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781.
Solid-phase microextraction coupled with gas chromatography-mass spectrometry (SPME-GC-MS) was used to analyze two triazine (atrazine and simazine) and three chloroacetamide herbicides (acetochlor, alachlor, and metolachlor) in water samples from a midwest US agricultural drainage ditch for two growing seasons. The effects of salt concentration, sample volume, extraction time, and injection time on extraction efficiency using a 100-mum polydimethylsiloxane-coated fiber were investigated. By optimizing these parameters, ditch water detection limits of 0.5 microgL(-1) simazine and 0.25 microgL(-1) atrazine, acetochlor, alachlor, and metolachlor were achieved. The optimum salt concentration was found to be 83% NaCl, while sample volume (10 or 20 mL) negligibly affected analyte peak areas. The optimum extraction time was 40 min, and the optimum injection time was 15 min. Results indicated that atrazine levels in the ditch water exceeded the US maximum contaminant level for drinking water 12% of the time, and atrazine was the most frequently detected among studied analytes. 相似文献
782.
Nichols EG Gregory ST Musella JS 《Environmental pollution (Barking, Essex : 1987)》2008,156(3):928-935
Relationships between sedimentary organic matter (SOM) composition and PAH desorption behavior were determined for vegetated and non-vegetated refinery distillate waste sediments. Sediments were fractionated into size, density, and humin fractions and analyzed for their organic matter content. Bulk sediment and humin fractions differed more in organic matter composition than size/density fractions. Vegetated humin and bulk sediments contained more polar organic carbon, black carbon, and modern (plant) carbon than non-vegetated sediment fractions. Desorption kinetics of phenanthrene, pyrene, chrysene, and C3-phenanthrene/anthracenes from humin and bulk sediments were investigated using Tenax® beads and a two-compartment, first-order kinetic model. PAH desorption from distillate waste sediments appeared to be controlled by the slow desorbing fractions of sediment; rate constants were similar to literature values for kslow and kvery slow. After several decades of plant colonization and growth (Phragmites australis), vegetated sediment fractions more extensively desorbed PAHs and had faster desorption kinetics than non-vegetated sediment fractions. 相似文献
783.
The dominant discourse in 20th century UK food and agricultural policies of a liberal, free trade agenda was modified at the
turn of the 21st to embrace ecological sustainability and “food security.” The latter term has a long international history;
the relationship between issues of technical production and equality of distributional access are also much debated. The paper
examines shifts in UK policy discourse in the context of international research, policy, and initiatives to promote food security,
and highlights the implications for social justice in and through the food system. 相似文献
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Amy M. Breman Jennifer C. Chow Lance U'Ren Elizabeth A. Normand Sadeem Qdaisat Li Zhao David M. Henke Rui Chen Chad A. Shaw Laird Jackson Yaping Yang Liesbeth Vossaert Rachel H. V. Needham Elizabeth J. Chang Daniel Campton Jeffrey L. Werbin Ron C. Seubert Ignatia B. Van den Veyver Jackie L. Stilwell Eric P. Kaldjian Arthur L. Beaudet 《黑龙江环境通报》2016,36(11):1009-1019
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Francesca Romana Grati Denise Molina Gomes Jose Carlos Pinto B. Ferreira Celine Dupont Viola Alesi Laetitia Gouas Nina Horelli-Kuitunen Kwong Wai Choy Sandra García-Herrero Alberto Gonzalez de la Vega Krzysztof Piotrowski Rita Genesio Gloria Queipo Barbara Malvestiti Bérénice Hervé Brigitte Benzacken Antonio Novelli Philippe Vago Kirsi Piippo Tak Yeung Leung Federico Maggi Thibault Quibel Anne Claude Tabet Giuseppe Simoni François Vialard 《黑龙江环境通报》2015,35(8):801-809
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