加油站电气设备安全隐患分析及防范对策

针对加油站电气设备存在的诸多问题,通过对加油站典型电气事故案例分析、电气隐患危害程度分级、第一级电气隐患原因分析、电气防爆检测要求与技术进行总结,对加油站电气设备隐患检查及安全管理提出建议和改进措施,为提升加油站电气安全管理水平提供指导。     

铜-胺改性ZSM-5吸附剂的制备及其对NOx的净化机理

以ZSM-5分子筛粉体为原料，成型后负载铜盐和有机胺改性，制备出一种高效脱除氮氧化物的吸附剂。通过改变铜盐、有机胺的含量以及铜盐活化温度使吸附剂的性能得到优化，在实验条件下（NO：初浓度1000mg／m^3，气流2．7L／min）床层对NO2动态吸附的透过时间由改性前的3min提高到90min，并使NO气体的释放得到有效减缓。通过动态吸附实验研究了NO释放时间在负载前后的变化，通过X射线光电子能谱（XPS）和红外分析（FTIR）研究了吸附剂表面铜元素、有机基团等在吸附前后的变化规律，提出了可能的净化机理。     

泥石流拦砂坝抗滑稳定性与剖面参数的关系

为了揭示泥石流重力式拦砂坝各剖面参数的变化对坝体稳定的影响规律,利用坝体抗滑稳定计算基本公式,在对不同性质泥石流(稀性泥石流和黏性泥石流)的两种荷载条件下(空库和满库)拦砂坝稳定性计算分析的基础上,推导出泥石流重力式拦砂坝的剖面参数与抗滑稳定系数的关系式.结果表明:当冲击力足够大时,抗滑稳定系数与拦砂坝高度和迎水面坝面坡度均呈正比,且抗滑稳定系数对迎水面坝面坡度更加敏感;其他受力状态时,抗滑稳定系数与迎水面的坝面坡度成正比,与拦砂坝高度成反比.基于推出的计算公式,提出了坝体剖面参数拟定的新方法,对坝体剖面进行优化.     

航空装备研制风险的综合赋权-双基点法评估

为实现对航空预研项目技术风险的定量评估,建立技术风险评价指标体系,建立基于综合赋权和双基点方法的综合评估模型,采用层次分析法(AHP)求得主观权重,熵值赋权法求得客观权重,运用线性规划方法求得对2类权重加权的权值,构造综合权重;使用正负理想点间的投影距离代替传统的相对欧式距离对TOPSIS方法进行改进;实例分析中,通过对某航空预研项目5种不同的方案进行风险评估,得出各方案的优劣度,选出了较为优化的技术方案,该方法可用于指导其他装备研制风险的评估。     

Aerosol optical properties of regional background atmosphere in Northeast China

Aerosol optical properties from 2005 to 2008 at the Longfengshan regional background station in Northeast China were measured and analyzed. The annual mean of aerosol optical depth (AOD) at 440 nm for the four years was about 0.27 ± 0.25, 0.39 ± 0.37, 0.35 ± 0.34, and 0.38 ± 0.38, respectively, and the corresponding annual mean for the Angstrom exponent between 440 nm and 870 nm was about 1.43 ± 0.48, 1.23 ± 0.37, 1.53 ± 0.47, and 1.55 ± 0.42. The average monthly AOD_440nm showed similar seasonal variation with a maximum in spring and a minimum in autumn. The monthly means of AOD at 440, 675, 870 and 1020 nm increase from the January to March with the maxima about 0.77 ± 0.04, 0.65 ± 0.04, 0.58 ± 0.06, 0.57 ± 0.07, respectively and decrease from September to February with the minima about 0.32 ± 0.12, 0.22 ± 0.09, 0.15 ± 0.08, and 0.13 ± 0.07 in January. The monthly mean of Angstrom exponent shows a minimum in March (0.97 ± 0.52) and a maximum in September (1.66 ± 0.29). Both the AOD and Angstrom exponent presents single peak distributions of occurrence frequencies. The Longfenshan data showed high AODs (>1.00) both clustering in the fine mode growth wing and the coarse mode. Two typical cases under dust and haze conditions showed that the AOD under dusty day decreased from 2.20 to 1.20 and the Angstrom exponent increased from 0.10 to 1.00. On the contrast, the AOD under haze day remained relatively stable about 0.90 and the Angstrom exponent was around 1.40. The 3-day backtrajectory analysis at Longfengshan illustrated that the air-masses near ground on the dust day were from Bohai Sea and passed through Liaodong Peninsula and Northeast plain in China. But the air-masses on 500 m AGL were originated from western Mongolia and crossed Gobi deserts, Otindag Sand Land and Horqin Sand Land in Northeast China. The air-masses at Longfengshan near ground 500 m and 1000 m AGL on the haze days were from North China Region and passed through Northeast Heavy Industrial Base in Northeast China.     

废旧混凝土用作水泥稳定基层的实验研究

随着城市建设的发展,城市道路改建时产生的大量的废弃混凝土块的有效利用成了一个亟待解决的问题。结合宜昌市东山大道改建项目,将废弃的混凝土面板加工形成再生集料用作水泥稳定碎石基层,达到节约资源和保护环境的目的。实验分析了再生集料的颗粒级配、压碎值、针片状颗粒含量、表观密度和吸水率等工程性质指标,同时对水泥稳定再生碎石的级配、最佳水泥掺量进行了设计,并对水泥稳定再生碎石的无侧限抗压强度指标进行了研究。研究表明,废旧混凝土经加工形成的再生集料具有良好的路用性能,其颗粒级配、压碎值以及主要指标均达到了路面基层材料的要求;掺3%、5%和7%水泥稳定再生集料7 d浸水抗压强度均达到路面基层的要求,水泥稳定再生集料用作路面基层是可行的;掺3%水泥稳定的再生集料可以用在公路的底基层,掺5%及7%水泥稳定的再生集料可以分别用作路面下基层和上基层。     

汶川地震灾区小流域洪水计算方法初探

汶川地震灾区小流域山洪不仅造成巨大损失,同时也是泥石流等灾害的激发因素,探寻一种准确且可操作的洪水峰值流量计算方法对防灾减灾具有重要意义。本文选择不同产流和汇流计算方法,组合成不同水文模型,进行小流域洪水过程计算,对模拟结果和参数选择进行对比,旨在探究最适合该地区的小流域水文计算方法。分别选择SCS曲线法、Green-Ampt入渗法、初损稳渗法进行坡面产流计算,应用SCS单位线法、Snyder单位线法和运动波方程进行坡面和沟道汇流计算,组合成5种小流域产汇流计算模型,利用6场洪水进行参数率定和结果验证。模拟结果对比分析,得出SCS曲线法是最适宜的产流模型,其与SCS单位线、运动波汇流计算方法组合而成的SCS和SKK模型,峰现时间的模拟误差最小,在0~25 min之间;洪峰流量模拟的相对误差较小,平均误差不超过4%;洪水总量模拟误差在10%左右。另外,这两种模型参数设置及确定较简单,更适合在数据稀缺的小流域中进行洪水模拟应用。研究可为汶川地震灾区小流域山洪和泥石流等灾害的流量估算提供方法和参数借鉴。     

环境保护成为长三角城市新型城镇化建设共识

2014年3月国家发展和改革委员会(简称国家发改委)颁布的《国家新型城镇化规划(2014—2020年)》为今后我国城镇化发展指明了方向,成为未来城镇化发展的纲领性文件。长江三角洲(简称长三角)是我国最大也是最强的经济区域,是我国仅有的世界级城市群,作为国家新型城镇化所在地,有23个成员城市列入国家试点。在《国家新型城镇化规划(2014—2020年)》颁布一周年之际,长江三角洲城市经济协     

美国超级基金5年回顾政策对我国污染场地风险管理的启示

通过简要概述美国超级基金5年回顾政策的形成与发展、执行约束力、实施内容,分析其实施过程中面临的问题,从环境立法、强化后期风险管理、完善污染场地风险管理链条、公开修复治理信息和提高社会公众参与度等角度,为解决我国因多样性修复技术实施导致的污染场地修复后风险难题提供可借鉴的重要经验,以期为构建适宜我国国情的污染场地修复长期风险管理和污染控制制度提供理论依据,实现污染场地修复后的安全再利用。     

A Comparison of Bayesian Methods for Uncertainty Analysis in Hydraulic and Hydrodynamic Modeling

We evaluate and compare the performance of Bayesian Monte Carlo (BMC), Markov chain Monte Carlo (MCMC), and the Generalized Likelihood Uncertainty Estimation (GLUE) for uncertainty analysis in hydraulic and hydrodynamic modeling (HHM) studies. The methods are evaluated in a synthetic 1D wave routing exercise based on the diffusion wave model, and in a multidimensional hydrodynamic study based on the Environmental Fluid Dynamics Code to simulate estuarine circulation processes in Weeks Bay, Alabama. Results show that BMC and MCMC provide similar estimates of uncertainty. The posterior parameter densities computed by both methods are highly consistent, as well as the calibrated parameter estimates and uncertainty bounds. Although some studies suggest that MCMC is more efficient than BMC, our results did not show a clear difference between the performance of the two methods. This seems to be due to the low number of model parameters typically involved in HHM studies, and the use of the same likelihood function. In fact, for these studies, the implementation of BMC results simpler and provides similar results to MCMC. The results of GLUE are, on the other hand, less consistent to the results of BMC and MCMC in both applications. The posterior probability densities tend to be flat and similar to the uniform priors, which can result in calibrated parameter estimates centered in the parametric space.