Poly- and perfluorinated compounds in household consumer products

Several household consumer products were analyzed for their content of perfluorooctanoate (PFOA), perfluorooctane sulfonate (PFOS), and fluorotelomer alcohols (FTOH) by nanoflow ultra performance liquid chromatography – mass spectrometry and gas chromatography – mass spectrometry. Among the investigated products, which are applied as sprays, were impregnating agents, cleaning agents, lubricants, and conditioners. In 14 of the 26 products analyzed, at least one polyfluorinated compound (PFC) was detected in 14 samples. 8?:?2 FTOH was the dominating PFC with concentrations up to 149?µg?mL^?1. The maximum concentration of PFOA was 14.5?µg?mL^?1, whereas PFOS was not detected in any sample. Investigated PFCs were mostly found in impregnating agents and lubricants, but were not detected in cleaning agents and conditioners. In FTOH-containing impregnating agents, similar ratios between 6?:?2 FTOH, 8?:?2 FTOH, and 10?:?2 FTOH were found. FTOH proportions in PFC-containing lubricants were similar as well. Total human exposure to PFC from consumer product aerosols for three different scenarios was estimated to be between 42.8 and 464?ng?kg^?1?per day.     

全球粮食危机：原因何在？ 出路何在？

当前,高涨的粮食价格已经造成了全球粮食危机,全球贫困人口无法获得粮食供应。解决粮食危机,关键是要根本改变世界农业发展方向。以往,人们以为通过向大自然不断索取,就可以提高食物产量。为了消灭所 有昆虫,或为了耕种,人们在土地上施用大量农药,最终使土地变成“工厂”。而不再是食物生产地。农业产业化确实能够在几年内增加农作物产量,收成显著。     

Determination of naturally occurring MTBE biodegradation by analysing metabolites and biodegradation by-products

Methyl tert-butyl ether (MTBE) is one of the main additives in gasoline. Its degradation is known to be difficult in natural environments. In this study, significant MTBE degradation is demonstrated at a contaminated site in Leuna (eastern Germany). Since the extent of the plume appeared to be constant over the last 5 years, an extended study was performed to elucidate the degradation processes. Special attention was paid to the production, accumulation and degradation of metabolites and by-products. Groundwater samples from 105 monitoring wells were used to measure 20 different substances. During the degradation process, several intermediates such as tert-butyl alcohol (TBA), tert-butyl formate, formate and lactate were produced. However, the potentially carcinogenic by-product methacrylate was not detected in several hundred samples. At the Leuna site, MTBE degradation occurred under microaerobic conditions. In contrast to hydrocarbons and BTEX, there was no evidence for anaerobic MTBE degradation. Among the degradation products, TBA was found to be a useful intermediate to identify MTBE degradation, at least under microaerobic conditions. TBA accumulation was strongly correlated to MTBE degradation according to the kinetic properties of both degradation processes. Since maximum degradation rates (v(max)) and k(m) values were higher for MTBE (v(max)=2.3 mg/l/d and k(m)=3.2 mg/l) than for TBA (v(max)=1.35 mg/l/d and k(m)=0.05 mg/l), TBA significantly accumulated as an intermediate by-product. The field results were supported by bench scale model aquifer experiments.     

A seventeen-year study of the rose star Crossaster papposus population in a coastal bay in southeast Alaska

A 17 yr study of a population of the rose star Crossaster papposus (Linnaeus, 1767) in Auke Bay, near Juneau, Alaska, used SCUBA to follow a total of 956 individually marked stars. Population density was relatively constant over the 17 yr of study, although the influx of smaller individuals varied by an order of magnitude. Growth in diameter of individual stars was inversely related to size, with the largest individuals showing negligible growth for periods of months or years. Annual survivorship was relatively high (from 76.3 to 90.4%), and some individuals persisted throughout the study, indicating longevities of at least 20 yr in this species. Observations of food habits indicated that the principal prey item is the reddish scallop Chlamys rubida. In summary, this rose star population was characterized by a relatively stable number of long-lived, slow-growing individuals. Received: 7 April 1998 / Accepted: 5 October 1998