Resources and waste management in Turin (Italy): the role of recycled aggregates in the sustainable supply mix

The ever increasing quantity of construction and demolition waste (C&DW) in Italy is presently challenging public administrators, which strive to ensure that collection and recycling are sustainably managed and need to understand whether and to what extent recycled aggregates can complement natural aggregates in a sustainable supply mix (SSM) for the construction industry. The paper presents a research aimed at analysing energy and environmental implications of the C&DW recycling chain in the administrative territory of Provincia di Torino in Northern Italy, with 2.25 million inhabitants and yearly generation of 1.8 million tons of C&DW. A combined Geographical Information System (GIS) and Life Cycle Assessment (LCA) model was developed using site-specific data and paying particular attention to land use, transportation and avoided landfill: crucial issues for sustainable planning and management. A GIS was used to handle data and information about 89 recycling plants, including technological features, output and physical–mechanical characteristics of recycled aggregate. The LCA methodology was used to identify and quantify energy and environmental loads, under different assumptions relevant to delivery distances, quality of recycled aggregates, local availability of natural aggregates and geographical coverage of market demand. The C&DW recycling chain was proved to be eco-efficient, as avoided impacts were found to be higher than the induced impacts for 13 out of 14 environmental indicators. It was also estimated that the transportation distance of recycled aggregate should increase 2–3 times before the induced impacts outweigh the avoided impacts.     

Comparison of atmosphere/aquatic environment concentration ratio of volatile chlorinated hydrocarbons between temperate regions and Antarctica

For the purpose of understanding the transport and deposition mechanisms and the air–water distribution of some volatile chlorinated hydrocarbons (VCHCs), their atmosphere/aquatic environment concentration ratio was evaluated. In addition, for the purpose of differentiating VCHC behaviour in a temperate climate from its behaviour in a polar climate, the atmosphere/aquatic environment concentration ratio evaluated in matrices from temperate zones was compared with the concentration ratio evaluated in Antarctic matrices.In order to perform air samplings also at rigid Antarctic temperatures, the sampling apparatus, consisting of a diaphragm pump and canisters, was suitably modified.Chloroform, 1,1,1-trichloroethane, tetrachloromethane, 1,1,2-trichloroethylene and tetrachloroethylene were measured in air, water and snow using specific techniques composed of a purpose-made cryofocusing-trap-injector (for air samples) and a modified purge-and-trap injector (for aqueous samples) coupled to a gas chromatograph with mass spectrometric detection operating in selected ion monitoring mode. The VCHCs were retrieved in all the investigated matrices, both Italian and Antarctic, with concentrations varying from tens to thousands of ng m⁻³ in air and from digits to hundreds of ng kg⁻¹ in water and snow.The atmosphere/aquatic environment concentration ratios were always found to be lower than 1. In particular, the Italian air/water concentration ratios were smaller than the Antarctic ones, by reason of the higher atmospheric photochemical activity in temperate zones. On the other hand, the Antarctic air/snow concentration ratios proved to be largely in favour of snow with respect to the Italian ratios, thus corroborating the hypothesis of a more efficient VCHC deposition mechanism and accumulation on Antarctic snow.     

Missing safety measures led to the jet fire and seven deaths at a steel plant in Turin. Dynamics and lessons learned

The Authors of this paper are the technical experts that were entrusted by the Public Prosecutor to conduct the technical inquiry into the accident that occurred in the ThyssenKrupp plant in Torino on December 6, 2007. The paper contains the results of the inquiry under the above mentioned point of view. The dynamics of the accident, the main causes and the consequences have been defined.This was an unusual accident from which important lessons can be learned. On December 6, a modest fire developed in the entry section of a pickling and annealing line in the TK plant in Turin. The eight workers on duty seized the firefighting equipment and started to try to extinguish the fire. The workers had portable fire extinguishers and a fire hydrant, so they had to get close to the fire to fight it. Suddenly, a violent jet fire, caused by the rupture of a hydraulic circuit, occurred. The flame instantaneously struck the eight workers while they were still fighting the fire. Seven workers suffered very serious burns, one died instantaneously while the other six had over the following month. One of the workers, who was partly protected by an operating machine, suffered only minor burns and survived. The paper contains some important lessons that have been learned from the present case, which demonstrate that the fire risk at pickling and annealing lines has generally been underestimated by the steel industry. The fire risk due to hydraulic actuators is also evident and new fire fighting strategies are suggested.     

Intrinsic vulnerability assessment of Sette Comuni Plateau aquifer (Veneto Region, Italy)

Maps illustrating the different degrees of vulnerability within a given area are integral to environmental protection and management policies. The assessment of the intrinsic vulnerability of karst areas is difficult since the type and stage of karst development and the related underground discharge behavior are difficult to determine and quantify. Geographic Information Systems techniques are applied to the evaluation of the vulnerability of an aquifer in the alpine karst area of the Sette Comuni Plateau, in the Veneto Region of northern Italy. The water resources of the studied aquifer are of particular importance to the local communities. This aquifer must therefore be protected from both inappropriate use as well as possible pollution. The SINTACS and SINTACS P(RO) K(ARST) vulnerability assessment methods have been utilized here to create the vulnerability map. SINTACS P(RO) K(ARST) is an adaptation of the parametric managerial model (SINTACS) to karst hydrostructures. The vulnerability map reveals vast zones (81% of the analyzed areas) with a high degree of vulnerability. The presence of well-developed karst structures in these highly vulnerable areas facilitate water percolation, thereby enhancing the groundwater vulnerability risk. Only 1.5 of the studied aquifer have extremely high-vulnerability levels, however these areas include all of the major springs utilized for human consumption. This vulnerability map of the Sette Comuni Plateau aquifer is an indispensable tool for both the effective management of water resources and as support to environmental planning in the Sette Comuni Plateau area.     

Effects of the herbicide molinate on the metabolic activities of a degradative Streptomyces griseus strain

Abstract

Cometabolic degradation of the herbicide molinate was tested using two microorganisms, Arthrobacter sp., strain M3 and Streptomyces griseus strain M2; the latter classified on the basis of the presence of the enzymatic cofactor SF‐420. The strains M3 and M2, inoculated in a basic salts medium with glucose as carbon source and added with 100 mg L^‐1 of molinate, degraded respectively 35 and 51% of the herbicide in 36 days.

Increasing concentrations of molinate, ranging from 50 to 200 mg L^‐1 in glucose medium, did not affect the final ATP yield of the strain M2, but decreased the final growth yield and the ATP synthesis rate. Moreover, the onset of coenzyme SF‐420 synthesis was progressively delayed.

In contrast, surprisingly, SF‐420 final yield and production rate were increased by progressive increasing concentrations of molinate in the mineral medium.     

Field derived accumulation and release kinetics of DDTs in plants

Vegetation plays an important role in influencing the air/surface exchange of semivolatile organic compounds (SOCs). In order to predict the capability of different plant species to capture chemicals from the air, plant-air partition coefficients and kinetic accumulation parameters must be defined. In this study, potted plants of three different species were transferred to the vicinity of a source point for DDT, namely a contaminated area around a former production plant in Italy. Leaves were constantly sampled in order to follow the uptake from air over time. Later, the potted plants were transported to a location characterized by background diffuse air concentrations for the release phase. Coupling the experimental results with a two-compartment accumulation model it was possible to derive the kinetics parameters and the plant-air partition coefficient K(PA) for p,p'-DDT. The logK(PA) (on a mass/volume basis) ranged between 1.7 and 2.2 for the different species. The uncertainties related to the different phenomena involved in a field uptake/release experiment are discussed.     

Implication of organic acids in the long-distance transport and the accumulation of lead in Sesuvium portulacastrum and Brassica juncea

The implication of organic acids in Pb translocation was studied in two species varying in shoot lead accumulation, Sesuvium portulacastrum and Brassica juncea. Citric, fumaric, malic and α-cetoglutaric acids were separated and determined by HPLC technique in shoots, roots and xylem saps of the both species grown in nutrient solutions added with 200 and 400 μM of Pb(II). The lead content of the xylem saps was determined by ICP–MS. Results showed that S. portulacastrum is more tolerant to Pb than B. juncea. Lead concentration in xylem sap of the S. portulacastrum was significantly greater than in that of B. juncea. For both species, a positive correlation was established between lead and citrate concentrations in xylem sap. However minor relationship was observed for fumaric, malic and α-cetoglutaric acids. In the shoots lead treatment also induced a significant increase in citric acid concentration. Both observations suggest the implication of citric acid in lead translocation and shoot accumulation in S. portulacastrum and B. juncea. The relatively high accumulation of citric acid in xylem sap and shoot of S. portulacastrum could explain its high potential to translocate and accumulate this metal in shoot suggesting their possible use to remediate Pb polluted soils.     

Air pollution impact assessment on agroecosystem and human health characterisation in the area surrounding the industrial settlement of Milazzo (Italy): a multidisciplinary approach

In order to evaluate the impact of atmospheric pollutants emitted by the industrial settlement of Milazzo (Italy) on agriculture, sulphur dioxide and ozone levels in air were monitored and the data were used to estimate yield losses of the most widespread cultures. Trace element concentrations in crops and soils were also detected and metabolic profiles of soil microbial communities were considered. Vibrio fischeri test was used to appraise airborne pollutant ecotoxicity and epidemiological studies on causes of death distribution were carried out to characterize health state of people living in the area. All the sampling points were selected in farms on the basis of a theoretical meteo-diffusive model of industrial air pollutants. Experimental SO₂ and O₃ values mainly exceeded the threshold established by Italian and EU regulations to protect vegetation and they correspond to estimated significant crop losses. Conversely toxic element residues in soils and in agroalimentary products were generally lower than the fixed values. SO₂ and O₃ concentrations, toxic element contents and ecotoxicity levels of airborne pollutants were not related only to industrial site emissions, while the fluctuations on metabolic profiles of soil microbial communities seem to agree with the predicted deposition of xenobiotic compounds from the industrial plants. The epidemiological study evidenced a better health state of populations living in the investigated area than in the Messina province and the Sicily region but, inside the area, males living in the municipalities closest to the industrial settlement exhibited a worst health state than those in the very far ones.     

Land Use, Climate and Transport of Nutrients: Evidence Emerging from the Lake Vicocase Study

Soil erosion is a Europe-wide problem, causing both loss of soil fertility and pollution due to nutrient transport into water bodies. This process is particularly important in the Mediterranean area, where the climate, characterised by long periods of drought followed by intense precipitation, favours soil erosion. Research carried out in this field has amply described this process, showing that climate and land use/land cover (LU/LC) are the two main factors regulating this phenomenon. However, the interaction between these factors is complex and experimental research is needed to understand the nutrient loads deriving from different land uses. This paper shows the results of a long-term monitoring project carried out in the Lake Vico basin (central Italy), using high resolution data and runoff samples to determine the phosphorus (P) export from four different LU/LC classes resulting from the same climatic event. The results highlight the fundamental role that LU/LC plays in terms of phosphorus load. Furthermore, the results appear to indicate that the maximum rainfall registered for 30′ (I _{30, max}), rather than the total quantity of precipitation, has the greatest effect on levels of erosion, and consequently on the migration of nutrients rather than the total quantity of precipitation can affect on erosion and therefore the migration of nutrients. These data could contribute to scientific planning support for land management choices aimed at controlling water pollution from non-point pollution sources.