Probabilistic approach for estimating the release of contaminants under field management scenarios

A probabilistic approach is presented for estimating the release of contaminants by leaching, when wastes are being considered for disposal in a class of landfills but the specific landfill disposal site is uncertain. A simple percolation and equilibrium-based release model is used in conjunction with laboratory testing results and observations of field leachate characteristics for municipal solid waste landfills, hazardous waste landfills and industrial co-disposal landfills. The approach is applied for assessing the efficacy of potential treatment processes for mercury contaminated soils. For each landfill scenario, historical values of leachate pH and annual leachate generation quantities were used to derive the probability distribution functions of the field pH and LS ratio that may be expected to contact the disposed material over an estimated time period of 100 years. For each potential treatment process, laboratory testing was used to establish the treated material's leaching characteristics as a function of pH LS ratio. This approach allowed determination of distribution frequencies and limit values for release estimates instead of single point estimates. The probability of the mass of a constituent of interest released exceeding a hypothetical threshold was examined for each treatment process and landfill system. Results of the probabilistic analysis allowed for integration of a range of data and provided a good basis for assessing the efficacy of the examined treatment processes over the three assumed disposal scenarios.     

Multi-Scale Characterization of Fractured Rocks Used as a Means for the Realistic Simulation of Pollutant Migration Pathways in Contaminated Sites: A Case Study

An integrated methodology is developed to quantify the geostatistical and transport properties of fractured media at multiple scales. Such information is helpful in developing numerical models and estimating the up-scaled transport coefficients of fractured formations. An oil-contaminated fractured site, overlying granite rock and situated in northern Spain, is investigated, and a macroscopic geological model that quantifies the regional distribution of faults and fractures over the entire area is established. The methodology is based on the measurement of fractured outcrops in the field (scale ～1-100 m), the collection of representative fractured samples and measurement of the fracture aperture (scale ～0.01-1 mm), and the analysis of macroscopic characteristics (scale ～1-5 km) of fracture/faults. The multi-scale fracture properties are utilized to construct a discrete fracture/fault network model which provides input data to a macroscopic simulator of contaminant transport in fractured porous media. The transient NAPL migration pathways are predicted for one scenario of pollution. Such information is helpful in the risk assessment of fractured contaminated sites.     

New directions in Mexican environmental policy

Since taking office 1 December 1988, Mexico's incumbent president, Carlos Salinas de Gortari, has introduced important innovations in environmental policy that distinguish his administration from those of his predecessors. Greater administrative continuity, improved regulatory capacity achieved through statutory change, focused priorities centering on pollution abatement in Mexico City, and an aggressive search for external financing for pollution control are hallmarks of Salinas' approach. The success of these environmental reforms depends heavily on economic recovery, however, and environmental policy still suffers from underfunding, bureaucratic fragmentation, and heavy reliance on voluntarist enforcement mechanisms. Recently, U.S. congressional debate on a proposed free trade agreement with Mexico has been a factor in spurring the Salinas government to take new antipollution and conservation measures. Mexico's growing environmental movement is also an important force behind the government's new responsiveness in environmental matters. The Salinas administration recognizes the issue's political salience and has sought to defuse environmental criticism using a large arsenal of resources at its disposal. Salinas' environmental policy strategy may thus be characterized as both proactive and reactive in nature. While the reforms are evidence that Mexico is beginning to take environmental matters more seriously, economic recovery and sustained environmental activism remain vital to further progress.     

No detectable impact of small-scale disturbances on ‘blue carbon’ within seagrass beds

Seagrass meadows are among the most efficient and long-term carbon sinks on earth, but disturbances could threaten this capacity, so understanding the impacts of disturbance on carbon stored within seagrass meadows—‘blue carbon’—is of prime importance. To date, there have been no published studies on the impacts of seagrass loss on ‘blue carbon’ stocks. We experimentally created several kinds of small-scale disturbances, representative of common grazer and boating impacts, within seagrass (Zostera nigracaulis) meadows in Port Phillip Bay (Australia) and measured the impacts on sediment organic carbon stocks (‘C _org’, and other geochemical variables—%N, δ¹³C, δ¹⁵N). Disturbance had no detectable effect on C _org levels within seagrass sediments, even for high-intensity disturbance treatments, which remained bare (i.e. no seagrass recovery) for 2 years after the disturbance. These findings challenge the widely held assumption that disturbance and concomitant loss of seagrass habitat cause release of carbon, at least for small-scale disturbances. We suggest that larger (e.g. meadow scale) disturbances may be required to trigger losses of ‘blue carbon’ from seagrass meadows.     

Agricultural waste from the tequila industry as substrate for the production of commercially important enzymes

Approximately 1 million tons of Agave tequilana plants are processed annually by the Mexican Tequila industry generating vast amounts of agricultural waste. The aim of this study was to investigate the potential use of Agave tequilana waste as substrate for the production of commercially important enzymes. Two strains of Aspergillus niger (CH-A-2010 and CH-A-2016), isolated from agave fields, were found to grow and propagate in submerged cultures using Agave tequilana waste as substrate. Isolates showed simultaneous extracellular inulinase, xylanase, pectinase, and cellulase activities. Aspergillus CH-A-2010 showed the highest production of inulinase activity (1.48 U/ml), whereas Aspergillus niger CH-A-2016 produced the highest xylanase (1.52 U/ml) and endo-pectinase (2.7U/ml) activities. In both cases production of enzyme activities was significantly higher on Agave tequilana waste than that observed on lemon peel and specific polymeric carbohydrates. Enzymatic hydrolysis of raw A. tequilana stems and leaves, by enzymes secreted by the isolates yielded maximum concentrations of reducing sugars of 28.2 g/l, and 9.9 g/l respectively. In conclusion, Agave tequilana waste can be utilized as substrate for the production of important biotechnological enzymes.     

Manufacturing SMEs doing it for themselves: developing,testing and piloting an online sustainability and eco-innovation toolkit for SMEs

ABSTRACT

Public discourse frequently cites the damaging activities of large organisations on global environmental issues, but smaller organisations are rarely, if ever, featured. Small and Medium Enterprises (SMEs) make up 99% of all businesses in the EU, cumulatively causing more industrial pollution and producing more waste than larger businesses. However, large companies are more likely to address sustainability issues than smaller ones. SMEs need help to change. In a collaborative approach, an online sustainability framework was developed to overcome the barriers contributing to the slow uptake in environmental management in SMEs. The views of owner-managers were incorporated throughout the development process. Best practice environmental tools and training were identified, which were designed in an SME-friendly way and made available online. This paper describes the development of the pilot Sustainability and Eco-Innovation (SEco) toolkit, followed by an analysis of its use. This research finds that a self-led toolkit was not enough to nudge SMEs to address environmental issues, despite being approved by owner-managers at each step.     

The transboundariness approach and prioritization of transboundary aquifers between Mexico and Texas

“Transboundariness” refers to a new approach that identifies and prioritizes transboundary aquifers using socio-economic and political criteria, improving their characterization by using other variables in addition to their mere physical boundaries. This approach is applied to the hydrogeological units/aquifers shared by Mexico and Texas, with the following results. First, the rankings agree with the current level of attention to transboundary aquifers in the region by both countries, providing a quantifiable system that could be tested in other transboundary aquifers. Second, this approach provides a holistic and integrative perspective for transboundary aquifer assessment and prioritization. Third, this prioritization exercise expands the criteria currently used into a more integrative regime of groundwater links to the community as a whole. Finally, the results reflect not only how the transboundary aquifers are being used (or neglected) but also the socio-political context of the populations that depend on these resources for current and future development.     

Brazil’s Amazonian protected areas as a bulwark against regional climate change

Regional Environmental Change - Brazil’s Amazonian protected areas play an important role in maintaining the environmental services of the region, including Amazonia’s role in regional...     

Prenatal diagnosis of fragile x syndrome: (cgg)n expansion and methylation of chorionic villus samples

Fragile X syndrome is the most common form of inherited mental retardation, due to an expansion of the (CGG)_n trinucleotide repeat in the FMR-1 gene and hypermethylation of its 5′ upstream CpG island. Two major problems remain to be resolved for fragile X prenatal diagnosis: the abnormal methylation patterns of chorionic villus samples (CVS) and the inability to predict the mental status of females with the full mutation. We present here the results of ten prenatal diagnoses of fragile X syndrome using Southern blotting and polymerase chain reaction (PCR) amplification, and the analysis of 50 further CVS to test the methylation status of the CpG island of the FMR-1 gene. In the ten ‘at-risk’ CVS, eight normal (five males and three females) and two affected male fetuses were detected. Absence of methylation in the CVS was observed in two cases, which was not found upon subsequent examination of the newborn or of fetal tissues. In the 50 CVS not ‘at risk’ for fragile X syndrome, abnormal fragment patterns for probe StB12.3 were detected in 32 per cent for female and 24 per cent for male fetuses. This abnormal pattern could be due to absent or partial methylation of the CpG island of the FMR-1 gene in chorionic villus tissues.     

Primary prevention of neural tube defects with folic acid supplementation: Cuban experience

Folic acid (5 mg) was given daily, for not less than one menstrual period before conception and until the tenth week of pregnancy, to 81 women (FS) with a history of a previous neural tube defect (NTD) birth. There was no NTD recurrence among this group or among the offspring of a further 20 women (PS) whose folic acid supplementation fell short of the full regime. In another 114 women who became pregnant without folic acid supplementation (US), there were four NTD recurrences (3.5 per cent). Our results suggest that folic acid supplementation might be an effective method of primary prevention of neural tube defects.