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41.
Falandysz J Wyrzykowska B Strandberg L Puzyn T Strandberg B Rappe C 《Journal of environmental monitoring : JEM》2002,4(6):929-941
The concentration, pattern, bioaccumulation and biomagnification features of many chlorobiphenyl congeners including non- and mono-ortho chlorine substituted members have been determined in a pelagic food chain including mixed phyto- and zooplankton, herring (Clupea harengus), harbour porpoise (Phocoena phocoena) and black cormorants (Phalacrocorax carbo sinensis) collected from the southern part of the Baltic Proper. TCDD (tetrachlorodibenzo-p-dioxin) toxic equivalents (TEQs) in plankton, herring, harbour porpoise and cormorants were 0.42, 5.3, 79 and 2,700 pg g(-1) lipid weight, respectively. Concentrations of total polychlorinated biphenyls (PCBs) in plankton, herring, harbour porpoise and cormorants were 1.9, 120, 8700 and 2,100 ng g(-1) wet weight (210, 1,300, 10,000 and 42,000 ng g(-1) lipid weight) respectively. Herring, harbour porpoise and black cormorant apparently bioaccumulate many PCBs found in their food, and the values of the bioaccumulation factors (BAFs) for PCBs were approximately 10 in herring, 35 in harbour porpoise and up to 300 in breast muscle of cormorants. Harbour porpoise clearly is able to metabolize the most toxic non-ortho PCBs (no. 77, 126 and 169) and a few mono-ortho PCBs (no. 114, 123 and 156), while all non- and mono-ortho PCBs are bioaccumulated by herring. Penta-, hexa- and hepta-CBs were the dominatant homologue classes both in the muscle tissue and liver. PCB congeners nos. 201, 209, 172/192, 194 and 195 were characterized by the largest BAFs (between 100 and 300). Principal component analysis has been used to analyse the interdependences and differences in the CB congener accumulation patterns between the components of the investigated pelagic food web. 相似文献
42.
Development and validation of methods for environmental monitoring of cyclophosphamide in workplaces
Methods to monitor contamination of workplaces with antineoplastic drugs have been developed and validated. Cyclophosphamide (CP) was used as a model compound as it is one of the most commonly used antineoplastic drugs. A wipe sampling method to detect contamination with CP at surfaces was developed. A personal air sampling method to sample gas and vapour on solid sorbent tubes and particles with filters was also developed. Wipe and filter samples were extracted and sorbent samples were eluted, all with ethyl acetate. The samples were analysed with liquid chromatography tandem mass spectrometry. (2)H(6)-labelled cyclophosphamide was used as an internal standard. The between-day precision was 2-5% for wipe samples, 4-6% for sorbent samples and 3-8% for filter samples. The limit of detection was 0.02 ng CP per sample for the wipe and filter methods and 0.03 ng CP per sample for the solid sorbent method. Wipe sampling on surfaces made of different materials resulted in mean recoveries between 78-106%. The desorption recovery was between 97-102% for the wipe samples, 97% for the sorbent samples and 101% for the filter samples. Samples were stable for up to 2 months at 5 degrees C and -20 degrees C and for about 2 d at room temperature. The developed methods were applied to the measurement of contamination with CP in a hospital pharmacy. Trace amounts of CP, 1.3 and 1.4 ng, were detected on surfaces in the pharmacy. 相似文献
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水体中重要污染元素化学形态分析研究方法及其进展 总被引:3,自引:0,他引:3
概述了元素化学形态分析的意义、概念和范围,元素化学形态分析与模拟计算方法,并分别对某些重要元素的化学形态分析方法的进展作了综述,介绍了115篇文献。 相似文献
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综述了酶传感器、酶联免疫传感器、液相色谱、荧光光谱和流动注射化学发光等方法在环境水西维因残留检测中的应用,对各种分析方法的工作原理作了简要介绍,并对其应用前景作了展望. 相似文献
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中国生物入侵现状及对策 总被引:6,自引:0,他引:6
生物入侵是当今世界三大难题之一,中国也是世界上遭受生物入侵危害最大的国家之一.入侵中国的生物主要是以陆生植物为主,源地以美洲为主.在地域分布上南方和东部地区比较严重.主要侵入途径是以人类活动影响为主,自然扩散比重比较小.生物入侵对我国造成的危害十分巨大,解决生物入侵的主要对策是加强立法,全民重视. 相似文献
50.
高浓度印染废水处理工程工艺条件与实例分析 总被引:8,自引:0,他引:8
研究以三相生物流化床作为工程化反应器处理印染废水的工程工艺条件及操作特性,分别测定流化床内的气相含率,兴体循环速度及体积氧传质系数。 相似文献