黄海近岸表层沉积物中多环芳烃来源解析

采集了黄海近岸(日照岚山海域)12个站位的表层沉积物样品,利用气相色谱-质谱仪(GC-MS)分析了样品中16种多环芳烃(PAHs)的含量,结果显示16种PAHs含量范围在76.384～7512.023 ng·g-1,平均值为2622.576 ng·g-1.低环PAHs组分所占比重较大,中高环PAHs相对较小.利用比值法定性解析PAHs的来源,初步判断PAHs可能来自燃煤、燃油、焦化、柴油泄漏等污染源.进一步引用相关源成分谱,应用化学质量平衡模型(CMB8.2)对PAHs的来源进行定最解析,拟合计算结果表明研究海域表层沉积物中PAHs的主要来源为燃煤源、燃油源(主要为柴油燃烧)和焦炉源,其相对贡献率分别为53.99%、25.57%和13.97%.     

Species and distribution of rare earth elements in the Baotou section of the Yellow River in China

This paper analyses the contents and species distributions of rare earth elements (REEs) in the water-suspended particulate-sediment system of the Baotou section of the Yellow River, China, with known anthropogenic REE input from industrial discharges. The major forms of REEs were suspended and dissolved in the mainstream and the tributaries of the Baotou section, respectively. The concentrations of the dissolved and suspended REEs had the same trends in the overlying water along the mainstream, which increased from the Seqi section (site A) to the mouth of the Sidaosha River (site D), reaching a maximum value at site D, and tending to decrease thereafter. The contents of REEs in sediment cores showed enrichment with light rare earth elements (LREEs). The bound to carbonates and to Fe–Mn oxides are the major forms of REE in the secondary phase and the REE exhibited LREE enrichment pattern and moderate Eu depletion in suspended particulates and surface sediments. The contents and species distributions of REEs in the water-suspended particulate-sediment system of the Baotou section suggest that the anthropogenic source of REEs from Baotou city have enhanced REE accumulation to the Baotou section. This information is important for predicting possible pollution resulting from anthropogenic REE input into rivers.     

渤海典型海域表层沉积物正构烷烃特征比较

对渤海典型海域表层沉积物正构烷烃特征进行比较研究.分别采集葫芦岛市近岸海域(1#)、东营市近岸海域(2#)、营口市近岸海域(3#)9个站点的表层沉积物样品,经索氏提取、柱净化后进行GC-MS分析.结果表明,各站位都表现为双峰型,显示了陆源与海源双重贡献特征,但主导峰各不相同;正构烷烃含量(∑n-alk)均值分别为5.43μg.g-1、2.27μg.g-1、4.30μg.g-1;三海域碳优势指数CPI、奇偶优势指数OEP、姥鲛烷和植烷比值Pr/Ph等特征比值基本相同,指示混合来源及中性偏氧化的沉积环境;C31/C19均值分别为11.19、4.51、6.73,短/长链比值L/H均值分别为0.50、1.48、1.31,类脂物比值TAR均值分别为3.61、1.03、1.19,综合显示葫芦岛市近岸海域正构烷烃来源主要为陆源高等植物,而营口及东营近岸海域沉积物正构烷烃更多来源于内生浮游生物源及石油源,三海域沉积物受人类污染影响程度从高到低分别为2#海域(东营)>3#海域(营口)>1#海域(葫芦岛市),且东营近岸海域沉积物受石油污染特征明显.这些特征都与3个海域周边城市发展与污染输入特征有直接的关系.     

杂多酸水溶液脱除烟气中SO2的性能研究

合成了H3PMo12O40、H4SiW12O40、H3PW12O40、H4PMo11VO40、H5PMo10V2O40和H6PMo9V3O406种杂多酸,分别采用红外光谱（FT-IR）和X射线衍射（XRD）表征杂多酸的结构,并采用气相色谱仪对6种杂多酸水溶液进行脱硫实验测试。实验结果表明：制备的6种杂多酸具有良好的Keggin型结构;H3PMo12O40、H3PW12O40和H4SiW12O40的3种水溶液中,磷钼杂多酸的脱硫性能最好,脱硫率在120 min时可达到16.38%;不同比例的多原子也会使杂多酸有不同的脱硫性能,脱硫性能顺序为：H6PMo9V3O40〉H5PMo10V2O40〉H4PMo11VO40;且6种杂多酸的脱硫稳定性的顺序为：H4PMo11VO40〉H6PMo9V3O40〉H3PMo12O40〉H5PMo10V2O40〉H4SiW12O40≈H3PW12O40。     

基于Revit的医院火灾人员疏散路径优化及智能诱导

为了充分保障大规模人群疏散安全目标的实现,进行Revit二次开发,构建建筑物节点状态数据智能提取系统,自动生成建筑物节点初始状态数据库,利用自适应蚁群算法,以全体待疏散人群完成安全疏散时间最短为优化目标,开发人群应急疏散路径优化及智能诱导模型.通过对有无疏散诱导情况下某医院火灾中人员完成疏散所需时间及各出口人员滞留情况...     

基于PCA和SOM网络的洪泽湖水质时空变化特征分析

2010年分4个季度对洪泽湖全湖20个样点的水质理化特征进行了定期监测,采用修正的卡尔森营养状态指数法（TSIm）综合评价了洪泽湖水质的营养状况,同时应用主成分分析（PCA）和自组织特征映射网络（SOM网络）分析了洪泽湖水质的时空变化特征。结果显示：除了水深（WD）和透明度（SD）,洪泽湖的pH、EC、NH+4 N、TN、TP、和CODMn等水质参数季节差异显著。TSIm综合评价结果表明洪泽湖4个季节的水质均呈富营养化状态,夏季富营养化程度最严重。PCA分析表明洪泽湖水质主要受离子和氮盐的控制,磷不是控制洪泽湖水质的最主要因素。SOM网络将全湖20个样点聚为G1、G2和G3三类,G1代表洪泽湖相对封闭的北部区域,有沉水植被分布,水质主要受围网养殖污染的影响;G2代表洪泽湖东部和南部区域,〖JP2〗航运繁忙,直接承接淮河入湖河水,水质主要受淮河入湖河水和航运的影响;G3代表洪泽湖西部水域,沿岸密布养殖池塘且人口密度大,水质主要受养殖废水和城镇生活污水的影响。研究认为,控制外源污染和恢复沉水植被是防治洪泽湖富营养化的有效途径     

A study of daily and seasonal variations of radon concentrations in underground buildings

A study of daily and seasonal variations of radon concentrations in underground buildings in major cities of China was carried out. According to the data from the Model 1027 continuous monitor, radon concentrations in the underground buildings changed through two cycles each day. The first cycle was from 12:00 to 0:00 and the highest or lowest value, depending on location, was at about 19:00. The second cycle had a little change. Based on the data from solid state nuclear detectors (SSNTDs), it was concluded that the radon concentrations in underground buildings in winter were lower than in summer, which was opposite to that above the ground level. Similar to that above the ground level, the radon concentrations in spring were close to the year-round average radon concentrations.     

农地城市流转中农民集体福利均衡分析

农地城市流转中不同利益集团的福利状况韭已成为学者和政策制定者关注的焦点.农民集体作为影响最为深刻的利益集团之一,其福利在农地城市流转中能否实现以及如何实现均衡成为本文研究的核心内容.本文首先介绍了农民集体福利的概念及其测度方法,然后论述福利均衡的概念,提出农民集体福利均衡分析的三个假设,在此基础上,对农地城市流转中的农民集体福利进行分析,提出实现农民集体福利均衡的条件,结果表明农地城市流转中农民集体福利均衡的必要条件为农民集体获得的经济补偿大于或等于其福利损失.然后通过比较分析发现当前土地征收中农民集体获得的福利补偿不能弥补其福利损失,农地城市流转前后农民集体福利呈现不均衡状态.最后提出农地城市流转中要尊重农民集体的土地产权,进一步提高农地征收的补偿标准,使农民集体获得的货币补偿能够弥补其由于土地财产损失造成的福利损失,以实现农民集体福利的均衡;政府应当通过改善农村交通、通讯、电力、饮水、居住等条件,完善农村社会保障体系等措施提高农民集体的福利水平,以弥补农民集体土地发展权受限造成的二次福利损失.     

Is the degrowth debate relevant to China?

In industrialized countries, the idea of degrowth has emerged as a response to environmental, social, and economic crises. Realizing environmental limits to and failures of more than half a century of continual economic growth in terms of social progress and environmental sustainability, the degrowth paradigm calls for a downscaling of consumption and production for social equity and ecological sustainability. The call for economic degrowth is generally considered to be delimited to rich countries, where reduced consumption can save “ecological space” enabling people in poor countries to enjoy the benefits of economic growth. China, as one of the economically most expanding countries in the world, has dramatically improved its living standards, particularly along the Eastern coast, over the latest 30 years. However, China is absent from the international debates on growth. This article discusses the implications of the Western degrowth debates for China. Given the distinctive features of China’s development, the paper aims to enrich the degrowth debates, which have hitherto been dominated by Western perspectives. Based upon reflections on social, environmental, and moral dimensions of economic growth, the paper argues that limited natural resources may not continuously support universal affluence at the current level of the rich countries, a level that China is likely to reach within a few decades. Priority for growth in China should therefore be given to the poor regions of the country, and future growth should be beneficial to social and environmental development.     

气溶胶稳定硫同位素研究进展

稳定硫同位素可以用来示踪硫酸盐气溶胶的来源、迁移和转化的过程.本文首先介绍了目前气溶胶稳定硫同位素相关的分析测试方法,即EA-IRMS、MC-ICPMS和NanoSIMS.归纳了国内外气溶胶δ34S的时空组成特征,两极和沿海区域气溶胶δ34S值普遍高于内陆区域;冬季燃煤和夏季生物排放作用使得气溶胶δ34S值冬高夏低.同...