秦山核电站运行后对邻近海域生态环境及其水质影响评价

通过对秦山核电站运行前后相隔近７ ａ 的工程区邻近海域四季度月生物与非生物环境生态各要素的两次调查分析，进行了Ⅰ期工程运行以来海域生态环境及水质状况的影响评价。结果认为，秦山海域具典型强潮河口湾生态特征，营养盐丰富，而生产力低下。潮汐、径流和湾外海水入侵是导致海洋环境要素季节和年际变化并直接影响海洋生物结构的主要因子。水体富营养化指数上升是沿岸工业和生活污水大量排放的结果。核电站运行中冷却水的热排放由于杭州湾特殊的海底地形和强潮混合的水体环境对附近水域的热升温效应不明显。秦山Ⅰ期工程运行以来对海域生态环境和水质变化未见明显影响     

大气中痕量挥发性有机物气相色谱保留时间的预估

为探寻环境中挥发性有机物气相色谱保留行为与结构的关系,应用三维原子场全息作用矢量(3D-HoVAIF),对39个大气中痕量挥发性有机物进行了结构表征.采用逐步回归对变量进行筛选,建立了8变量定量结构色谱保留相关(QSRR)模型,模型的复相关系数为R-1=0.985; 进而将3D-HoVAIF矢量与相对分子质量结合,建立了9变量QSRR模型,模型的复相关系数为R-2 = 0.991; 采用留一法交互检验,结果分别为RCV,1 = 0.970、RCV,2 =0.978,表明模型具有良好的估计能力和稳定性.     

新型TCAS吸附树脂对水中Cd2+的吸附去除研究

通过静态吸附试验,研究一种由超分子受体化合物磺化硫杂杯芳烃（TCAS）与树脂结合的产物——新型TCAS吸附树脂对重金属Cd²⁺的吸附去除性能,并初步探讨了吸附机理。试验研究结果表明,TCAS吸附树脂对Cd²⁺的饱和吸附量为14.45 mg/g。当温度为20℃,0.5 g TCAS吸附树脂对10 mL浓度为5 mg/L的Cd²⁺溶液吸附60 min时, Cd²⁺的去除率可达到99%以上。pH值是影响TCAS吸附树脂吸附效果的重要因素,在pH=5～9时,Cd²⁺的去除率随着pH值的升高而增大。在试验范围内,TCAS吸附树脂对Cd²⁺吸附符合Freundlich方程。吸附在TCAS吸附树脂上的Cd²⁺可洗脱回收,TCAS吸附树脂也可再生利用。 TCAS吸附树脂对重金属Cd²⁺的吸附机理主要归因于TCAS对Cd²⁺的络合作用。     

不同浓度养殖废水对青萍生长能力的影响

为了探讨废水浓度对青萍(Lemna minor)净化能力、生物质和能量积累能力的影响,以猪场养殖废水为供试废水,分析了在不同废水浓度下青萍对废水中总氮(TN)、氨氮和总磷(TP)的净化能力,青萍的生长情况,以及青萍中碳(C)、氮(N)、磷(P)元素含量和热值的变化情况。研究表明,青萍在1%浓度的废水中表现出最高的污染物净化能力。虽然青萍的C、N、P含量和热值均随废水浓度的增加而增加,但是由于相对增长率以1%的废水中生长的青萍最高,青萍的最高生产力、C和能量的固定能力均出现在1%废水浓度培养的青萍中,其次是5%废水浓度培养的青萍。多项式回归分析表明,可以使青萍获得最大C和能量固定能力的废水浓度为3.4%,对应的氨氮浓度为26 mg/L,TP浓度为3.4 mg/L。研究结果为进一步优化高生物质生产、高污染物去除率的养殖废水-浮萍培养体系提供了一定的基础。     

基于GPS的北京市2007-2012年地面沉降变化研究

利用经验模态分解(EMD)方法处理2007-2012年的北京GPS数据,并通过与地下水埋深比较分析近年来的地面沉降。首先通过2007-2012年的年沉降速率,发现北京沉降中心连片,形成了中东部的沉降漏斗。DSQI累积沉降量达到510 mm,DSQI、CHAO、NLSH三站点的年沉降速率分别为85 mm/a,41.7 mm/a和20mm/a。其次采用EMD方法提取DSQI、NLSH的垂向序列的趋势项,分析其沉降趋势。最后,对地下水埋深和GPS站点沉降趋势之间的关系进行了对比分析,地面沉降变化趋势与地下水水位变化具有较好的一致性,地下水水位变化是地面沉降发生发展的主要诱因。     

Antioxidative response to Cd in a newly discovered cadmium hyperaccumulator, Arabis paniculata F

A hydroponic experiment was carried out to study the effect of cadmium (Cd) on growth, Cd accumulation, lipid peroxidation, reactive oxygen species (ROS) content and antioxidative enzymes in leaves and roots of Arabis paniculata F., a new Cd hyperaccumuator found in China. The results showed that 22-89 microM Cd in solution enhanced the growth of A. paniculata after three weeks, with 21-27% biomass increase compared to the control. Cd concentrations in shoots and roots increased with increasing Cd supply levels, and reached a maximum of 1662 and 8670 mg kg(-1) Cd dry weight at 178 microM Cd treatment, respectively. In roots, 22-89 microM Cd reduced the content of malondialdehyde (MDA), superoxide (O(2)(-1)) and H(2)O(2) as well as the activities of superoxide dismutase (SOD), guaiacol peroxidase (GPX), ascorbate peroxidase (APX) and glutathione reductase (GR). In leaves, the contents of MDA, O(2)(-1) and H(2)O(2) remained unaffected by 22-89 microM Cd, while 178 microM Cd treatment significantly increased the MDA content, 69.5% higher than that of the control; generally, the activities of SOD, catalase (CAT), GPX and APX showed an increasing pattern with increasing Cd supply levels. Our present work concluded that A. paniculata has a great capability of Cd tolerance and accumulation. Moderate Cd treatment (22-89 microM Cd) alleviated the oxidative stress in roots, while higher level of Cd addition (178 microM) could cause an increasing generation of ROS, which was effectively scavenged by the antioxidative system.     

环境水中污染物亚硝酸根的现场快速测定研究

通过研制一种环境保护试纸从而能简便快速地现场半定量测定环境水中污染物亚硝酸根,便于野外水环境普查,应用它可使测定时间由标准法的3h左右短到5min,使分析成本大为降低。     

The epidemic characteristics of Kaschin-Beck disease (KBD) in different eco-environments

Epidemiological survey of 573 families, clinical examination of 2593 persons, and X-ray examination of 1136 persons (in 16 typical endemic villages) were conducted, based on the classification of endemiology for KBD disease areas, i.e, mountain type, loess plateau type, plateau type, and flatlands type. It was revealed that the KBD disease areas exhibited the regular pattern of corming-into-being, development and passing-away and the characteristics of growth and decline. Further, it was found clinically that the disease areas may be divided into 4 types, i.e., recent onset, developing, stable, and historical. This division is simple and easy, practical, scientific, and reliable and can be applied by medical personnel at different levels.     

含Cu-EDTA废水吸附法处理研究

用活性炭吸附法对Cu-EDTA废水的处理进行了工艺条件研究。结果表明,对含Cu40mg/L的络合剂废水,利用络合铜在酸性条件下的不稳定和活性炭表面电荷作用,在pH=5—6,采用活性炭进行搅拌吸附0.5h,铜的吸附率可达98％,出水残铜稳定在1mg/L以下。同时采用0.5mol/L H_2SO_4洗脱回收铜,且做到活性炭再生使用,铜的回收率为98％。为Cu-EDTA废水的处理提供了一个经济有效的方法。