NO oxidation performance and kinetics analysis of BaMO3 (M=Mn,Co) perovskite catalysts

Environmental Science and Pollution Research - Perovskite is an efficient and emerging catalyst for NO oxidation. In this study, BaMnO3 and BaCoO3 perovskite catalysts were synthesized by the...     

Adsorption of volatile benzene series compounds by surface-modified glass fibers: kinetics,thermodynamic adsorption efficiencies,and mechanisms

Environmental Science and Pollution Research - The presence of volatile benzene series compounds (VBSCs) in the environment is continually increasing, with the potential for negative effects on...     

Identifying the crash characteristics on freeway segments based on different ramp influence areas

Objective: This study aimed to explore the relationship between crash types and different freeway segments and identify the factors contributing to crashes on different freeway segments. Unlike most of the previous studies on freeway segments, this study separately investigates basic freeway segments, single ramp influence segments, and multiple ramp influence segments.

Methods: Nonlinear canonical correlation analysis (NLCCA) and proportionality test were used to identify the relationship between crash types and different freeway segments. The data sets for the different freeway segments accumulated for this study consist of 9,867 crash samples with complete information on all 22 chosen variables. A multinomial logit model (MNL) was used to estimate the influence of crash factors on different freeway segments.

Results: The results show that weaving and diverge overlap influence segments (WD) are more likely to have injury or fatal crashes; diverge and diverge overlap influence segments (DD) are more likely to have property damage–only (PDO) crashes; merge and merge overlap influence segments (MM) are more likely to have sideswipe crashes; and WD have non-sideswipe crashes; WD and weaving overlap influence segments (MW) are more likely to have rear end crashes; and MM segments are less likely to have hit object crashes. The contributing factors are identified by MNL and the results show that different traffic variables, environmental variables, vehicle variables, driver variables, and geometric variables significantly affected the likelihood of crashes on different freeway segments.

Conclusions: Investigation of crash types and factors contributing to crashes on different freeway segments is based on multiple ramp influence segments, which can promote a better understanding of the safety performance of various freeway segments.     

Experimental study on the stability of the ClHgSO3 − in desulfurization wastewater

Environmental Science and Pollution Research - Wet flue gas desulfurization technologies have received much concern for their superior performance on co-controlling the acid gases and mercury....     

Estimation of emission reduction potential in China’s industrial sector

The industrial sector is usually the largest economy sector for carbon emissions in many countries, which made it the sector with greatest potential for carbon reduction although the process duration might be very long. Studying the potential of industrial emission reduction has great significance in estimating the carbon emission peak of China on the one hand, and adjusting its strategy in international climate change negotiations. By employing the economic accounting method, this article estimates the emission reduction potential of China’s Industrial sector for the period of 2010–2050. It reveals that, taking 2030 as the year when the emission reaches the peak, the total reduction can be 8.38 billion tons (bts) for the period of 2010–2030, with 3.12 bts from structural reduction while 5.26 bts from intensity reduction. Afterwards, reduction will continue with a total amount of 6.59 bts for the period of 2030–2050, where the structural reduction accounts for 2.47 bts, and intensity reduction 4.115 bts. If both industrial and energy consumption structures are improved during the above period, the reduction potential can be even greater, e.g. the emission peak can arrive five years earlier (in the year of 2025) and the peak value can decline by about 8% as compared to the original estimation. Reviewing the trajectory of emission changes in developed countries indicates that the industry sector can contribute to the overall reduction targets through the dual wheels of structural reduction and intensity reduction, even beyond the emission peak. This article concludes with the following policy suggestions. (1) Our estimation on the emission peak of the industrial sector suggests that China should avoid any commitment earlier than 2030 on the timeline of the overall emission peak; (2) the great potential of industrial emission reduction can improve the situation of China in climate change negotiation, where the intensity reduction can serve as an important policy option. (3) Reduction potential can be further enhanced through technology advancement, which requires furthering of market oriented reforms and improvement of institutional design. (4) To secure the reduction effects of the industrial structure adjustment, the balanced development among different regions should be encouraged in order to avoid the reverse adjustment caused by industrial transferring. (5) International cooperation promoting the application and development of industrial emission reduction technologies, including carbon capture, utilization and storage, should be encouraged.     

水电站鱼类人工增殖放流标记方法研究概述

鱼类人工增殖放流是缓解水电建设对鱼类资源影响的一个重要措施,也是一项非常复杂的系统工程。标记放流可以帮助人们准确获得鱼类的种群信息,是鱼类增殖放流效果评估的重要手段之一。目前,国内外常用的标记方法主要有体外标记法、体内标记法、自然标记法、化学标记法、生物遥测法、分子遗传标记法,文章介绍了这些标记方法的特点及应用,分析了中国鱼类标记放流方面存在的问题并提出了加强鱼类标记方法的科学研究、采用多种途径对标记鱼类进行回收、建立科学合理的回收体系和加强鱼类回收后研究的建议。     

黄骅港三期筒仓防煤体高温对策研究

黄骅港三期是单个容量3万吨共24座筒仓的超大型群仓储煤系统,储煤主要来自神华集团所属煤矿,少部分为外购协作煤,多属易自燃煤种。为更有效控制火灾隐患,通过工艺流程分析及危险因素提取,试运营期间数据分析等,研究了致使煤体高温的危险因素和对策。发现运输过程中出现因雨淋而产生润湿热,因粉尘积聚发热的危险;筒仓储煤曾出现数天内温度从10℃升高到45℃,筒仓内有毒有害气体可能超限的危险;输煤皮带可能跑偏引起摩擦生热的危险等。试运营期间针对性采取了喷洒抑尘剂,设置警报系统及检测装置,加强皮带机监控和管理等安全措施。     

生活垃圾焚烧发电厂低温SCR烟气脱硝技术研究

针对生活垃圾焚烧产生的NOx的处理要求提高,提出一种低温SCR脱硝工艺,给出了该工艺的流程图,并详细分析了影响脱硝效果的因素,比较分析了相比SNCR、常规SCR,低温SCR工艺所具备的优势。     

PVA降解酶催化反应的动力学方程

(上接2012年第6期第255页)结合图2发现,混合菌系产生的PVA降解酶在PVA浓度4 g/L以下时显示出一级反应特征。即,当底物浓度低时,酶的活性中心未被饱和,反应速度随底物浓度上升而成正比关系。因此,底物浓度越大,酶反应速率越快,PVA降解酶酶活越大。利用双倒数作图法求解该PVA降解酶酶催化的米氏方程。将图2中的PVA浓度([S])和PVA降解酶酶活(酶催化反应速率V)化为对应的1/[S]和1/V(见表2)。