全文获取类型
收费全文 | 206篇 |
免费 | 6篇 |
国内免费 | 2篇 |
专业分类
安全科学 | 10篇 |
废物处理 | 21篇 |
环保管理 | 16篇 |
综合类 | 41篇 |
基础理论 | 50篇 |
污染及防治 | 38篇 |
评价与监测 | 24篇 |
社会与环境 | 13篇 |
灾害及防治 | 1篇 |
出版年
2023年 | 3篇 |
2022年 | 4篇 |
2021年 | 2篇 |
2020年 | 1篇 |
2019年 | 5篇 |
2018年 | 9篇 |
2017年 | 9篇 |
2016年 | 9篇 |
2015年 | 5篇 |
2014年 | 10篇 |
2013年 | 15篇 |
2012年 | 16篇 |
2011年 | 15篇 |
2010年 | 12篇 |
2009年 | 11篇 |
2008年 | 4篇 |
2007年 | 13篇 |
2006年 | 10篇 |
2005年 | 9篇 |
2004年 | 6篇 |
2003年 | 8篇 |
2002年 | 5篇 |
2001年 | 3篇 |
2000年 | 3篇 |
1999年 | 1篇 |
1998年 | 3篇 |
1996年 | 1篇 |
1995年 | 7篇 |
1994年 | 2篇 |
1992年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1982年 | 1篇 |
1974年 | 1篇 |
1958年 | 1篇 |
排序方式: 共有214条查询结果,搜索用时 15 毫秒
101.
Seasonal variations of heavy metals in central Greenland snow deposited from 1991 to 1995 总被引:1,自引:0,他引:1
Barbante C Boutron C Morel C Ferrari C Jaffrezo JL Cozzi G Gaspari V Cescon P 《Journal of environmental monitoring : JEM》2003,5(2):328-335
To better assess the seasonality in the fallout of heavy metals to central Greenland, a continuous series of 68 snow samples has been collected at a remote site in the Summit area from a 2.7 m pit using ultraclean sampling procedures. This covers a continuous four year time period from spring 1991 to spring 1995. Co, Cu, Zn, Mo, Rh, Pd, Ag, Cd, Sb, Pt, Pb, Bi and U were determined using ultrasensitive inductively coupled plasma sector field mass spectrometry under clean room conditions. In addition we also determined Al by graphite furnace atomic absorption spectrometry and Na+, Ca2+, SO4(2-), MSA and oxalate by ion chromatography, species that will assist in the interpretation of the trace metal data. The data show pronounced inter- and intra-annual variations, with large differences in the amplitude of these variations for the element studied, with few clear seasonality patterns. Generally, high concentrations are observed in the spring snow layers, while much lower concentrations are typical of summer snow layers. Significant correlations are observed between Co, Cu, Zn, Ag and Sb, while Pt, Pd and Rh show no correlation with the other metals. Crustal enrichment factors show that while the crustal dust contribution is probably important for some metals for part of the year (spring), anthropogenic inputs are as important in many instances. Pronounced intra-annual variations are observed for some metals, in particular Pt. The variations observed for this metal parallel fairly closely changes in Russian Pt production, which points to emissions from smelters in the Russian Arctic as likely sources for Pt. 相似文献
102.
Intercomparison of alpha and gamma spectrometry techniques used in (210)Pb geochronology 总被引:1,自引:0,他引:1
Zaborska A Carroll J Papucci C Pempkowiak J 《Journal of environmental radioactivity》2007,93(1):38-50
(210)Pb geochronology is a widely used tool in sedimentological studies aimed at the absolute ages of modern sediments (up to 100 years). (210)Pb activities required to model sedimentation regimes are measured using either alpha, gamma or beta spectrometry. Sediment accumulation rates derived from (210)Pb activity profiles measured by these methods are often used interchangeably in mass balance studies. Yet there is a lack of investigations considering the comparability of data derived using different analytical methods. Differences between methods could be caused by different behaviors of (210)Pb and (210)Po (used for alpha measurement) in the marine environment. In gamma spectrometry errors may arise when many gamma emitters are measured simultaneously and their activity peaks overlap. In alpha spectrometry chemical separation of (210)Po may result in analytical error due to incomplete sample dissolution. In the present study we evaluate total, supported and excess (210)Pb activities and their use in deriving sediment accumulation rates and (210)Pb excess inventories for three sediment cores collected from the Barents Sea. (210)Pb activities derived by alpha and gamma methods are shown to agree within counting error and there is also good agreement in the derived sediment accumulation rates. The inherent compatibility of analytical results based on alpha or gamma techniques is established. 相似文献
103.
Carlo C. Jaeger 《Environmental Modeling and Assessment》1998,3(4):211-225
Integrated Assessment (IA) is the pursuit of a research program generated by the limitations of traditional forms of risk
management. This claim can be justified by the following argument. Over the last decades, analysts and practitioners have
brought to maturity a large array of tools for risk management. Most of them rely on combining judgments of utility with judgments
of probability. This is the approach of the Rational Actor Paradigm (RAP). With many environmental problems, however, RAP‐based
tools have run into considerable practical and theoretical difficulties. In response to these difficulties, a series of alternative
approaches to practical risk management and to the theoretical understanding of risk have been elaborated. They try to embed
the rational choices of individual actors studied by RAP into a broader framework of social rationality. This task can be
approached by distinguishing situations where an actor holds unambiguous judgments of preference and probability from situations
characterized by ambivalent judgments. RAP can handle the former, but not the latter. Problems whose management requires a
combination of widely differing scientific disciplines are especially likely to involve ambivalent judgments of probability.
The study of such problems constitutes the research program of integrated assessment. It involves three main tasks: developing
IA models which can represent ambivalent expectations and evaluations, developing IA models which use such representations
to study non‐marginal changes of social systems, and developing procedures of participatory IA which enable researchers to
engage in an iterative exchange with various stakeholders.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
104.
Gloria Antonini Paolo Audisio Emiliano Mancini Alessio De Biase Carlo Tronci Giulia Rossetti Marco Trizzino 《Marine Biology》2010,157(2):371-381
Marine rock-pools, commonly found along the Mediterranean coasts, are isolated patches of habitat characterised by large spatial and temporal variations. The phylogeography of Calobius quadricollis and C. urbanelliae, two sibling species of moss beetles (Coleoptera, Hydraenidae) inhabiting Italian temporary marine rock-pool ecosystems, were studied using mitochondrial cytochrome c oxidase subunit I (COI). Our data suggest a strong association between the scored genetic variability and the geographical distribution of populations sampled for both species. These analyses provided evidences of episodic species range expansion and fragmentation, recurrent “flush and crash” and bottleneck episodes probably occurring during the Glacial Cycles. The observed phylogeographical pattern is probably related to the historical and biogeographical processes of Mediterranean areas, as well as both to the ephemeral habitat tipology and limited dispersal ability of these beetles. 相似文献
105.
Pedro A. Ochoa George Alexis Sagastume Gutiérrez Juan B. Cogollos Martínez Carlo Vandecasteele 《Journal of Cleaner Production》2010,18(12):1171-1176
An approach to Cleaner Production in a small factory of hydrated lime is presented. The work aims to improving fuel and limestone utilization and reducing waste production in the plant. Efforts mainly focus on the calcination stage, where around 50% of the production costs due to fuel consumption occur. To fulfill this objective, new indicators are proposed to evaluate the performance of the lime shaft kiln, in order to develop an operational control method for the calcination process. The systematic use of the developed operational control method is a powerful tool in the daily operation of a small lime factory, since it allows a more efficient calcination process with reduced environmental impact and production cost. 相似文献
106.
Paul van Nugteren Leon Moodley Geert-Jan Brummer Carlo H. R. Heip Peter M. J. Herman Jack J. Middelburg 《Marine Biology》2009,156(11):2277-2287
Organic matter (OM) remineralization may be considered a key function of the benthic compartment of marine ecosystems and
in this study we investigated if the input of labile organic carbon alters mineralization of indigenous sediment OM (OM priming).
Using 13C-enriched diatoms as labile tracer carbon, we examined shallow-water sediments (surface and subsurface layers) containing
organic carbon of different reactivity under oxic versus anoxic conditions. The background OM decomposition rates of the sediment
used ranged from 0.08 to 0.44 μmol C mlws−1 day−1. Algal OM additions induced enhanced levels of background remineralization (priming) up to 31% and these measured excess
fluxes were similar to mineralization of the added highly degradable tracer algal carbon. This suggests that OM priming may
be important in marine sediments. 相似文献
107.
Maria Concetta Bruzzoniti Rosa Maria De Carlo Corrado Sarzanini Dario Caldarola Barbara Onida 《Environmental science and pollution research international》2012,19(9):4176-4183
High concentration of NO 3 ? in groundwater has raised concern over possible contamination of drinking water supplies. In addition, the formation of haloacetic acids (HAAs) as by-products during disinfection with chlorine-based agents is still a relevant issue, since HAAs pose serious health hazard. In this work, we investigated the affinity of a precursor of Al-MCM-41 (a mesostructured hexagonal aluminosilicate containing the template surfactant) towards nitrate and HAAs, for its possible application in the removal of these pollutants from natural and drinking waters. Additionally, adsorption kinetics and isotherms were studied. The adsorbent was synthesized using cetyltrimethylammonium bromide as surfactant and characterized by physico?Cchemical techniques. Simulated drinking water was spiked with the EPA-regulated HAAs (monochloroacetic (MCAA), monobromoacetic (MBAA), dichloroacetic (DCAA), dibromoacetic (DBAA), and trichloroacetic (TCAA) acids) and placed in contact with the adsorbent. The effect of matrix composition was studied. Adsorption kinetic studies were performed testing three kinetics models. For the adsorption studies, three adsorption isotherm approaches have been tested to experimental data. The pollutant recoveries were evaluated by suppressed ion chromatography. The affinity of the adsorbent was TCAA = DBAA = DCAA > MBAA > MCAA with DCAA, DBAA, and TCAA completely removed. A removal as high as 77?% was achieved for 13?mg/L nitrate. The adsorption isotherms of NO 3 ? and monochloroacetic acid can be modeled by the Freundlich equation, while their adsorption kinetics follow a pseudo-second-order rate mechanism. The adsorbent exhibited high affinity towards HAAs in simulated drinking water even at relevant matrix concentrations, suggesting its potential application for water remediation technologies. 相似文献
108.
The phytotoxicity of olive-mill wastewater (OMW) has been suggested to be mainly due to its phenolic components. This study investigated the impact of three different low-cost dephenolization treatments on the wastewater phytotoxicity. To this aim, germinability of maize (Zea mays L.) seeds sown on a sandy-loamy soil which had been spread with different volumes (from 40 to 160m(3)ha(-1)) of either biologically-treated OMW or relative incubation control was determined. Biological treatments included either Panus tigrinus liquid cultures or incubation with commercial laccase (1UIml(-1)) or an innovative sequential combination of laccase and P. tigrinus cultures. All treatments markedly reduced phytotoxicity and promising results were obtained with commercial laccase. In fact, germinability and mean germination times in soil spread with laccase-treated OMW, did not significantly differ from those observed in soil irrigated with tap water (control) up to OMW volumes of 120m(3)ha(-1). Although the highest phenol reduction (ca. 81%) was obtained by the sequential use of laccase and P. tigrinus, the feasibility of the enzyme treatment is undoubtedly more convincing under the technological point of view. 相似文献
109.
Marinari S Calfapietra C De Angelis P Mugnozza GS Grego S 《Environmental pollution (Barking, Essex : 1987)》2007,147(3):507-515
The experiment was carried out on a short rotation coppice culture of poplars (POP-EUROFACE, Central Italy), growing in a free air carbon dioxide enriched atmosphere (FACE). The specific objective of this work was to study whether elevated CO(2) and fertilization (two CO(2) treatments, elevated CO(2) and control, two N fertilization treatments, fertilized and unfertilized), as well as the interaction between treatments caused an unbalanced nutritional status of leaves in three poplar species (P. x euramericana, P. nigra and P. alba). Finally, we discuss the ecological implications of a possible change in foliar nutrients concentration. CO(2) enrichment reduced foliar nitrogen and increased the concentration of magnesium; whereas nitrogen fertilization had opposite effects on leaf nitrogen and magnesium concentrations. Moreover, the interaction between elevated CO(2) and N fertilization amplified some element unbalances such as the K/N-ratio. 相似文献
110.
Alessandra Capponi Dr Giuseppe Rizzo Donatella Rinaldo Domenico Arduini Carlo Romanini 《黑龙江环境通报》1995,15(11):1007-1016
The objective of this study was to evaluate the effect of fetal blood sampling on cardiac flow velocity waveforms. Flow velocity waveforms were measured from the ascending aorta and pulmonary artery immediately before and after fetal blood sampling in 29 normally grown and 12 growth-retarded fetuses. The latter group was characterized by abnormal Doppler indices in the umbilical artery and middle cerebral artery suggestive of uteroplacental insufficiency as the causative factor of the impaired growth. The flow velocity parameters studied were the peak velocity, the time to peak velocity, and the left and right cardiac output and their ratio. In normally grown fetuses, the peak velocity and right and left cardiac output values increased significantly after fetal blood sampling, while no significant changes were observed in the other indices considered. The gestational age at the time of the procedure was positively related to the amplitude of these changes. In growth-retarded fetuses, fetal blood sampling did not induce any significant increase in cardiac output or peak velocities, while in more than 50 per cent of the fetuses these Doppler indices decreased. The amplitude of the decrease was significantly related to the severity of acidosis in the umbilical vein. In conclusion, the cardiac haemodynamic response to fetal blood sampling differs between normally grown and growth-retarded fetuses. This difference may explain the higher rate of complications occurring in the latter group of fetuses after blood sampling. 相似文献