全文获取类型
收费全文 | 2427篇 |
免费 | 202篇 |
国内免费 | 998篇 |
专业分类
安全科学 | 211篇 |
废物处理 | 129篇 |
环保管理 | 223篇 |
综合类 | 1451篇 |
基础理论 | 445篇 |
污染及防治 | 796篇 |
评价与监测 | 136篇 |
社会与环境 | 116篇 |
灾害及防治 | 120篇 |
出版年
2024年 | 11篇 |
2023年 | 58篇 |
2022年 | 125篇 |
2021年 | 125篇 |
2020年 | 128篇 |
2019年 | 94篇 |
2018年 | 97篇 |
2017年 | 122篇 |
2016年 | 98篇 |
2015年 | 148篇 |
2014年 | 172篇 |
2013年 | 240篇 |
2012年 | 204篇 |
2011年 | 235篇 |
2010年 | 205篇 |
2009年 | 171篇 |
2008年 | 196篇 |
2007年 | 160篇 |
2006年 | 155篇 |
2005年 | 96篇 |
2004年 | 89篇 |
2003年 | 80篇 |
2002年 | 82篇 |
2001年 | 74篇 |
2000年 | 76篇 |
1999年 | 61篇 |
1998年 | 62篇 |
1997年 | 46篇 |
1996年 | 41篇 |
1995年 | 43篇 |
1994年 | 29篇 |
1993年 | 26篇 |
1992年 | 23篇 |
1991年 | 19篇 |
1990年 | 9篇 |
1989年 | 9篇 |
1988年 | 7篇 |
1987年 | 5篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 2篇 |
排序方式: 共有3627条查询结果,搜索用时 15 毫秒
961.
Methyl iodide (MeI) is a promising alternative to methyl bromide in soil fumigation. The pest-control efficacy and ground water contamination risks of MeI as a fumigant are highly related to its gas-phase distribution and leaching after soil application. In this study, the distribution and leaching of MeI in soil following shank injection and subsurface drip application were investigated. Methyl iodide (200 kg ha(-1)) was directly injected or drip-applied at a 20-cm depth into Arlington sandy loam (coarse-loamy, mixed, thermic Haplic Durixeralfs) columns (12-cm i.d., 70-cm height) tarped with virtually impermeable film. Concentration profiles of MeI in the soil air were monitored for 7 d. Methyl iodide diffused rapidly after soil application, and reached a 70-cm depth within 2 h. Relative to shank injection, drip application inhibited diffusion, resulting in significantly lower concentration profiles in the soil air. Seven days after MeI application, fumigated soil was uncapped, aerated for 7 d, and leached with water. Leaching of MeI was significant from the soil columns under both application methods, with concentrations of >10 mug L(-1) in the early leachate. The leaching was greater following shank injection than drip application, with an overall potential of 33 g ha(-1) for shank injection and 19 g ha(-1) for drip application. Persistent residues of MeI remaining in soils after leaching were 50 to 240 ng kg(-1), and the contents were slightly higher following shank injection than drip application. The results suggest that fumigation with MeI may pose a risk of ground water contamination in vulnerable areas. 相似文献
962.
Adsorption of CrVI and p-methoxyphenol (PMP) on soil colloids at different pH media was studied. The resulting k1 and n of 1.89 x 10(2) and 0.53 (r2 = 0.99) and k2 and b of 0.13 and 1.25 x 10(3) (r2 = 0.96) were obtained from Freundlich (Q = k1Caqn) and Langmuir [Q = k2bCaq/(1 + k2Caq)] simulation equations, respectively, for CrVI adsorption on soil colloids (pH 4.20). The adsorption of PMP on soil colloids in pH 5.72 media was simulated by five different equations and the results indicated that the Fritz-Schluender one (r2 = 1.00) was the most suitable among them. Adsorption quantity of CrVI and PMP on colloids increased with increasing acidity in the pH range of 3.5-9.0. Study of CrVI adsorption kinetics indicated that the adsorption equilibrium of CrVI was reached rapidly within 2 h. In pure aqueous solution, CrVI reduction by PMP was observed only when the media's pH was lower than 4.0. Oxidation and reduction reaction between CrVI and p-methoxyphenol obviously occurred when soil colloids were involved in this system, even at pH > or = 7.0, which strongly suggested that minerals in soil colloids acted as catalysts to speed the reaction of CrVI and PMP. The oxidized product of PMP by CrVI, extracted by chloroform in acid media and analyzed by gas chromatography-mass spectrometry, was identified as benzoquinone. The reaction included two steps of one electron process. 相似文献
963.
Cd2+、Cu2+和Zn2+对人工湿地反硝化作用的影响 总被引:7,自引:1,他引:6
实验室研究了 3种重金属离子 Cd2+、Cu2+、Zn2+对人工湿地反硝化作用的影响 .以 100、500、1000 mg/kg剂量的 Cd2+、Cu2+、Zn2+处理人工湿地土壤样品 ,检测其 N2O的产生 .结果表明 ,3种金属离子的 500、1000mg/kg处理组土样 N2O的产生均显著降低 ,各金属离子抑制 N2O产生的程度顺序为 Cd2+>Zn2+>Cu2+,这与 3种金属离子在土样中的有效态浓度顺序是一致的 ,反硝化微生物在处理过程中逐步产生了对重金属离子的耐受性 ,500、1000mg/kg处理组样品的 NH+4- N浓度较对照组显著升高提示部分 NO-3- N由于反硝化过程的抑制而异化性还原为 NH+4-N. 相似文献
964.
965.
966.
电化学法生成Fenton试剂及其在工业染料废水降解脱色中的应用 总被引:2,自引:0,他引:2
以多孔石墨电极为阴极 ,电解时在阴极通以氧气或空气 ,电解生成的过氧化氢与阳极溶解的Fe2 +进行随后化学反应 ,现场生成羟基自由基 (Fenton试剂 ) ,进而对有机染整工业废水进行降解脱色反应。以可见光吸收谱图表征了工业染料废水经电解槽处理后吸光度的变化 ,以重铬酸钾法测试染料处理后的COD。实验结果表明 ,COD的去除率大于 80 % ,染料的脱色率达 1 0 0 % ,若将电解电流密度控制在 1 0mA/cm2 以下 ,槽电压可控制在 5V以内。实验结果表明 ,向阴极多孔石墨电极中通入空气与通入氧气的效果一致。 相似文献
967.
968.
A comparison of mussels (Perna viridis) and semi-permeable membrane devices (SPMDs) was carried out at five sites, representing a gradient of contaminant concentrations, in Hong Kong coastal waters. Mussels, originally collected from a “clean” location, were deployed along with SPMDs at each site for 30 days. Analyses for chlorinated pesticides and polychlorinated biphenyls (PCBs) indicated that SPMDs have potential as monitoring tools, and to some extent can overcome the problems associated with mussels, such as natural variability, differing age, sex, and physical condition. However, in most cases, SPMDs failed to rank the sites in the same order as mussels in terms of contaminant concentrations. Nonetheless, in localities where mussels cannot survive – as shown at Kwun Tong in the present experiment – SPMDs may be valuable in providing an indication of potentially bio-available lipophilic pollutants. 相似文献
969.
在分析国内外危险废物分级管理经验的基础上,结合健康风险的评估步骤,提出了基于全过程危险废物污染物释放情景的精细化-动态健康风险评价方法。充分考虑处理利用工艺、企业管理水平等因素对于危险废物中污染物释放概率和能力的影响,并基于污染物向环境介质的迁移转化,定量评估危险废物的健康风险。基于危险废物污染特性数据库和事故情景数据库,结合全过程信息采集技术,构建危险废物分级分类管理平台,进行涉废企业的风险级别划分,实施差异化管理,形成更加科学有效的危险废物全过程精细化管理体系。 相似文献
970.
两级滴滤去除硫化氢和甲硫醇混合恶臭气体 总被引:11,自引:0,他引:11
把氧化硫硫杆菌(T. thiooxidans)、排硫硫杆菌(T. thioparus)组成的自养菌群和黄单胞菌(Xanthomonas)为主的异养菌群分别接种在两个生物滴滤反应器中,将其依次串联净化处理硫化氢(H2S)、甲硫醇(MT)混合臭气.一级反应器(A#)的复合自养菌在酸性环境下对负荷为7~8g/(m3h)的H2S平均去除率可达94%,且不受混合气体中MT含量的影响.二级反应器(B#)适于中性环境,对负荷为4~5g/(m3h)的MT平均去除率为83%.若H2S在混合气体中浓度过高,经A#处理后的浓度仍高于50mg/m3,可导致后反应器酸化,使MT脱臭效率显著下降. 相似文献