Concentrations and Source Characteristics of Airborne Carbonyl Compounds Measured Outside Urban Residences

Abstract

This paper presents the analysis of ambient air concentrations of 10 carbonyl compounds (aldehydes and ketones) measured in the yards of 87 residences in the city of Elizabeth, NJ, throughout 1999–2001. Most of these residences were measured twice in different seasons; the sampling duration was 48 hr each time. The authors observed higher concentrations for most of the measured carbonyl compounds on warmer days, reflecting larger contributions of photochemical reactions on warmer days. The estimated contributions of photochemical production varied substantially across the measured carbonyl compounds and could be as high as 60%. Photochemical activity, however, resulted in a net loss for formaldehyde. The authors used stepwise multiple linear regression models to evaluate the impact of traffic sources and meteorological conditions on carbonyl concentrations using the data collected on colder days (with lower photochemical activities). They found that the concentrations of formal-dehyde, acetaldehyde, acrolein, propionaldehyde, crotonaldehyde, benzaldehyde, glyoxal, and methylglyoxal significantly decreased with increasing distance between a measured residence and one or more major roadways. They also found significant negative associations between concentrations for most of the measured carbonyl compounds and each of the following meteorological parameters: mixing height, wind speed, and precipitation.     

Linking academic and local knowledge: community-based research and service learning for sustainable rural development in Hungary

Discussions about the potential role of academic and research institutions in regional sustainability initiatives (RSIs) inevitably raise the issue of the role of science in society in general. In democratic societies, it can be argued that science–society relationships should be based on establishing and institutionalizing mutual dialogues, making public concerns not only visible but the public as equal partner. In order to fulfil the social responsibilities of academic institutions involved in RSIs through establishing dialogues with diverse stakeholders, a possible methodology is conducting participatory action research (PAR) combined with the educational model of service learning. The PAR project reported here aims at facilitating a bottom-up, micro-region level sustainability planning and development process in one of the most socio-economically disadvantaged rural areas of north-east Hungary. Some of the main results of this university–community partnership were its contribution to sustainability, including the activation of local capabilities and networking across various local stakeholder groups through various small-scale projects and the co-production of a socially grounded and landscape-based rural development plan for the micro-region.     

Quantifying MTBE biodegradation in the Vandenberg Air Force Base ethanol release study using stable carbon isotopes

Compound-specific isotope analysis (CSIA) was used to assess biodegradation of MTBE and TBA during an ethanol release study at Vandenberg Air Force Base. Two continuous side-by-side field releases were conducted within a preexisting MTBE plume to form two lanes. The first involved the continuous injection of site groundwater amended with benzene, toluene and o-xylene ("No ethanol lane"), while the other involved the continuous injection of site groundwater amended with benzene, toluene and o-xylene and ethanol ("With ethanol lane"). The delta(13)C of MTBE for all wells in the "No ethanol lane" remained constant during the experiment with a mean value of -31.3 +/- 0.5 per thousand (n=40), suggesting the absence of any substantial MTBE biodegradation in this lane. In contrast, substantial enrichment in (13)C of MTBE by 40.6 per thousand, was measured in the "With ethanol lane", consistent with the effects of biodegradation. A substantial amount of TBA (up to 1200 microg/L) was produced by the biodegradation of MTBE in the "With ethanol lane". The mean value of delta(13)C for TBA in groundwater samples in the "With ethanol lane" was -26.0 +/- 1.0 per thousand (n=32). Uniform delta(13)C TBA values through space and time in this lane suggest that substantial anaerobic biodegradation of TBA did not occur during the experiment. Using the reported range in isotopic enrichment factors for MTBE of -9.2 per thousand to -15.6 per thousand, and values of delta(13)C of MTBE in groundwater samples, MTBE first-order biodegradation rates in the "With ethanol lane" were 12.0 to 20.3 year(-1) (n=18). The isotope-derived rate constants are in good agreement with the previously published rate constant of 16.8 year(-1) calculated using contaminant mass-discharge for the "With ethanol lane".     

QUANTIFICATION OF THE WATER BUDGET AND NUTRIENT LOADING IN A SMALL PEATLAND1

ABSTRACT: Few water budgets exist for specific types of wetlands such as peatlands, even though such information provides the basis from which to investigate linkages between wetlands and upland ecosystems. In this study, we first determined the water budget and then estimated nutrient loading from an upland farm field into a 1.5 ha, kettle-block peatland. The wetland contains highly anisotropic peat and has no distinct, active layer of groundwater flow. We estimated the depth of the active layer using Fick's law of diffusion and quantified groundwater flow using a chemical mass balance model. Evapotranspiration was determined using MORECS, a semi-physical model based on the Penman-Monteith approach. Precipitation and surface outflow were measured using physical means. Groundwater provided the major inflow, 84 percent (44,418 m³) in 1993 and 88 percent (68,311 m³) in 1994. Surface outflow represented 54 percent (28,763 m³) of total outflows in 1993 and 48 percent (37,078 m³) in 1994. A comparison of several published water budgets for wetlands and lakes showed that error estimates for hydrologic components in this study are well within the range of error estimates calculated in other studies. Groundwater inflow estimates and nutrient concentrations of three springs were used to estimate agricultural nutrient loading to the site. During the study period, nutrient loading into the peatland via groundwater discharge averaged 24.74 kg K ha^-1, 1.83 kg total inorganic P ha^d, and 21.81 kg NO₃-N ha^-1.     

Evaluating landfill disposal of chromated copper arsenate (CCA) treated wood and potential effects on groundwater: evidence from Florida

Chromated copper arsenate (CCA) treated wood has been used for more than 50 years. Recent attention has been focused on appropriate disposal of CCA-treated wood when its service life ends. Groups in the US and Europe concerned with the possibility of arsenic migration to groundwater from disposed CCA-treated wood have proposed that consumers be required to dispose of the wood as a hazardous waste, in the most protective of landfills. We examined available data for evidence of arsenic migration from unlined construction and demolition (C&D) debris landfills in Florida, where CCA-treated wood is disposed. Florida was chosen because soil, groundwater, landfill design, weather, and levels of CCA-treated wood use make the state a uniquely sensitive indicator for observing arsenic migration from CCA-treated wood disposal sites, should it occur. We developed and quality-checked a CCA-treated wood disposal model to estimate the amount of wood and associated arsenic disposed. By 2000, an estimated 13 million kg of arsenic in CCA-treated wood was disposed in Florida; however, groundwater monitoring data do not indicate that arsenic is migrating from unlined C&D landfills. Our results provide evidence that highly stringent regulation of CCA-treated wood disposal, such as treatment as a hazardous waste, is unnecessary.     

Movements,behavior, and habitat utilization of yellowfin tuna (<Emphasis Type="Italic">Thunnus albacares</Emphasis>) in the northeastern Pacific Ocean,ascertained through archival tag data

Sixty-eight yellowfin tuna, Thunnus albacares, (60-135 cm fork length) were caught and released with implanted archival tags offshore off Baja California, Mexico, during October 2002 and October 2003. Thirty-six fish (53%) were recaptured and the data were downloaded from all 36 recovered tags. Time at liberty ranged from 9 to 1,161 days, and the data were analyzed for the 20 fish that were at liberty for 154 or more days. The accuracy in the position estimates, derived from light-level longitude data and sea-surface temperatures (SSTs) based latitude, is about 0.41° in longitude and 0.82° in latitude, in this region. The movement paths, derived from position estimates, for the 20 yellowfin indicated that 19 (95%) remained within 1,445 km of their release locations. The estimated mean velocity along movement paths was 77 km/day. The southern and northern seasonal movement paths observed for yellowfin off Baja California are influenced by the seasonal movements of the 18°C SST isotherm. Cyclical movements to and from suitable spawning habitat (≥24°C SST) was observed only for mature fish. For the 12 fish that demonstrated site fidelity, the mean 95 and 50% utilization distributions were 258,730 km² and 41,260 km², respectively. Evaluations of the timed depth records resulted in discrimination of four distinct behaviors. When exhibiting type-1 diving behavior (78.1% of all days at liberty) the fish remained at depths less than 50 m at night and did not dive to depths greater than about 100 m during the day. Type-2 diving behavior (21.2% of all days at liberty) was characterized by ten or more dives in excess of 150 m during the day. Type-2 diving behavior is apparently a foraging strategy for fish targeting prey organisms of the deep-scattering layer during the day, following nighttime foraging within the mixed layer on the same prey. Yellowfin tuna exhibited occasional deep-diving behavior, and some dives exceeded 1,000 m, where ambient temperatures were less than 5°C. Surface-oriented behavior, defined as the time fish remained at depths less than 10 m for more than 10 min, were evaluated. The mean number and duration of surface-oriented events per day for all fish was 14.3 and 28.5 min, respectively. Habitat utilization of yellowfin, presented as monthly composite horizontal and vertical distributions, indicates confined geographical distributions, apparently resulting from an affinity to an area of high prey availability. The vertical distributions indicate greater daytime depths in relation to a seasonally deeper mixed layer and a greater proportion of daytime at shallower depths in relation to a seasonally shallower mixed layer.     

Guided group discussion and attitude change: The roles of normative and informational influence

Kurt Lewin and others have showed that group discussion effectively changed attitudes and behaviors compared to individually targeted messages. This study examines the roles of normative and informational social influence in this effect. High school students heard a message about replacing toxic products with nontoxic alternatives; classes were randomly assigned to hear the message delivered as a lecture or via guided group discussion. For female students (N=250 in 26 classes), HLM mediation analyses suggested normative influence predominated: Discussion was more effective than lecture and this effect was fully mediated by students’ perceptions that other students endorsed nontoxics. Content analyses of students’ comments indicated that three kinds of remarks led female students to this perception: (1) sharing knowledge about nontoxics; (2) asking questions about nontoxics; and (3) little praise for toxic products. For male students in separate HLM analyses (N=107 in 19 of the same classes), informational influence was most apparent: Postmeeting attitudes were higher after discussion than lecture, and this effect was partially mediated by cognitive elaboration about the message (but not perceptions others endorsed the message). In addition, males’ quiz grades were higher after discussion, and students’ comments fully mediated the discussion to quiz grades relationship. Results support the importance of hearing others’ promessage comments for changing socially motivated behaviors, although the routes of influence appear to differ for these samples of male and female students.