Relationship between biogenic amines and free amino Acid contents of wines and musts from Alentejo (Portugal)

The concentration of biogenic amines and free amino acids was studied in 102 Portuguese wines and 18 musts from Alentejo demarcated (D.O.C.) regions. Most wines were commercial, except for 38 monovarietals obtained by micro vinification. Musts from the varieties used to produce the latter wines were also studied. Both biogenic amines and free amino acids were analyzed by HPLC using fluorescence detection for their o-phthalaldehyde/fluorenylmethyl chloroformate (OPA/FMOC) derivatives. The most significant amines (average 10.8 mg/L for histamine+tyramine in red, and 7.4 mg/L for white wines) were found to be present at low levels and, although no important relationship between each individual biogenic amine could be obtained, the total amine content depends significantly on the assimilable amino acid content in wine.     

Characteristics of soil organic matter (SOM) extracted using base with subsequent pH lowering and sequential pH extraction

Humic substances from eight soils of varying properties were extracted by two different methods: (1) the traditional NaOH-extraction with subsequent acidification to different pH (approximately 1 to approximately 12) and sequential extractions using 0.01 M NaNO(3) at incremental pH (approximately 1 to approximately 11). Cumulative organic matter (OM) in the sequential extractions showed properties that were consistent with NaOH-extracted OM. The release of Al and Fe in the sequential extractions was closely related with the release of organic carbon (OC). The ratio of OC associated with humic acid (HA) and fulvic acid (FA) (the HA:FA ratio) varied widely among the soils indicating heterogeneity in their OM composition. However, a significant correlation between this HA:FA ratio and the NaOH extractable %OC content of the soils is indicative of the possible relationship between them. Between pH 5 and 7, which is a typical soil solution pH, a significant amount of HA-associated OC was soluble. In modeling metal speciation in soil solutions, it has been assumed that all dissolved organic carbon (DOC) that is active toward metal binding is associated with FA. The results of this study indicate that the validity of these assumptions based on model sensitivity alone is questionable.     

TOWARD A BETTER UNDERSTANDING OF RECREATIONAL BOATING IN THE ADIRONDACK LAKES REGION1

ABSTRACT: Results of a study to determine the relationship between physical characteristics of Adirondack lakes and variations in peak boat-use intensity indicated that 69 percent of the variation in peak use can be accounted for by the number of public and commercial boat-launching facilities per mile of lake shoreline. Other lake characteristics related to peak boat use were: the number of commercial overnight accommodations available, number of boat slips, lake size, and miles of lake shoreline. Lake characteristics not related to peak use were: accessibility, configuration, tent spaces available, surrounding landscape quality, volume of traffic and availability of other lakes. This information should provide recreation managers and planners with a better understanding of factors related to variation in peak boating-use periods.     

Molecular-level investigation of monoaromatic compound sorption to suspended soil particles by deuterium nuclear magnetic resonance

Molecular-level sorption behavior of monoaromatic compounds in suspensions of water-dispersable clay components was studied by measuring 2H nuclear magnetic resonance (NMR) spin-spin relaxation times (T2). In general, decreased T2 values indicate stronger solute-sorbent interactions and increased sorption of the solute. A decreasing trend for T2 values in the order benzene > fluorobenzene > toluene (-C6D5 moiety) was observed, which was probably caused by the hydrophobic effect. The T2 values for benzene and the -C6D5 moiety of toluene increased with increasing pH, whereas the trend with pH was much weaker and less consistent for fluorobenzene and the methyl group of toluene. Conversely, no clear relationship was found between T2 values and pH for dichloromethane. These contrasting results cannot be explained by the pH-dependent self-assembly and hydrophobicity of humics. Instead, directed specific forces, including hydrogen bonding, cation-pi interactions, and aromatic-aromatic interactions, are proposed between the benzene ring of monoaromatic solutes and soil organic matter (SOM). Substituents of benzene affect these interactions by varying the pi electron density. When the soil fraction was treated with NaOH to remove humic and fulvic acids, T2 values for the different monoaromatic solutes were surprisingly lower compared with those for the untreated soil fraction. This result is probably caused by the increased ratio of solutes adsorbed to "hard" or "glassy" SOM components, which leads to less mobile sorbed solute molecules, after removing NaOH-extractable humics that contain more "soft" or "rubbery" SOM components.     

Assessing potential bioavailability of metals in sediments: A proposed approach

Due to anthropogenic inputs, elevated concentrations of metals frequently occur in aquatic sediments. In order to make defensible estimates of the potential risk of metals in sediments and/or develop sediment quality criteria for metals, it is essential to identify that fraction of the total metal in the sediments that is bioavailable. Studies with a variety of benthic invertebrates indicate that interstitial (pore) water concentrations of metals correspond very well with the bioavailability of metals in test sediments. Many factors may influence pore water concentrations of metals; however, in anaerobic sediments a key phase controlling partitioning of several cationic metals (cadmium, nickel, lead, zinc, copper) into pore water is acid volatile sulfide (AVS). In this paper, we present an overview of the technical basis for predicting bioavailability of cationic metals to benthic organisms based on pore water metal concentrations and metal-AVS relationships. Included are discussions of the advantages and limitations of metal bioavailability predictions based on these parameters, relative both to site-specific assessments and the development of sediment quality criteria.     

Predictive effects of occupational and marital stress on the mental health of a male workforce

This study examined the predictive contribution of occupational and marital stress to the development of symptomatolgoy, affective disorder, and alcohol-related problems in a sample of 325 male power plant employees interviewed at baseline and one-year follow up. After controlling for known clinical and social risk factors, we found statistically significant predictive effects of job demands on affective disorder and job decision latitude on alcohol problems. In addition, the specific combination of high job demands with low decision latitude was important in predicting the occurrence of alcohol problems. Marital stress was not predictive of poorer mental health. The analyses provided only minimal support for a stress-buffering rote of social support.     

PROJECT 2000, A PLANNING IMPERATIVE1

Time is running out on this country's planners. Generally speaking, the art of planning has retrogressed since the time of Christ. If we are to survive, this will have to be drastically changed by the year 2000. To achieve this, we need to begin to change our thinking, today. We badly need wider social planning, giving us more alternatives-more thought on where we are going. Reasonableness requires blending of planning and construction-but a sharp line of independence is essential. We must think about all the consequences of a particular act. Through intensive professional development and achievement of professional expertise, many outstanding technicians often move into vital decision making positions within their respective agencies. As planners, they see a part of the action but miss the big picture. Problem solutions become restricted to agency or individual authorities and are not always the best alternative. Thus, the planning field is overflowing with solutions to our every problem but many solutions offer spot control, and while the black spot is removed from the garment the white spot remaining from the solution offers little consolation to the wearer.