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Ester Gutiérrez Sebastián Lozano M. Teresa Moreira Gumersindo Feijoo 《Journal of environmental management》2010,91(4):1002-1011
Nowadays, there is a trend in many countries towards more environmentally benign products and processes. Life-Cycle Assessment (LCA) is a quantitative analysis tool developed and utilized for the evaluation of environmental impacts occurring throughout the entire life-cycle of a product, process or activity. LCA requires a large amount of data in its different phases and can also generate large amounts of results which may be hard to interpret. In order to uncover and visualize the structure of large multidimensional data sets, Multivariate Analysis techniques can help. Hence, in this paper, a methodology using Principal Component Analysis and Multi-Dimensional Scaling is proposed and illustrated by means of two case studies. The first case study evaluates the operation of several wastewater treatment plants. The second case study deals with the environmental evaluation of the cultivation, processing and consumption of mussels. In both case studies, the redundancy present in the data allowed a dimensionality reduction from seven and ten to two dimensions, with a small loss of information. Plotting the environmental impact data in these two dimensions can help visualize, interpret and communicate them. 相似文献
64.
Analysis of Mosses and Soils for Quantifying Heavy Metal Concentrations in Sicily: A Multivariate and Spatial Analytical Approach 总被引:1,自引:0,他引:1
Gramatica P Battaini F Giani E Papa E Jones RJ Preatoni D Cenci RM 《Environmental science and pollution research international》2006,13(1):28-36
- DOI: http://dx.doi.org/10.1065/espr2006.01.006
Background The use of vegetal organisms as indicators of contamination of the environment is partially replacing traditional monitoring
techniques. Amongst the vegetal organisms available, mosses appear to be good bioindicators and are used for monitoring anthropogenic
and natural fall-out on soils. This study has two objectives: the evaluation of the concentrations of heavy metals in soils
and mosses of the Sicily Region, in Italy and the identification of the origin of fall-out of heavy metals.
Methods Mosses and the surface soil were sampled at 28 sites, only the youngest segments of Hylocomium splendens and Hypnum cupressiforme,
corresponding to the plant tissues produced during the last 3 years, were taken. The elements Cd, Cu, Ni, Pb and Zn were analysed
by ICP-MS and Hg by AAS. Statistical analysis was by PCA and spatial representation by GIS.
Results and Discussion In the mosses sampled in Sicily, the highest concentrations of Cd were found around the cities of Palermo and Messina. The
highest concentrations of Hg were recorded in the northern part of the island between Trapani and Messina, similar to the
distribution of Cu. Different areas with the highest concentrations of Ni were found near the south coast, in the vicinity
of Palermo and around the Volcano Etna. The highest concentrations of Pb were found in the south-west coast near Agrigento,
where important chemical plants and petroleum refineries are located. Except for a few locations, Zn fall-out was found to
be evenly distributed throughout Sicily.
Conclusion The sites where the concentrations of heavy metals cause greatest concern have been revealed by the PCA analysis and portrayed
using GIS. Also of some concern is the diffuse and anthropogenic origin of Hg and Cd. The combined approach of using soil
and mosses, together with pedological interpretation and application of multivariate statistical techniques has provided valuable
insight into the environmental aspects of heavy metal deposition in a region of southern Europe.
Recommendations and Outlook Further insight into the deposition of heavy metals will require more detailed sampling of soils and mosses in both new and
previous study areas. This needs to be complemented by detailed pedological investigations in the study areas. Future research
programmes will address these issues. 相似文献
65.
The contribution of chlorinated hydrocarbons (CHCs) to environmental problems in the Netherlands is discussed in an economic
context. The economic interactions within the chlorine market, including the link to caustic soda production, are described,
and PVC is taken as a case study. Key policy options are evaluated in terms of their potential for environmental improvement.
It appears that 95% of CHC emissions causing environmental problems are due to dissipative applications. With respect to the
specific problems of ozone depletion and global warming, only a small group of compounds is responsible for most of the impact.
Moreover, economic interactions within the group of CHCs can strongly influence the net effect of environmental policy measures.
Policies aimed at a reducing volume output of certain specific groups of CHCs will inevitably lead to trade-offs between environmental
problems. The environmental impact of a hypothetical ban on CHCs is discussed in relation to the use of PVC as a sink for
chlorine. Both these options appear to have drawbacks. Moreover, no absolute conclusion can be drawn until the environmental
impact of CHC substitutes is known. 相似文献
66.
Laura Scrano Sabino A. Bufo Franz Menzinger Philippe Schmitt-Kopplin 《Environmental Chemistry Letters》2006,4(4):225-228
Two new intermediates rising from the photolytic reaction of the sulfonylurea herbicide oxasulfuron have been identified in aqueous environment. The higher concentrations of the two derivatives oxetan-3-yl 2-(formilsulfamoyl) benzoate and N-(4,6-dimethyl-pyrimidin-2-yl) formamide were reached within 8 h of UV-irradiation. Here we demonstrate that an optimal separation and analysis of such compounds can be achieved by using a novel analytical method based on “non-aqueous” capillary electrophoresis (CE) system joined to an electrospray ionisation-mass spectrometry equipment. Using such a separation method and a particular electrophoretic solution a high reproducibility of migration times and peak areas can be obtained. 相似文献
67.
Ranking of aquatic toxicity of esters modelled by QSAR 总被引:1,自引:0,他引:1
68.
Pedro C. Silva J. Orestes Cerdeira M. João Martins T. Monteiro-Henriques 《Environmental and Ecological Statistics》2014,21(1):27-39
Given a set $X$ of $k$ points and a point $z$ in the $n$ -dimensional euclidean space, the Tukey depth of $z$ with respect to $X$ , is defined as $m/k$ , where $m$ is the minimum integer such that $z$ is not in the convex hull of some set of $k-m$ points of $X$ . If $z$ belongs to the closed region $B$ delimited by an ellipsoid, define the continuous depth of $z$ with respect to $B$ as the quotient $V(z)/\text{ Vol }(B)$ , where $V(z)$ is the minimum volume of the intersection of $B$ with the halfspaces defined by any hyperplane passing through $z$ , and $\text{ Vol }(B)$ is the volume of $B$ . We consider $z$ a random variable and prove that, if $z$ is uniformly distributed in $B$ , the continuous depth of $z$ with respect to $B$ has expected value $1/2^{n+1}$ . This result implies that if $z$ and $X$ are uniformly distributed in $B$ , the expected value of Tukey depth of $z$ with respect to $X$ converges to $1/2^{n+1}$ as the number of points $k$ goes to infinity. These findings have applications in ecology, namely within the niche theory, where it is useful to explore and characterize the distribution of points inside species niche. 相似文献
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Josep Mateu-Sbert Ignacio Ricci-Cabello Ester Villalonga-Olives Elena Cabeza-Irigoyen 《Waste management (New York, N.Y.)》2013,33(12):2589-2593
Tourism can sustain high levels of employment and income, but the sector is a source of environmental and health impacts. One of the most important is the generation of municipal solid waste (MSW). However, there is a lack of studies which quantify how much the tourist population engages in total MSW and separately collected recyclables. The aim of this paper is to estimate the impact of the tourist population on MSW, both total and separately collected, for the period 1998–2010, for the Mediterranean island of Menorca (Spain). We use dynamic regressions models, including data for monthly stocks of tourists. The results show that, on average, a 1% increase in the tourist population in Menorca causes an overall MSW increase of 0.282% and one more tourist in Menorca generates 1.31 kg day?1 (while one more resident generates 1.48 kg day?1). This result could be useful to better estimate the seasonal population of different regions, since intrannual fluctuation of MSW is used as a proxy measure of actual population (the sum of residents and tourists). Moreover, an increase of 1% in the tourist population causes an increase of 0.232% in separately collected recyclables and an additional tourist generates 0.160 kg day?1. One resident selectively collects on average 47.3% more than one tourist. These results can help in the planning of waste infrastructure and waste collection services in tourist areas. 相似文献