Emission Factors for High-Emitting Vehicles Based on On-Road Measurements of Individual Vehicle Exhaust with a Mobile Measurement Platform

ABSTRACT

Fuel-based emission factors for 143 light-duty gasoline vehicles (LDGVs) and 93 heavy-duty diesel trucks (HDDTs) were measured in Wilmington, CA using a zero-emission mobile measurement platform (MMP). The frequency distributions of emission factors of carbon monoxide (CO), nitrogen oxides (NO_x), and particle mass with aerodynamic diameter below 2.5 μm (PM_2.5) varied widely, whereas the average of the individual vehicle emission factors were comparable to those reported in previous tunnel and remote sensing studies as well as the predictions by Emission Factors (EMFAC) 2007 mobile source emission model for Los Angeles County. Variation in emissions due to different driving modes (idle, low- and high-speed acceleration, low- and high-speed cruise) was found to be relatively small in comparison to intervehicle variability and did not appear to interfere with the identification of high emitters, defined as the vehicles whose emissions were more than 5 times the fleet-average values. Using this definition, approximately 5% of the LDGVs and HDDTs measured were high emitters. Among the 143 LDGVs, the average emission factors of NO_x, black carbon (BC), PM_2.5, and ultrafine particle (UFP) would be reduced by 34%, 39%, 44%, and 31%, respectively, by removing the highest 5% of emitting vehicles, whereas CO emission factor would be reduced by 50%. The emission distributions of the 93 HDDTs measured were even more skewed: approximately half of the NO_x and CO fleet-average emission factors and more than 60% of PM_2.5, UFP, and BC fleet-average emission factors would be reduced by eliminating the highest-emitting 5% HDDTs. Furthermore, high emissions of BC, PM_2.5, and NO_x tended to cluster among the same vehicles.

IMPLICATIONS This study presents the characterization of on-road vehicle emissions in Wilmington, CA, by sampling individual vehicle plumes. Approximately 5% of the vehicles were high emitters, whose emissions were more than 5 times the fleet-average values. These high emitters were responsible for 30% and more than 50% of the average emission factors of LDGVs and HDDVs, respectively. It is likely that as the overall fleet becomes cleaner due to more stringent regulations, a small fraction of the fleet may contribute a growing and disproportionate share of the overall emissions. Therefore, long-term changes in on-road emissions need to be monitored.     

Multireservoir real-time operations for flood control using balanced water level index method

This paper presents a real-time simulation-optimization operation procedure for determining the reservoir releases at each time step during a flood. The proposed procedure involves two models, i.e., a hydrological forecasting model and a reservoir operation model. In the reservoir operation model, this paper compares two flood-control operation strategies for a multipurpose multireservoir system. While Strategy 1 is the real-time joint reservoir operations without using the balanced water level index (BWLI) method, Strategy 2 involves real-time joint reservoir operations using the BWLI method. The two strategies presented are formulated as mixed-integer linear programming (MILP) problems. The idea of using the BWLI method is derived from the HEC-5 program developed by the US Army Corps of Engineers. The proposed procedure has been applied to the Tanshui River Basin system in Taiwan using the 6h ahead forecast data of six typhoons. A comparison of the results obtained from the two strategies reveals that Strategy 2 performs much better than Strategy 1 in determining the reservoir real-time releases throughout the system during flood emergencies in order to minimize flooding, while maintaining all reservoirs in the system in balance if possible. Consequently, the proposed model using the BWLI method demonstrates its effectiveness in estimating real-time releases.     

Electrokinetic extraction of lead from kaolinites: II. Experimental investigation

This is the second paper of two companion papers presenting the results of laboratory bench-scale experimental studies on electrokinetic extraction of lead from two different kaolinites. The theoretical formulation and numerical simulation of the process are presented in the first paper. Two different kaolinites were used in the study: (1) Georgia kaolinite and (2) Milwhite kaolinite. The lead spiked in Georgia kaolinite was highly mobilized and effectively extracted by the technique as the pH in the soil was significantly lowered by the electrokinetic process. Milwhite kaolinite has a much higher acid/base buffer capacity, and the required acidic environment could not be developed. As a result, removal of the lead spiked in Milwhite kaolinite was minimal. Comparison between simulations and experimental results is also presented. Factors affecting the cleanup efficiency of the process and potential enhancement techniques are also discussed.     

Development of regenerative dye impregnated mesoporous silica materials for assessing exposure to ammonia

The mesostructured materials MCM-41 and SBA-15 were studied as possible supports of bromocresol green (BG) dye impregnation for the ammonia gas detection because of their large surface area, high regenerative property, and high thermal stability. X-ray diffraction, transmission electron microscopy, scanning electron microscope, and N₂ adsorption analysis were used to characterize the prepared materials. These materials could sense ammonia via visible color change from yellowish-orange to blue color. The color change process of the nanostructured materials was fully reversible during 10 cyclic tests. The results indicated that the ammonia absorption responses of the two nanostructured materials were both very sensitive, and high linear correlation and high precision were achieved. As the gaseous ammonia concentrations were 50 and 5 ppmv, the response times for the SBA-15/BG were only 1 and 5 min, respectively. Moreover, the BG dye-impregnated SBA-15 was less affected by the variation in the relative humidity. It also had faster response for the detection of NH₃, as well as lower manufacturing price as compared to that of the dye-impregnated MCM-41. Such feature enables SBA-15/BG to be a very promising material for the detection of ammonia gas.

Implications: The detector tube is a convenient ambient ammonia detection device. However, almost all the commercial detector tubes can be used once only, which not only increases the purchase cost but also produces lots of waste. In this study, we developed two sensing materials that are sensitive for repeated usage. The two mesoporous silica-based materials, MCM-41 and SBA-15, are impregnated by an organic dye of bromocresol green to induce color change behavior that can be easily observed by the naked eye, and it is concluded that dye-impregnated SBA-15/BG is a very promising material for the detection of ammonia gas.     

Production of Activated Carbons from Pyrolysis of Waste Tires Impregnated with Potassium Hydroxide

ABSTRACT

Activated carbons were produced from waste tires using a chemical activation method. The carbon production process consisted of potassium hydroxide (KOH) impregnation followed by pyrolysis in N₂ at 600-900 °C for 0-2 hr. The activation method can produce carbons with a surface area (SA) and total pore volume as high as 470 m²/g and 0.57 cm³/g, respectively. The influence of different parameters during chemical activation, such as pyrolysis temperature, holding time, and KOH/tire ratio, on the carbon yield and the surface characteristics was explored, and the optimum preparation conditions were recommended. The pore volume of the resulting carbons generally increases with the extent of carbon gasified by KOH and its derivatives, whereas the SA increases with degree of gasification to reach a maximum value, and then decreases upon further gasification.     

Comparing removal of trace organic compounds and assimilable organic carbon (AOC) at advanced and traditional water treatment plants

Stability of drinking water can be indicated by the assimilable organic carbon (AOC). This AOC value represents the regrowth capacity of microorganisms and has large impacts on the quality of drinking water in a distribution system. With respect to the effectiveness of traditional and advanced processing methods in removing trace organic compounds (including TOC, DOC, UV₂₅₄, and AOC) from water, experimental results indicate that the removal rate of AOC at the Cheng Ching Lake water treatment plant (which utilizes advanced water treatment processes, and is hereinafter referred to as CCLWTP) is 54%, while the removal rate of AOC at the Gong Yuan water treatment plant (which uses traditional water treatment processes, and is hereinafter referred to as GYWTP) is 36%. In advanced water treatment units, new coagulation–sedimentation processes, rapid filters, and biological activated carbon filters can effectively remove AOC, total organic carbon (TOC), and dissolved organic carbon (DOC). In traditional water treatment units, coagulation–sedimentation processes are most effective in removing AOC. Simulation results and calculations made using the AutoNet method indicate that TOC, TDS, NH₃-N, and NO₃-N should be regularly monitored in the CCLWTP, and that TOC, temperature, and NH₃-N should be regularly monitored in the GYWTP.     

High variation of PCDDs, PCDFs, and dioxin-like PCBs ratio in cooked food from the first total diet survey in Taiwan

This study determined the levels of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs), and dioxin-like polychlorinated biphenyls (dl-PCBs) in 240 individual food samples, belonging to 37 different foodstuffs in first total diet study (TDS) in Taiwan. The foods were collected from markets located in eight cities or counties around Taiwan. The food was cooked in a laboratory according to recipes typically used in Taiwan. In this study, PCDD/Fs were lower than the limits proposed by the European Union (EU) regulation for commercialized food, except for a notable PCDD/Fs level in ducks (3.660 pg WHO-TEQ/g, fat) obtained from central Taiwan. We hypothesize the duck meat might be probably polluted via emission of a fly ash recycling plant located near the duck farms. In addition to fish, most foods had high PCDD/Fs to dl-PCBs ratio. Needle fish and sea perch had relatively lower PCDD/Fs and dl-PCBs levels compared with those in other fish. Data from this study can be utilized for further consideration about dietary intake.