Spatial and Temporal Variation of Ozone Concentrations at High Altitude Monitoring Sites in Germany

The present study deals with the characterisation and interpretation of hourly taken maximum ozone concentrations of each day at various high altitude monitoring sites in Germany and contributes to the understanding of ozone transport processes. The relation between long range transport of ozone as well as its precursors and high ozone concentrations is of special interest. Aim of this paper is to investigate the influence and importance of large scale meteorological circulation and source regions of anthropogenic ozone precursors to local ozone concentrations using 2-dimensional backward trajectories. Further, reasons for the spatial and temporal variation of ozone concentration levels will be shown. Investigating numerous cases a similar origin of air masses causing high ozone concentrations in Germany and uniform patterns at various sites could be identified.     

Detection of fetal cells in transcervical samples and prenatal diagnosis of chromosomal abnormalities

Transcervical samples collected by lavage, aspiration, and cytobrush from women between 6 and 13 weeks of gestation were tested for the presence of fetal cells using fluorescence in situ hybridization (FISH) with probes for chromosomes X, Y, 1, and 21, and by polymerase chain reaction (PCR) amplification of DNA sequences derived from chromosomes X, Y, and 21. With a few exceptions, a good correlation was observed between the results of sexing the fetuses using FISH or PCR on transcervical cell (TCC) samples retrieved by lavage and those obtained by testing fetal (placental) tissue. In a comparative study between TCC samples collected by lavage or cytobrush, the sex of the fetus was correctly diagnosed by PCR amplification of a Y-derived DNA sequence. Variable results were observed with samples obtained by aspiration, mainly because this procedure was found to be more prone to failure to remove thick mucus without previous injection of physiological saline. Chromosome 21-derived small tandem repeats (STRs) of fetal origin were successfully detected in about 40 per cent of TCC samples recovered by lavage. Two cases of chromosomal abnormalities, one of trisomy 21 and one of triploidy, were detected in TCC samples in the course of our investigations.     

ZnO nanoparticles dissolution,penetration and toxicity in human epidermal cells. Influence of pH

Environmental Chemistry Letters - Zinc oxide (ZnO) nanoparticles are widely used in cosmetics, food packaging, drug delivery and biosensors. There is therefore a risk of toxicity for organisms,...     

Thermal co-reduction approach to vary size of silver nanoparticle: its microbial and cellular toxicology

In recent years, silver nanoparticles (AgNPs) have attracted considerable interest in the field of food, agriculture and pharmaceuticals mainly due to its antibacterial activity. AgNPs have also been reported to possess toxic behavior. The toxicological behavior of nanomaterials largely depends on its size and shape which ultimately depend on synthetic protocol. A systematic and detailed analysis for size variation of AgNP by thermal co-reduction approach and its efficacy toward microbial and cellular toxicological behavior is presented here. With the focus to explore the size-dependent toxicological variation, two different-sized NPs have been synthesized, i.e., 60 nm (Ag60) and 85 nm (Ag85). A detailed microbial toxicological evaluation has been performed by analyzing minimum inhibitory concentration (MIC), minimum bactericidal concentration (MBC), diameter of inhibition zone (DIZ), growth kinetics (GrK), and death kinetics (DeK). Comparative cytotoxicological behavior was analyzed by 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay. It has been concluded by this study that the size of AgNPs can be varied, by varying the concentration of reactants and temperature called as “thermal co-reduction” approach, which is one of the suitable approaches to meet the same. Also, the smaller AgNP has shown more microbial and cellular toxicity.     

ASSESSMENT OF IMPACTS OF CLIMATE CHANGE ON WATER QUALITY IN THE SOUTHEASTERN UNITED STATES1

ABSTRACT: An assessment of current and future water quality conditions in the southeastern United States has been conducted using the EPA BASINS GIS/database system. The analysis has been conducted for dissolved oxygen, total nitrate nitrogen and pH. Future streamflow conditions have been predicted for the region based on the United Kingdom Hadley Center climate model. Thus far, the analyses have been conducted at a fairly coarse spatial scale due to time and resource limitations. Two hydrologic modeling techniques have been employed in future streamflow prediction: a regional stochastic approach and the application of a physically based soil moisture model. The regional model has been applied to the entire area while the physically based model is being used at selected locations to enhance and support the stochastic model. The results of the study reveal that few basins in the southeast exhibit dissolved oxygen problems, but that several watersheds exhibit high nitrogen levels. These basins are located in regions of intense agricultural activity or in proximity to the gulf coast. In many of these areas, streamflow is projected to decline over the next 30–50 years, thus exacerbating these water quality problems.     

Evaporative Cooling of Water in a Small Vessel Under Varying Ambient Humidity

Evaporative cooling of water in a small porous clay vessel was studied under controlled humidity conditions. In steady-state experiments performed at an ambient temperature of 23 °C, the cooling effect increased from 4.7 to 8.3 °C as the ambient relative humidity decreased from 60 to 15%. External heat and mass transfer coefficients, estimated from the steady-state measurements, were used in mathematical models to predict the experimentally observed transient temperature variation of the water under ramp changes of the ambient relative humidity. With a prototypical cool chamber containing water tested in Kolkata, India under an ambient temperature of 34.5–35 °C, the cooling effect reached a maximum of 7 °C between 3 and 3:30 PM and then declined to 4.5 °C around 6 PM.