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81.
Influence of pH on the sonolysis of ciprofloxacin: Biodegradability, ecotoxicity and antibiotic activity of its degradation products 总被引:3,自引:0,他引:3
Evelien De Bel Jo Dewulf Bavo De Witte Herman Van Langenhove Colin Janssen 《Chemosphere》2009,77(2):291-295
The presence of antibiotics in the aquatic environment has raised concerns due to the potential risk for the emergence or persistence of antibiotic resistance. Antibiotics are often poorly degraded in conventional wastewater treatment plants. In this study, sonolysis at 520 kHz and 92 W L−1 was used for the degradation of the fluoroquinolone antibiotic ciprofloxacin. In a first experiment at pH 7, 57% of the ciprofloxacin (15 mg L−1) was degraded after 120 min of ultrasonic irradiation at 25 °C. pH proved to be an important parameter determining the degradation rate, since the pseudo first order degradation constant increased almost fourfold when comparing treatment at pH 7 (0.0058 min−1) and pH 10 (0.0069 min−1) with that at pH 3 (0.021 min−1). This effect can be attributed to the degree of protonation of the ciprofloxacin molecule. The BOD/COD ratio of the solutions, which is a measure for their biodegradability, increased from 0.06 to 0.60, 0.17, and 0.18 after 120 min of irradiation depending on the pH (3, 7, and 10, respectively). The solution treated at pH 3 can even be considered readily biodegradable (BOD/COD > 0.4). The antibiotic activity against Escherichia coli (G−) and Bacillus coagulans (G+) of the treated solutions also reduced after sonolysis. The highest decrease was again found when irradiated at pH 3. In contrast, ecotoxicity of the solutions to the alga Pseudokirchneriella subcapitata increased 3- to 10-fold after 20 min of treatment, suggesting the formation of toxic degradation products. The toxicity slowly diminished during further treatment. 相似文献
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83.
Clément Feger Laurent Mermet Bhaskar Vira Prue F.E. Addison Richard Barker Frank Birkin John Burns Stuart Cooper Denis Couvet Thomas Cuckston Gretchen C. Daily Colin Dey Louise Gallagher Rosemary Hails Stephen Jollands Georgina Mace Emily Mckenzie Markus Milne Paolo Quattrone Alexandre Rambaud Shona Russell Marta Santamaria William J. Sutherland 《Conservation biology》2019,33(4):972-975
Article impact statement: New collaborations with accounting research can improve conservation impact of ecosystem-based information systems. 相似文献
84.
Long-Term Effects of Logging on African Primate Communities: a 28-Year Comparison From Kibale National Park, Uganda 总被引:14,自引:0,他引:14
Colin A. Chapman † Sophia R. Balcomb Thomas R. Gillespie Joseph P. Skorupa ‡ and Thomas T. Struhsaker§ 《Conservation biology》2000,14(1):207-217
Abstract: If logging is to be compatible with primate conservation, primate populations must be expected to recover from the disturbance and eventually return to their former densities. Surveys conducted over 28 years were used to quantify the long-term effects of both low- and high-intensity selective logging on the density of the five common primates in Kibale National Park, Uganda. The most dramatic exception to the expectation that primate populations will recover following logging was that group densities of Cercopithecus mitis and C. ascanius in the heavily logged area continued to decline decades after logging. Procolobus tephrosceles populations were recovering in the heavily logged areas, but the rate of increase appeared to be slow (0.005 groups/km2 per year). Colobus guereza appeared to do well in some disturbed habitats and were found at higher group densities in the logged areas than in the unlogged area. There was no evidence of an increase in Lophocebus albigena group density in the heavily logged area since the time of logging, and there was a tendency for its population to be lower in heavily logged areas than in lightly logged areas. In contrast to the findings from the heavily logged area, none of the species were found at a lower group density in the lightly logged area than in the unlogged area, and group densities in this area were not changing at a statistically significant rate. The results of our study suggest that, in this region, low-intensity selective logging could be one component of conservation plans for primates; high-intensity logging, however, which is typical of most logging operations throughout Africa, is incompatible with primate conservation. 相似文献
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The ventilation mechanism of Rn gas in underground environments is considered. Ventilation plays an important role in influencing the variability (harmonics) of Rn gas in the porous space below the earth's surface. We propose a new physical-environmental model of relating Rn gas concentrations to air temperature variations at the earth's surface. Applicability of this model was tested after searching for Rn gas indicators of geodynamic processes in two underground tunnels in central and southern Israel. The theoretical estimation of Rn gas concentrations shows a good agreement with the observed values. We demonstrate the possibility of Rn gas anomalies being caused by atmospheric temperature variations and the necessity to take these effects into account when investigating geodynamic processes. 相似文献
87.
Variability in gasoline-water partitioning of major aromatic constituents (benzene, toluene, ethylbenzene, and xylenes (BTEX)) and methyl tert-butyl ether (MTBE) were examined for regular and ethanol-blended gasolines. By use of a two-phase liquid-liquid equilibrium model, the distribution of nonpolar solutes between fuel phase and water was related to principles of equilibrium. The models derived using Raoult's law convention for activity coefficients and liquid solubility is presented. The observed inverse log-log linear dependence of Kfw values on aqueous solubility, could be well predicted by assuming gasoline to be an ideal solvent mixture. Oxygenated additives (i.e., ethanol and MTBE), in the low percent range (below 5%), were shown to have minimal or negligible cosolvent effects on hydrocarbon partitioning. In the case of high fuel-to-water ratio (e.g., 1:1) or near contaminant source zone, the cosolvent effect of oxygenated gasoline with high content of ethanol (e.g., E85) will be environmentally significant. 相似文献
88.
Australian approaches to coastal vulnerability assessment 总被引:2,自引:1,他引:1
The Australian coastline is one of the longest and most diverse of any in the world, and Australian researchers have developed
preliminary models of the behaviour of major coastal systems such as beaches and reefs. The Australian population is particularly
focused along the coastline, especially in metropolitan centres; however, the population of regional centres along the coast
is increasing steadily in response to a phenomenon termed seachange. Coastal systems are increasingly threatened by potential
impacts as a result of climate change, as indicated by the successive assessments by the Intergovernmental Panel on Climate
Change (IPCC). Although Australia played a central role in applying a common methodology (CM), developed from IPCC guidelines
in the 1990s, and in devising alternative approaches, which were initially trialled at nine sites on the Australian coast,
there has not been a nationally co-ordinated approach to assessing the coastal vulnerability of Australia, and such an approach
is only emerging now. Instead, there have been a series of different approaches adopted to look at the different parts of
the Australian coast, including wetland mapping in northern Australia; geomorphic unit mapping in South Australia; storm surge
vulnerability modelling in Queensland; probabilistic approaches to beach erosion in New South Wales; indicative mapping of
potential coastal retreat in Tasmania. Additionally, there have been methods proposed by insurers and coastal engineers to
meet their requirements. Since 2005, the Australian government has once again seen the need for a national coastal vulnerability
assessment, and a series of studies are planned or under way to achieve the aims of a National Climate Change Adaptation Framework. 相似文献
89.
Van Hoecke K De Schamphelaere KA Ramirez-Garcia S Van der Meeren P Smagghe G Janssen CR 《Environment international》2011,37(6):1118-1125
Silica nanoparticles (NPs) belong to the industrially most important NP types. In a previous study it was shown that amorphous SiO(2) NPs of 12.5 and 27.0 nm are stable in algal growth inhibition assays and that their ecotoxic effects are related to NP surface area. Here, it was hypothesized and demonstrated that an alumina coating completely alters the particle-particle, particle-test medium and particle-algae interactions of SiO(2) NPs. Therefore, stability and surface characteristics, dissolution, nutrient adsorption and effects on algal growth rate of both alumina coated SiO(2) NPs and bare SiO(2) NPs in OECD algal test medium as a function of pH (6.0-8.6) and natural organic matter (NOM) contents (0-12 mg C/l) were investigated. Alumina coated SiO(2) NPs aggregated in all media and adsorbed phosphate depending on pH and NOM concentration. On the other hand, no aggregation or nutrient adsorption was observed for the bare SiO(2) NPs. Due to their positive surface charge, alumina coated SiO(2) NPs agglomerated with Pseudokirchneriella subcapitata. Consequently, algal cell density measurements based on cell counts were unreliable and hence fluorescent detection of extracted chlorophyll was the preferred method. Alumina coated SiO(2) NPs showed lower toxicity than bare SiO(2) NPs at concentrations ≥46 mg/l, except at pH 6.0. At low concentrations, no clear pH effect was observed for alumina coated SiO(2) NPs, while at higher concentrations phosphate deficiency could have contributed to the higher toxicity of those particles at pH 6.0-6.8 compared to higher pH values. Bare SiO(2) NPs were not toxic at pH 6.0 up to 220 mg/l. Addition of NOM decreased toxicity of both particles. For SiO(2) NPs the 48 h 20% effect concentration of 21.8 mg/l increased 2.6-21 fold and a linear relationship was observed between NOM concentration and effective concentrations. No effect was observed for alumina coated SiO(2) NPs in presence of NOM up to 1000 mg/l. All experiments point out that the alumina coating completely altered NP interactions. Due to the difference in surface composition the SiO(2) NPs, which had the smallest surface area, were more toxic to the alga than the alumina coated SiO(2) NPs. Hence, surface modification can dominate the effect of surface area on toxicity. 相似文献
90.