改性生物炭材料对稻田原状和外源镉污染土钝化效应

为研究改性处理后的生物炭对镉污染土壤钝化效应,以油菜秸秆制备的生物炭(BC)为原材料,通过不同处理(HNO_3氧化、NaOH碱化、KMnO_4浸渍、FeCl_3浸渍)制备改性炭材料,在室内连续培养试验中,分析了其对原土/外源镉污染土壤的钝化效应.结果表明,原炭及改性生物炭均降低了原状土壤有效态镉含量,其中Na OH和KMnO_4改性的炭材料钝化作用超过50%;在外源污染土壤中,NaOH、KMnO_4、FeCl_3改性炭材料均降低了土壤有效态镉含量,以添加10%的BC-KMnO_4较佳,降低作用超30%,HNO3改性炭却活化了3.8%~24.5%的土壤有效态镉.10%BC-KMnO_4显著降低原状土壤中可交换态镉含量达65.1%,而BC-HNO_3在外源污染土壤中活化可交换态镉含量高达20.2%.原炭及改性生物炭均增加了土壤中有机碳、盐基离子含量;原炭及NaOH、KMnO_4改性生物炭提高了土壤pH,HNO_3改性炭则降低了土壤p H;原状土中有效态镉含量与pH、交换性钠离子含量呈显著负相关,外源镉污染土中有效态镉含量则与pH、有机碳、交换性镁、钾、钠离子含量呈显著负相关.KMnO_4改性生物炭显著提高土壤pH,增加土壤有机碳和盐基离子含量,降低土壤镉活性形态含量,可作为优选的原位钝化修复材料,而HNO_3改性生物炭显著降低了土壤pH,提高了土壤有效态和可交换态镉含量,具有促进土壤镉生物有效性的风险.     

Urbanization in Western China

China has experienced considerable urbanization in the past 60 years,especially since the implementation of the Economic Reform and Opening-up Policy in 1978.In 1949,there were only 132 cities with an urban population of 27.4 million,while in 2008 China had 652 cities with a total urban population of 606 million.Such urbanization is attributed to the boost in the number of cities and the urban population.Urban expansion enhanced geographic inequality between the three major regions in China.Compared with the eastern and central regions,western China only has 19%of the total cities and 18%of the urban population.The urbanization rate was 37.2%for the western region in 2008,while it reached 53.3%for the eastern regions and 45.3%for central China.Using a geographic information system(GIS)and statistical analyses,this study aims at explaining the structure and spatial development of urbanization,and highlighting the current issues of urban inequality in western China during the past two decades.The paper drew following conclusions:(1)Urbanization disparities between eastern and western China have become increasingly obvious,but seem to be evolving slowly since the establishment of the government’s Western Development Priority Policy in 2000.(2)Cities of various sizes were expanded in western China,and the main factors affecting the urbanization are population numbers and density,government investment and geographic conditions.(3)Current patterns of urbanization in the western region are distributed unevenly between provinces.     

Analysis of Soil and Water Balance on the Land Arrangement Function

Abstract

The natural supply of land resources is limited, but the economic supply may change along with social and economic development, and its size is decided bye nature and social and economic body conditions. When the supplying ability of land resources threatens the development of society and the conflict between people and land becomes tense, it forced people to improve land utilization and to increase the effective supply of land resources. The paper made an overall consideration on the characteristics of the irrigated farming and the frail ecological environment in Fuhai County, Altay Area, Xinjiang Uigur Autonomous Region and explored land arrangement planning as well as water resource planning and environmental protection. The paper evaluated natural resources, land utilization and water resource of the case study areas and focused on the spatio-temporal balance between the utilization of water and land resources. In the end the paper a feasible plan was made out for the land arrangement project.     

Construction of Circular Economy Industrial System

Abstract

It is difficult to realize the transformation from traditional economy industrial system to circular economy industrial system. Regarding primary raw materials as the indicators, the industrial system has been specified according to the divergence among the indicators and the circular utilization modes. In comparison with the association among industrial systems, the relationship among industrial sub-systems is named as industrial cross-linking in this paper. The industrial system which could completely utilize and recycle the indicators should be increased and strengthened, and the circular economy industrial system with complete industrial association and industrial cross-linking should also be constructed. Taking the development of circular agricultural system basing on the traditional agricultural system as an example, the traditional agricultural products are regarded as the indicators which have been divided into foodstuff and crop straws which are used to produce food and articles for use, like fertilizer, energy and papers etc. The way to construct the circular agricultural industrial system is to increase the industrial systems that could utilize the products generated from crop straws, feces and other castoffs and transform the wastewater and other trucks into environmental friendly products. It has also been pointed out that the construction of circular economy industrial system is conducive to the foundation of circular industrial economics and the establishment of the construction layout of circular economy and the application schemes. Suggestions to the theoretical and practical work of the next step have also been brought forward in this paper.     

China’s Export Expansion,Export Structure and Energy Consumption

Abstract

Since the reform and opening up, China’s export trade has maintained a rapid growth; meanwhile, China’s energy consumption has been increasing sharply. “High export and high energy consumption” has become the feature of China’s trade and economic development. In this paper, based on the input–output analysis approach, the authors have conducted an empirical study on the export trade and energy consumption of 21 trade industrial sectors. The results show that, China is a big net exporter of embodied energy. Assuming that the export growth rate of embodied energy maintains to be about 23.6%, the average annual growth rate of the past 32 years, and based on the input–output data of 2005, by 2030 China’s net export of embodied energy would be over eight times more than the aggregate energy production, which is obviously infeasible. As a country of very low per capita energy, China must change its export pattern, encourage or restrain the export of different industrial sectors according to their energy consumption intensity, and promote structural change of energy– efficient exported products, so as to achieve the sustainable development. Accordingly, the authors put forward some suggestions.     

Impacts of Suburbanization on Urban Eco-environment of Xi’an in China

Abstract

Suburbanization in large cities is an important phenomenon in the process of urbanization development in China in recent decades, which plays a very important role in promoting city development, whereas some side effects on the eco-environment appeared at the same time. This paper, taking Xi’an City in China as a case study site, analyzed the features of population suburbanization and industry suburbanization and pointed out the impacts of suburbanization on urban eco-environment. Based on the research, suggestions of countermeasures for urban planning and municipal management of Xi’an City in protecting urban eco-environment and conserving natural ecology were put forward in the end.     

Overestimated role of sulfate in haze formation over Chinese megacities due to improper simulation of heterogeneous reactions

Environmental Chemistry Letters - Heterogeneous reactions involving aerosol water, i.e., haze chemistry, are responsible for high aerosol concentrations observed during severe haze events in...     

The inactivation of bacteriophages MS2 and PhiX174 by nanoscale zero-valent iron: Resistance difference and mechanisms

• The resistance of phage PhiX174 to nZVI was much stronger than that of MS2. • The nZVI damaged the surface proteins of both bacteriophages. • The nZVI could destroy the nucleic acid of MS2, but not that of PhiX174. •The phage inactivation was mainly attributed to the damage of the nucleic acid. Pathogenic enteric viruses pose a significant risk to human health. Nanoscale zero-valent iron (nZVI), a novel material for environmental remediation, has been shown to be a promising tool for disinfection. However, the existing research has typically utilized MS2 or f2 bacteriophages to investigate the antimicrobial properties of nZVI, and the resistance difference between bacteriophages, which is important for the application of disinfection technologies, is not yet understood. Here, MS2 and PhiX174 containing RNA and DNA, respectively, were used as model viruses to investigate the resistances to nZVI. The bacteriophage inactivation mechanisms were also discussed using TEM images, protein, and nucleic acid analysis. The results showed that an initial concentration of 10⁶ PFU/mL of MS2 could be completely inactivated within 240 min by 40 mg/L nZVI at pH 7, whereas the complete inactivation of PhiX174 could not be achieved by extending the reaction time, increasing the nZVI dosage, or changing the dosing means. This indicates that the resistance of phage PhiX174 to nZVI was much stronger than that of MS2. TEM images indicated that the viral particle shape was distorted, and the capsid shell was ruptured by nZVI. The damage to viral surface proteins in both phages was examined by three-dimensional fluorescence spectrum and sodium dodecyl sulfate polyacrylamide gel electrophoresis (SDS-PAGE). However, the nucleic acid analysis demonstrated that the nucleic acid of MS2, but not PhiX174, was destroyed. It indicated that bacteriophage inactivation was mainly attributed to the damage of nucleic acids.     

Prenatal air pollution exposure increases the risk of macrosomia: evidence from a prospective cohort study in the coastal area of China

Environmental Science and Pollution Research - Effects of prenatal ambient air pollution exposure could increase the risk of adverse pregnancy outcomes, which have been well documented by various...     

A novel preparation process of straw-based iron material for enhanced persulfate activation of reactive black 5 degradation

Environmental Science and Pollution Research - In this study, a new straw-iron composite material (ST@Fe) was synthesized through impregnation and freeze-drying process for persulfate (PS)...