, metallothioneins showed better correlation with the toxic exposure than Cu2+. To the best of our knowledge, this is the first time that hepatic metallothioneins and Cu2+ contents are voltammetrically determined in order to be compared in their function as heavy metal biological indicators. 相似文献
110.
da Silveira RP Rodrigues AP Santelli RE Cordeiro RC Bidone ED 《Environmental monitoring and assessment》2011,181(1-4):165-173
This study addressed the identification and monitoring of pollution sources of terrestrial origin in rivers (domestic sewage and industrial effluents) and critical fluvial segments in highly polluted environments under tidal influence (mixing marine and continental sources) from Guanabara Bay Basin, Rio de Janeiro, Brazil. The mass balance of contaminants was determined in conditions of continuous flow (low tide) during dry season (lower dilution capability). The results allowed the evaluation of the potential of contaminant mass generation by the different river segments and the estimation of their natural and anthropogenic components. The water quality of Igua?ú and Sarapuí Rivers were evaluated for metals and biochemical oxygen demand. The method gave an excellent response, including the possibility of sources identification and contaminated river segments ranking. The approach also offers fast execution and data interpretation, being highly efficient. 相似文献