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Wei Zhang Huaqiang Chu Libin Yang Xiaogang You Zhenjiang Yu Yalei Zhang Xuefei Zhou 《Frontiers of Environmental Science & Engineering》2023,17(7):83
144.
Environmental Chemistry Letters - Heavy metals are a common class of toxic contaminants in soil, water and air, yet their occurrence in indoor environments is less known. Heavy metals enter... 相似文献
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Hua Fang Yun L. Yu Xiu G. Wang Xiao Q. Chu Xiao E. Yang 《Journal of environmental science and health. Part. B》2013,48(2):123-129
Effects of repeated applications of the herbicide butachlor (N-(butoxymethyl)-2-chloro -N-2′,6′-dimethyl acetanilide) in soil on its persistence and soil microbial functional diversity were investigated under laboratory conditions. The degradation half-lives of butachlor at the recommended dosage in soil were calculated to be 12.5, 4.5, and 3.2 days for the first, second, and third applications, respectively. Throughout this study, no significant inhibition of the Shannon-Wiener index H′ was observed. However, the Simpson index 1/D and McIntosh index U were significantly reduced (P ≤ 0.05) during the initial 3 days after the first application of butachlor, and thereafter gradually recovered to a similar level to that of the control soil. A similar variation but faster recovery in 1/D and U was observed after the second and third Butachlor applications. Therefore, repeated applications of butachlor led to more rapid degradation of the herbicide, and more rapid recovery of soil microorganisms. It is concluded that repeated butachlor applications in soil had a temporary or short-term inhibitory effect on soil microbial communities. 相似文献
148.
Changes in biomass activity and characteristics of activated sludge exposed to low ozone dose 总被引:1,自引:0,他引:1
Libing Chu Jianlong Wang Bo Wang Xin-Hui Xing Sangtian Yan Xulin Sun Benjamin Jurcik 《Chemosphere》2009,77(2):269-272
In this paper, the response mechanism of activated sludge exposed to low-dose ozone at less than 20 mg O3 g−1 total suspended solids (TSS) was studied by analyzing the changes in sludge activity and the evolution of C, N, P and metals from sludge following ozonation. The intracellular ATP concentration was not affected at less than 5 mg O3 g−1 TSS and thereafter decreased rapidly to around 60% when the ozone dose increased to 20 mg O3 g−1 TSS. Similarly, the efficiency of sludge solubilization initially changed a little and then increased rapidly to around 30% at an ozone dose of 20 mg O3 g−1 TSS. However, the activities of superoxide dismutase and protease decreased immediately upon exposure to ozone. These findings indicate that ozone firstly destroys the floc, leading to the disruption of the compact aggregates, which does not affect cells viability but induces a decrease in enzyme activities. Ozone then attacks the bacterial cells of the sludge, causing a decrease in cells viability. During ozonation, the content of carbon, nitrogen and phosphorus in the sludge matrix decreased, while the content of these elements in the micro-solids and supernatant gradually increased. Most of the released metals from the sludge matrix were found in the micro-solids. 相似文献
149.
Chia-Chang Wu Chun Chu Yei-Shung Wang Huu-Sheng Lur 《Journal of environmental science and health. Part. B》2013,48(1):58-68
A multiresidue method was developed to determine 19 carbamate pesticides in tea samples. Optimizations of different parameters, such as the type of extraction solvents, clean-up cartridges, and elution solvents were carried out. The developed method used acetonitrile as extraction solvent, amino cartridge for adsorbents and acetone-n-hexane as the eluting solution. Nineteen carbamate residues were then analyzed by high-pressure liquid chromatography (HPLC) with fluorescence detector. The present results showed good linearity by correlation coefficients of more than 0.9999 for all analyses. Limits of detection and quantification varied from 0.0005–0.023 mg L? 1, 0.008–0.077 mg L? 1, respectively. Recoveries of sixteen carbamate pesticides ranged from 65% to 135% at the spiked level of 0.5, 1.0 and 2.0 mg L? 1. The relative standard deviations were lower than 20% and coefficient of variations were lower than 15%. The results indicate that the proposed method provides an effective multi and trace level screening determination of carbamate pesticides residues for tea samples. 相似文献
150.
The partitioning and modelling of pesticide parathion in a surfactant-assisted soil-washing system 总被引:1,自引:0,他引:1
Soil sorption of organic pollutants has long been a problematic in the soil washing process because of its durability and low water solubility. This paper discussed the soil washing phenomena over a wide range of parathion concentrations and several soil samples at various fractions of organic content (foc) levels. When parathion dosage is set below the water solubility, washing performance is stable for surfactant concentrations above critical micelle concentration (cmc) and it is observed that more than 90% of parathion can be washed out when dosage is five times lower than the solubility limit. However, such trends change when non-aqueous phase liquids (NAPL) is present in the system. Parathion extraction depends very much on the surfactant dosage but is not affected by the levels of foc in the system. In between the extreme parathion dosage, a two-stage pattern is observed in these boundary regions. Washing performance is first increased with additional surfactant, but the increase slows down gradually since the sorption sites are believed to be saturated by the huge amount of surfactant in the system. A mathematical model has included foc to demonstrate such behavior and this can be used as a prediction for extraction. 相似文献