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71.
72.
George A. Allen Jung-a Annie Oh Petros Koutrakis Costas Sioutas 《Journal of the Air & Waste Management Association (1995)》2013,63(9):133-141
ABSTRACT Several recent studies have shown associations between ambient concentrations of particle mass (PM) and rates of morbidity and mortality in the general population. These studies have raised the issue of quality of coarse mass (CM, PM between 2.5 and 10 µm) data used for these purposes. CM data may have precision three or more times worse than the associated PM 2.5 or PM10 data, depending on the measurement method, PM 2.5 to PM 10 ratios, and CM concentrations. CM is measured either as the difference between collocated PM10 and PM2.5 samplers or more directly with a dichotomous (virtual impactor) sampler. CM precision for the difference method is degraded due to the increased errors inherent with using the difference between two independent measurements, as well as the high PM2.5 to PM10 ratios (and low CM concentrations) typical of the eastern United States. The dichotomous sampler (dichot) makes a more direct measurement of CM, but there is a potential for significant postexposure loss of particles from unoiled CM dichot filters, as well as uncertainties in the dichot’s CM channel enrichment factor. Compared to the dichot, low-volume inertial impactor samplers such as the Harvard Impactor (HI) or PM2.5 Federal Reference Method (FRM) are simpler to operate and maintain, provide sharper cut points, and do not require oiled filters to prevent loss of CM from the filter during transport. With the recent interest in CM spatial and temporal variability with respect to PM health effects, we have developed modifications to the HI PM method to provide measurements of 24-hour PM with estimated CM precision of better than 5% CV and r2 higher than 0.95, primarily by lowering field blank variability and increasing gravimetric analytical precision. These high-precision PM techniques are not limited to the HI sampler; they can also be applied to the PM2.5 FRM sampler. The measurement methods described here can be applied to future PM studies to avoid the potential problems with exposure assessment caused by CM measurements that have poor precision. 相似文献
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PROBLEM: This paper addresses the effects of driver factors and sign design features on the comprehensibility of traffic signs. METHODS: A survey was designed to capture subjects' personal particulars, ratings on sign features, and comprehension scores, and then administered to 109 Hong Kong full driving license holders. RESULTS: Years with driving license and education level were significant predictors of sign comprehensibility. Contrary to expectation, the driver factors of age group, years of active driving, hours of driving, last time driving, driving frequency, and non-local driving experience had no effect on comprehension performance. Sign familiarity was correlated with comprehension score for licensed drivers, whereas sign concreteness, simplicity, and meaningfulness were not. IMPACT ON INDUSTRY: The results of this study provide useful guidelines for designing more user-friendly traffic signs in the future. It identified particular driver groups who lacked good understanding of traffic signs, and this information may assist the relevant organizations to better allocate traffic training resources, and better target future studies of traffic sign comprehension. 相似文献
74.
Ona LF Alberto AM Prudente JA Sigua GC 《Environmental science and pollution research international》2006,13(3):177-183
Background Aims, and Scope. Lead (Pb) is a naturally occurring element that poses environmental hazards when present at elevated concentration.
It is being released into the environment because of industrial uses and from the combustion of fossil fuels. Hence, Pb is
ubiquitous throughout global ecosystems. The existence of potentially harmful concentrations of Pb in the environment must
be given full attention. Emissions from vehicles are major source of environmental contamination by Pb. Thus, it becomes imperative
that concentrations of Pb and other hazardous materials in the environment not only in the Philippines, but elsewhere in the
world be adequately examined in order that development of regulations and standards to minimize risk associated with these
materials in urban areas is continued. The objectives of this study were: (1) to determine the levels of Pb in soil from selected
urbanized cities in central region of the Philippines; (2) to identify areas with soil Pb concentration values that exceed
estimated natural concentrations and allowable limits; and (3) to determine the possible sources that contribute to elevated
soil Pb concentration (if any) in the study area.
Methods This study was limited to the determination of Pb levels in soils of selected urbanized cities located in central region
in the Philippines, namely: Site 1 – Tarlac City in Tarlac; Site 2 – Cabanatuan City in Nueva Ecija; Site 3 – Malolos City
in Bulacan; Site 4 – San Fernando City in Pampanga; Site 5 – Balanga City in Bataan; and Site 6 – Olongapo City in Zambales.
Soil samples were collected from areas along major thoroughfares regularly traversed by tricycles, passenger jeepneys, cars,
vans, trucks, buses, and other motor vehicles. Soil samples were collected from five sampling sites in each of the study areas.
Samples from the selected sampling sites were obtained approximately 2 to 3 meters from the road. Analysis of the soil samples
for Pb content was conducted using an atomic absorption spectrophotometer. This study was conducted from 2003 to 2004. Since
this study assumed that vehicular emission is the major source of Pb contamination in urban soil, other information which
the researchers deemed to have bearing on the study were obtained such as relative quantity of each gasoline type disposed
of in each city within a given period and volume of traffic in each sampling site. A survey questionnaire for gasoline station
managers was prepared to determine the relative quantity of each fuel type (diesel, regular gasoline, premium gasoline, and
unleaded gasoline) disposed of or sold within a given period in each study area.
Results and Discussion Analysis of soil samples for Pb content showed the presence of Pb in all the soil samples collected from the 30 sampling
sites in the six cities at varying concentrations ranging from 1.5 to 251 mg kg–1. Elevated levels of Pb in soil (i.e. greater
than 25 mg kg–1 Pb) were detected in five out of the six cities investigated. Site 4 recorded the highest Pb concentration
(73.9 ± 94.4 mg kg–1), followed by Site 6 (56.3 ± 17.1 mg kg–1), Site 3 (52.0 ± 33.1 mg kg–1), Site 5 (39.3 ± 19.0 mg kg–1),
and Site 2 (38.4 ± 33.2 mg kg–1). Soil Pb concentration in Site 1 (16.8 ± 12.2 mg kg–1) was found to be within the estimated
natural concentration range of 5 to 25 mg kg–1. Site 1 registered the least Pb concentration. Nonetheless, the average Pb
concentration in the soil samples from the six cities studied were all found to be below the maximum tolerable limit according
to World Health Organization (WHO) standards. The high Pb concentration in Site 4 may be attributed mainly to vehicular emission.
Although Site 4 only ranked 3rd in total volume of vehicles, it has the greatest number of Type B and Type C vehicles combined.
Included in these categories are diesel trucks, buses, and jeepneys which are considered the largest contributors of TSP (total
suspended particles) and PM10 (particulate matter less than 10 microns) emissions.
Conclusion Only one (San Juan in Site 4) of the thirty sampling sites recorded a Pb concentration beyond the WHO permissible limit of
100 mg kg–1. San Juan in Site 4 had a Pb concentration of >250 mg kg–1. On the average, elevated Pb concentration was evident
in the soil samples from San Fernando, Olongapo, Malolos, Balanga, and Cabanatuan. The average soil Pb concentrations in these
cities exceeded the maximum estimated natural soil Pb concentration of 25 mg kg–1. Average soil Pb concentration in Site 1
(16.8 mg kg–1) was well within the estimated natural concentration range of 5 to 25 mg kg–1. Data gathered from the study
areas showed that elevated levels of Pb in soil were due primarily to vehicular emissions and partly to igneous activity.
Recommendation and Outlook The findings of this study presented a preliminary survey on the extent of Pb contamination of soils in urban cities in central
region of Philippines Island. With this kind of information on hand, government should develop a comprehensive environmental
management strategy to address vehicular air pollution in urban areas, which shows as one of the most pressing environmental
problems in the country. Basic to this is the continuous monitoring of Pb levels and other pollutants in air, soil, and water.
Further studies should be conducted to monitor soil Pb levels in the six cities studied particularly in areas with elevated
Pb concentration. The potential for harm from Pb exposure cannot be understated. Of particular concern are children who are
more predisposed to Pb toxicity than adults. Phytoremediation of Pb-contaminated sites is strongly recommended to reduce Pb
concentration in soil. Several studies have confirmed that plants are capable of absorbing extra Pb from soil and that some
plants, grass species in particular, and can naturally absorb far more Pb than others. 相似文献
75.
Meta-analysis of environmental contamination by phthalates 总被引:1,自引:0,他引:1
Alexandre Bergé Mathieu Cladière Johnny Gasperi Annie Coursimault Bruno Tassin Régis Moilleron 《Environmental science and pollution research international》2013,20(11):8057-8076
Phthalate acid esters (PAE), commonly named phthalates, are toxics classified as endocrine-disrupting compounds; they are primarily used as additives to improve the flexibility in polyvinyl chloride. Many studies have reported the occurrence of phthalates in different environmental matrices; however, none of these studies has yet established a complete overview for those compounds in the water cycle within an urban environment. This review summarizes PAE concentrations for all environmental media throughout the water cycle, from atmosphere to receiving waters. Once the occurrences of compounds have been evaluated for each environmental compartment (urban wastewater, wastewater treatment plants, atmosphere, and the natural environment), we reviewed data in order to identify the fate of PAE in the environment and establish whether geographical and historical trends exist. Indeed, geographical and historical trends appear between Europe and other countries such as USA/Canada and China, however they remain location dependent. This study aimed at identifying both the correlations existing between environmental compartments and the processes influencing the fate and transport of these contaminants into the environment. In Europe, the concentrations measured in waterways today represent the background level of contamination, which provides evidence of a past diffuse pollution. In contrast, an increasing trend has actually been observed for developing countries, especially for China. 相似文献
76.
Annie‐Claude Parent François Anctil Véronique Cantin Marie‐Amélie Boucher 《Journal of the American Water Resources Association》2008,44(3):679-688
Abstract: Snowmelt largely affects runoff in watersheds in Nordic countries. Neural networks (NN) are particularly attractive for streamflow forecasting whereas they rely at least on daily streamflow and precipitation observations. The selection of pertinent model inputs is a major concern in NNs implementation. This study investigates performance of auxiliary NN inputs that allow short‐term streamflow forecasting without resorting to a deterministic snowmelt routine. A case study is presented for the Rivière des Anglais watershed (700 km2) located in Southern Québec, Canada. Streamflow (Q), precipitations (rain R and snow S, or total P), temperature (T) and snow lying (A) observations, combined with climatic and snowmelt proxy data, including snowmelt flow (QSM) obtained from a deterministic model, were tested. NN implemented with antecedent Q and R produced the largest gains in performance. Introducing increments of A and T to the NNs further improved the performance. Long‐term averages, seasonal data, and QSM failed to improve the networks. 相似文献
77.
Annie J. Morris Joseph J. Donovan Michael Strager 《Environmental Modeling and Assessment》2009,14(1):73-84
Streamflow values are commonly synthesized for locations where flow measurement stations are lacking or where only intermittent
measurements are available. In an Appalachian Mountains dataset comprised of 29 watersheds, the most appropriate among geomorphic,
geologic, and hydrogeologic datasets were selected for use in prediction of streamflow at watershed scale. A statistical model
was developed using principal components analysis (PCA) and cluster analysis (CA) for. Using CA on variables derived from
the PCA, an optimum set of variables was derived for predicting streamflow. Results indicate there are two categories of watersheds
in the study area. The first is strongly correlated with climatic variables (precipitation, temperature, elevation, and groundwater
recharge). The second is strongly correlated with two geomorphic variables (watershed slope and percentage of forested area).
The spatial distribution of cluster classifications shows that watersheds dominated by the climatic component are located
along the Allegheny Front while watersheds dominated by the geomorphic component are located in the Allegheny Plateau and
Valley and Ridge physiographic provinces. These variations between the Allegheny Plateau and Valley and Ridge physiographic
provinces suggest that, to accurately model streamflow, modeling needs be done based on natural physiographic boundaries rather
than political boundaries. In this physiographic setting, elevation seems to be a major control. 相似文献
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